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dc.contributor.authorHuang, Jen-How
dc.date.accessioned2010-10-12T18:55:12Z
dc.date.available2010-10-12T18:55:12Z
dc.date.issued2004
dc.identifier.urihttp://hdl.handle.net/11858/00-1735-0000-0001-3153-4
dc.description.abstractOrganotin-compunds (OTC) and Trimethyllead (TML) have a higher toxicity than their corresponding inorganic forms and may affect the functioning of ecosystems. Little is known about their behaviour and fate in the terrestrial environment. The goal of this thesis was to investigate the biogeochemistry of OTC (methyltin, butyltin and octyltin compounds) and TML in a forested catchment, especially their input and output budget. The occurrence of OTC, TML, Sntotal and Pbtotal in the atmosphere, soils, precipitation, and runoff in a forested ecosystem in NE-Bavaria, Germany were investigatedand the inputs and outputs in the solute phase determined. In addition, their ad-desorption and transformation (degradation) in forest soils was studied using batch experiments and long term incubations, respectively. OTC and TML concentrations in the gas phase during April to June 2003 was on average 110 pg Sn m3 and 0,34 pg Sn m3. Tri-, di-substituted and octyl species were the dominant OTC in the gas phase. In aerosols, only butyltin compounds, dimethyltin and monomethyltin (<500 pg Sn m3) were found and mono-substituted OTC predominated. For OTC, the washout factors were in the order: mono- >= di- > tri-substituted OTC, and the gas / particle partition coefficients were mono- >> di- >> tri-substituted OTC. Aerosol particles serve as a sink for OTC in the atmosphere, especially for monomethyltin and monobutyltin...
dc.format.extent46 S.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherUniv. Bayreuth
dc.rights.urihttp://e-docs.geo-leo.de/rights
dc.subject.ddc551.9
dc.subject.gokVOBB 500
dc.subject.gokVON 000
dc.subject.gokVJF 000
dc.titleBiogeochemistry of organotin and organolead compounds in a forested catchment in NE-Bavaria, Germany
dc.typemonograph
dc.subject.gokverbalOrganische Bodenchemie, Organische Bodenbestandteile
dc.subject.gokverbalBodenverschlechterung und Bodenkontamination
dc.subject.gokverbalUmweltgeochemie insgesamt
dc.identifier.doi10.23689/fidgeo-203
dc.identifier.ppn503004146
dc.type.versionpublishedVersion
dc.relation.collectionUmweltwissenschaften
dc.relation.collectionGeologische Wissenschaften
dc.description.typethesis


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