ORIGINAL PAPER The Itajaı´ foreland basin: a tectono-sedimentary record of the Ediacaran period, Southern Brazil M. A. S. Basei • C. O. Drukas • A. P. Nutman • K. Wemmer • L. Dunyi • P. R. Santos • C. R. Passarelli • M. C. Campos Neto • O. Siga Jr • L. Osako Received: 8 April 2010 / Accepted: 5 September 2010 / Published online: 21 October 2010  Springer-Verlag 2010 Abstract The Itajaı´ Basin located in the southern border of the Luı´s Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It pre- sents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Pre- cambrian turbiditic deposits. The basal succession of Itajaı´ Group is represented by sandstones and conglomerates (Bau´ Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeira˜o Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeira˜o Neisse (arkosic sandstones and siltites), and Ribeira˜o do Bode (distal silty turbidites) formations. The Apiu´na Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite rep- resents the last felsic magmatic activity to affect the Itajaı´ Basin. The Brusque Group and the Floriano´polis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, Sa˜o Miguel and Camboriu´ com- plexes. The lack of any oceanic crust in the Itajaı´ Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaı´ Basin is temporally and tecton- ically correlated with the Camaqua˜ Basin in Rio Grande do Sul and the Arroyo del Soldado/Piria´polis Basin in Uruguay. It also has several tectono-sedimentary character- istics in common with the African-equivalent Nama Basin. Keywords Dom Feliciano Belt  Ediacaran  Foreland basin  U–Pb SHRIMP ages  Provenance M. A. S. Basei (&)  C. O. Drukas  P. R. Santos  C. R. Passarelli  M. C. Campos Neto  O. Siga Jr Geosciences Institute, USP, Sa˜o Paulo, Brazil e-mail: baseimas@usp.br C. O. Drukas e-mail: cesarosorio_8@hotmail.com P. R. Santos e-mail: dosantos@usp.br C. R. Passarelli e-mail: crpass@usp.br M. C. Campos Neto e-mail: camposnt@usp.br O. Siga Jr e-mail: osigajr@usp.br A. P. Nutman School of Earth and Environmental Sciences, University of Wollongong, Wollongong, NSW, Australia e-mail: allen.nutman@gmail.com K. Wemmer Gottingen University, Go¨ttingen, Germany e-mail: kwemmer@gwdg.de L. Dunyi Beijing SHRIMP Center, Chinese Academy of Sciences, Beijing, China e-mail: liudunyi@bjshrimp.cn L. Osako Geosciences Institute, UFC, Ceara´, Brazil e-mail: lilianaso@hotmail.com 123 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 DOI 10.1007/s00531-010-0604-4 Introduction The best record of the transition between the collisional events that culminated with the constitution of the western Gondwana (end of the Ediacaran) and the stable conditions that enabled the installation of the Parana´ Basin (Lower Paleozoic) is found in the northern portion of southern Brazil, in a series of sedimentary and volcano-sedimentary basins that do not show the deformation and metamor- phism that characterize the units in the adjacent fold belts. Among the existing Neoproterozoic basins (the Itajaı´, Camarinha, Corupa´, Campo Alegre, Guaratubinha, and Castro basins) can be divided into two major groups: foreland and extensional basins (continental rifts): The Camarinha and Itajaı´ basins, which are predominantly sedimentary and situated at the borders of the Ribeira and Dom Feliciano belts respectively, are interpreted as peripheral foreland basins. The Castro, Guaratubinha, Campo Alegre, and Corupa´ basins are extensional and were installed on an old gneissic substrate. They are predomi- nantly filled with bimodal volcanic material, and are here classified as continental rifts. Except for the Castro Basin, which is the youngest of all (ca. 550 Ma), the available radiometric information indi- cates that the main magmatic phase that affected the extensional basins (ca. 600 Ma) preceded up to 40 Ma that of the Itajaı´ foreland basin (ca. 560 Ma), with both mag- matic events taking place between the two main com- pressional periods of 610 and 535 Ma that can be observed in southern Brazil. Despite older, but due to their intraplate setting, the extensional basins are undeformed, whereas the Itajaı´ and Camarinha foreland basins clearly record defor- mation associated with the proximity of the adjacent belts. Geologic Context of Itajaı´ Basin The northeastern portion of southeastern Brazil encom- passes five tectonic domains, juxtaposed around 600 ± 10 Ma as part of the western Gondwana assembly processes (Fig. 1). Two of the four major domains are constituted by the Paleoproterozoic gneissic-migmatitic rocks of the Curitiba and Luı´s Alves Microplates, which separate the Neoproterozoic Ribeira (N) and Dom Felici- ano (S) belts from one another. The fifth segment occurs in the coastal region, being represented by the Neoproterozoic Costeiro Granitic Belt, constituted by a variety of grani- toids and supracrustal remnants (Basei et al. 1998b). The Ribeira Belt is predominantly composed of Meso- proterozoic metasedimentary successions deposited in a passive margin setting on the eastern edge of the Paran- apanema Craton. In the Neoproterozoic, this belt behaved as an active margin, and was intensely affected by calc- alkaline magmatism represented by large granitic batho- liths that constitute the roots of the Neoproterozoic Treˆs Co´rregos, Cunhaporanga, and Agudos Grandes magmatic arcs. The main metamorphism and deformation overprints also occurred at this time (Basei et al. 1992, Siga et al. 2009). The granulite-migmatitic terrains that constitute the basement of the Curitiba Microplate were grouped into the Atuba Complex (Siga et al. 1995). These are constituted by banded biotite-amphibole gneisses, amphibolites, and a variety of granitoids, which underwent medium- to high- grade metamorphism. The history of these gneisses starts with magmatism in the Mesoarchean, around 3.0 Ga (Sato et al. 2003), with a first migmatization phase in the Oros- irian (*2,100 Ma) and a second migmatization phase by the end of the Ediacaran (*600 Ma). The Atuba Complex has a metasedimentary cover (Capiru and Setuva Forma- tions) probably of Neoproterozoic age and is crosscut by several Ediacaran anorogenic granitoids. The Santa Catarina Granulitic Complex (Hartmann et al. 1979; Kaul 1980; Basei et al. 2009) is a crustal segment consisting of high-grade metamorphic rocks, predomi- nantly charno-enderbites and migmatitic gneisses with occasional mafic–ultramafic bodies and paragneiss rem- nants. The Campo Alegre Basin (*600 Ma) represents the main cover recognized in the Luis Alves Microplate central region. The north–northeast limit with the Curitiba Microplate is defined by the Pieˆn Suture Zone (Basei et al. 1992; Machiavelli et al. 1993; Harara 2001, Harara et al. 2002). The evolution of the Santa Catarina Granulitic Complex started with the emplacement of a 2,600 Ma TTG suite, which was later affected by regional, Siderian (2,350 Ma) granulite-facies metamorphism and by an Orosirian (2,000 Ma) granulite/amphibolite-facies metamorphic event (Basei et al. 2009). After *1,900 Ma, the region became tec- tonically stable and was the only block in the southeastern Brazil that remained cold (\300C) since the end of the Paleoproterozoic, showing no evidence of the Neoprote- rozoic tectono-thermal overprint that is characteristic of the other terranes in the region. Its southern border is covered with the Itajaı´ Basin sediments, which are in tectonic contact with the Dom Feliciano Belt supracrustal rocks, with inverse faulting responsible for tectonic imbrications related to low-angle thrusts. The domain situated farther south is represented by the Dom Feliciano Belt northern termination. As the other segments of this Belt, it is inter- nally organized into three major compartments (Fig. 2): the Granitoid Belt (Floriano´polis Batholith arc-related granitoids), the Schist Belt (Brusque Group sedimentary covers metamorphosed to the greenschist- to amphibolite- facies), and the Foreland Belt (Itajaı´ Basin supracrustal rocks). 544 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 The Floriano´polis Batholith is predominantly composed of calc-alkaline to alkaline granitoid rocks and late iso- tropic alkaline granitoids. It represents the roots of an Ediacaran magmatic arc formed between 620 and 590 Ma as a result of the eastward subduction of an oceanic crust (Adamastor Ocean). The supracrustal rocks related to the Kaoko/Damara/Gariep belts represent the back–arc deposits (Basei 2000; Basei et al. 2005; 2008b). The Brusque Group stretches out in a NE–SW belt of ca. 40 km in width. It is composed of two metavolcano-sedimentary units separated by the Valsungana Batholith. Metavolcano- sedimentary successions predominate and represent the Brusque paleo-basin rift phase. They are characterized by tourmalinites associated with metabasalts, banded iron formations, quartzites and calc-silicate rocks, tectonically overlain by a thick metasedimentary sequence composed of micaceous quartzites, quartz-sericite schists, sericite schists, and local acid metavolcanic rocks. The granitic magmatism is characterized by three isotropic to slightly deformed granitoid suites of metaluminous to peralumi- nous composition marked by crustal contribution. The Itajaı´ Basin The Itajaı´ Basin represents a foreland-type basin of the Dom Feliciano Belt deposited by the end of the Neopro- terozoic, between 600 and 560 Ma. It comprises a thick pile of sedimentary rocks with a marked turbiditic contri- bution and was affected by important felsic volcanic activity (Basei et al. 1998a). It is an asymmetric basin, elongated approximately in the N60E direction and having the shape of a sigmoidal prism, with thickening of sedi- ments from north to south (Rostirolla 1991, Rostirolla et al. 1992). It occupies an area of ca. 700 km2 and extends for more than 80 km from the coast of Santa Catarina to its Fig. 1 Tectonic domains resulting from the amalgamation of Western Gondwana. 1 Tertiary and quaternary covers; 2 Parana´ Basin; 3 Serra do Mar Suite Granites; 4 Campo Alegre Basin, 5 Ribeira Belt Southern Portion; 6 Capiru and Setuba Metasedimentary sequences; 7 Atuba Complex; 8 Rio Pieˆn Batholith; 9 Costeiro Granitic Belt (Paranagua´ and Mongagua´ Batholiths); 10 Santa Catarina Granulitic Complex; 11 Itajaı´ Foreland Basin; 12 Brusque Group; 13 Camboriu Complex; 14 Granitoid Belt (Floriano´polis Batholith); 15 thrusting; 16 inferred contact; 17 tectonic transport (Simplified after Basei et al. 2009) Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 545 123 southeastern extremity, covered by the Parana´ Basin sedi- ments. The northern and southern limits of the Itajaı´ Basin are well defined in the field and distinct from one to another. The sediments of the northern border rest on Santa Catarina Granulitic Complex, the Paleoproterozoic base- ment of Luis Alves Microplate. In contrast, the southern border contact is predominantly tectonic, with the basal units being overthrusted by banded tonalitic-granodioritic gneisses of the Sa˜o Miguel Complex and by the metavol- cano-sedimentary rocks of the Brusque Group. Studies involving the Itajaı´ Basin started at the begining of the 20th century with countless works focusing on stratigraphy, such as Carvalho and Pinto (1938), Freitas (1945), Maack (1947) and Salamuni et al. (1961). In this phase, the Itajaı´ Basin sediments were grouped into two formations and the importance of the conglomerates was recognized. In later studies (Schulz Jr et al. 1970; Kaul 1976; Silva and Dias 1981), the two formations were described in detail and correlated with basins situated to the north, the Campo Alegre Formation being defined in this period. Basei (1985) reiterated the stratigraphic division of the Itajaı´ Basin into two units. The lower sandy unit, equivalent to the Gaspar Formation, is composed of mas- sive arkosic sandstones, volcanic tuffs, and thick poly- mictic conglomerates lenses representing proximal fluvial deposits. These are overlain by a rhythmic sandy-silty package formed by alternating silty and sandy layers and conglomeratic sandstone levels, related to proximal turbi- dites with channelized portions. The upper unit starts with silty-sandy deposits, interpreted as intermediate to distal turbidites. The top sediments are homogeneous, bluish, laminated argillites and siltites, related to distal, diluted turbidity currents associated with the vertical deposition. Applying sequence stratigraphy, Krebs et al. (1988; 1990); Appi (1991); Appi and Cruz (1990); Rostirolla et al. (1992, 1999) and Fonseca (2004) described the sedimentary environments in detail and proposed a series of major sequences divided into several sedimentary facies. Differ- ing from the previous proposal, the last three works pro- pose a third unit, which marks the return of progressively Fig. 2 Tectonic compartmentation of the Dom Feliciano Belt (modified after Basei 2000 and Basei et al. 2008a, b, c) 546 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 more continental depositional systems. Citroni (1993), from the recognition of depositional paleo-environments and their succession, presents a stratigraphic column rep- resented in terms of facies associations, from base to top: Continental Associations, subdivided into interlacing flu- vial sandy paleo-environments, followed by rudaceous alluvial fans; Transitional Associations, with shallow-water sandstones, deltaic sandstones, and coastal-plain sand- stones; Basinal Associations, with subaqueous sliding deposits followed by hemipelagic deposits; Turbiditic Associations, with diluted turbidites; classic, medium- density turbidites; graded, dense turbidites; and sandy to conglomeratic, dense turbidites. In the tectonic context, by means of structural frame- work, sedimentation pattern, regional tectonic scenario, and geochronology, several classification proposals were presented for the Itajaı´ Basin, which can be gathered in two main groups, one of which being the Rift-type Basin (Citroni 1993) or, in a broader sense, Molassic Foredeep, Foreland, Peripheral Foreland (Basei 2000; Basei et al. 2008b; Rostirolla 1991, Rostirolla et al. 1992, 1999; Guadagnin 2007). In the second group, the mechanism in question is flexural subsidence, related to overload of allochthonous terrains of the Dom Feliciano Belt, tectonically transported NW. Alternatively, Gresse et al. (1996), considering subduction to SW, classifies the Itajaı´ Basin as a foreland back-arc basin. It is here sug- gested, in accordance with Dickinson (1974), that the best classification for the Itajaı´ Basin be ‘‘peripheral foreland basin’’. The Itajaı´ Basin lithostratigraphic units The geologic map of Fig. 3 is a synthesis of the informa- tion collected in the Itajaı´ Basin over the past 20 years. The layout of the five lithostratigraphic units that constitute the Itajaı´ Group results from the deformation (folding and faulting) that affected the Basin. This deformation has always been neglected and consequently its great impor- tance in the present configuration of the basin has not been appreciated. Detailed NW–SE-trending geologic-structural Fig. 3 Geologic map of the Itajaı´ Basin: 1 Quaternary; 2 Basic sill; 3 Parana´ Basin; 4 Cambrian Subida granite; 5 Apiu´na volcanics; 6 Ribeira˜o do Bode Fm; 7 Ribeira˜o Neisse Fm; 8 Ribeira˜o Carvalho Fm; 9 Bau´ Fm; 10 Brusque Group; 11 Sa˜o Miguel Complex; 12 Santa Catarina Granulite Complex. The foliation attitudes were excluded for clarity Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 547 123 sections (Fig. 4) largely contributed to the definition of the units, of the stratigraphy and to calculate the apparent thickness of each unit. To reach these aims, the surface bedding (S0) and sedimentary features indicative of top and base were used. One of the main contributions from the geologic map was finding out that the units in the southern border represent the tectonic repetition of the basal units that are better represented in the northern border of the Basin. The proposed stratigraphic sequence must be understood as valid for the Itajaı´ Basin as a whole. Locally, some of the units described in the complete sequence may be lacking. The proposed stratigraphic column (Fig. 5) was estab- lished from field relationships and the analysis of the spatial behavior of the lithostratigraphic units. From base to top, the complete sequence comprises the Bau´ Formation, the Ribeira˜o Carvalho Formation, the Ribeira˜o Neisse Formation, the Ribeira˜o do Bode Formation, and the Api- u´na Formation. The continental Bau´ Formation represents the basal unit and occurs in both borders. It is composed of clast-sup- ported, polymictic conglomerate lenses that extend for hundreds of meters, having a sandy-arkosic matrix. The clasts vary from granules to boulders. They are composed predominantly of gneisses, granites, vein quartz, quartzites, and mylonites (Fig. 6a). Mica-schist clasts and fragments of rock types of the Itajaı´ Basin itself are volumetrically less important. Toward the top, dark red, micaceous arkosic sandstones tend to predominate (Fig. 6b). They contain sub-angular to sub-rounded grains of moderate sphericity. These rocks are poorly sorted, medium- to coarse-grained or even conglomeratic and can grade to a granule-rich conglomerate. Volcanic tuffs occur intercalated with sandy levels. The primary sedimentary structures are clast imbrication and sigmoidal cross-stratification. Neverthe- less, the conglomerates are frequently chaotically orga- nized. The sandy levels form lenticular layers with thickness varying from 0.2 to 1.2 m and show an internal massive structure or normal graded bedding, plane-parallel stratification, tabular cross-stratification, tangential cross- stratification at the base, and low-angle, small, channelized cross-stratification. The estimated thickness of this unit is 1,350 m. The deposition of this pile can be attributed to deltaic fan systems, representing immature, coarse-grained alluvial sediments that entered the basin transversally, the basal conglomeratic level representing the gravelly deltaic plain facies and the upper sandy level representing the proximal deltaic front facies (Fonseca 2004). Overlying the Bau´ Formation there occur the rhythmic sediments of the Ribeira˜o Carvalho Formation. This 650- m-thick unit is composed of rhythmites resulting from proximal turbiditic contribution and can be divided into two main rock types: (1) Rhythmites represented by tabular bodies with rippled top and rare erosion features, composed of medium- to fine-grained sandstones intercalated with centimeter- to decimeter-sized layers of shale (Fig. 6c), Fig. 4 Geologic-structural sections that show the spatial relationships between the mapped units. Same colors as presented in Fig. 3 548 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 siltites, and thicker, medium-grained sandstones. They present as sedimentary structures the TA, TB, TC, and TD Bouma facies, turboglyphs, and overload structures. The best examples occur close to Apiu´na, along the BR-470 highway, and are interpreted as turbiditic lobes and lobe fringes formed under a non-confined regime (Santos et al. 2008); (2) Rhythmites represented by apparently massive, slightly channelized bodies, composed predominantly of medium-sand- to coarse-sand-graded sandstones and thin sandstones intercalated with shale. These rhythmites are interpreted as channelized and lobe-channel transition turbidites (Santos et al. 2008), and are intercalated with polymictic conglomerate levels of massive structure. Locally they exhibit upward-fining and are formed by centimeter- to decimeter-sized angular to sub-angular clasts composed of quartz, milky quartz, fragments of varied Itajaı´ Basin rock types, and abundant acid volcanic rock clasts. The rhythmites are overlain and in gradational contact with the 1,000 m-thick Ribeira˜o Neisse Formation. This formation is composed of immature, poorly sorted, fine- to medium-grained, gray arkosic sandstones, showing plane- parallel stratification, climbing-ripple cross-stratification (Fig. 6d), small- and medium-scale channelized cross- stratification, and slumps. The upper Ribeira˜o do Bode Formation represents the youngest sedimentary unit of the Itajaı´ Group with esti- mated thickness of 1,500 m. It is composed of finely laminated siltites alternating with silty-argillaceous layers containing silty-sandy levels (Fig. 6e). Massive siltite levels occur subordinately. The greenish-gray laminated siltites constitute meter-sized layers with plane-parallel lamination, wavy, linsen, slump structures, and graded bedding. Intercalations of polymictic conglomerates with acid volcanics clasts occur associated with this unit. Completing the lithostratigraphic column, rhyolitic rocks of the Apiu´na Formation occur. The Subida leu- cosyenogranite represents the last magmatic activity to affect the Itajaı´ Group sediments, the emplacement taking place after the units that constitute the Basin had been deformed (Basei et al. 2008b). Structural geology The deformation pattern observed in the Itajaı´ Basin is characterized by two main folding phases with distinct axial orientations. The surface bedding S0 is the main surface in the whole Basin. Several primary structures can be recognized, which have not been transposed by any foliation generated by the tectonic events that followed sedimentation. On the map of Fig. 7, the stereograms constructed with the attitudes of the bedding poles mea- sured throughout the Itajaı´ Basin are represented. The dispersion of the foliation S0 poles indicate that the basin was affected by two phases of cylindrical folding: the first Fig. 5 Itajaı´ Group lithostratigraphic column, Santa Catarina Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 549 123 and more intense presents preferential axial orientation between E–W and NE–SW, parallel to the length of the basin; the second strikes approximately N–S. The first phase (D1) is the main deformation phase affecting the Itajaı´ Group as a whole. It is genetically associated with the thrusting that deformed the southern portion of the Basin. It is characterized by cylindrical folds, with axes parallel to the Basin elongation and to the thrusting front, which resulted from the Brusque Group overthrusting the Basin sediments, causing the repetition of the Itajaı´ Basin basal units in its southern flank. Figure 8a represents phase D1 folds affecting the bed- ding (S0) of the Ribeira˜o Neisse Formation sandstones, localized in the vicinity of Faxinal da A´gua Fria. Cylindrical folds (Fig. 9a) with axial orientation N70E/6 and N64E/16 are represented in this figure, the oblique cleavage poles S1 dipping much more strongly to SE, indicating tectonic vergence to NW. Figure 8b shows cylindrical folds of the same phase, which were charac- terized in rhythmites localized close to the Basin southern border. By using the maximum concentration of oblique cleavage S1 (Fig. 9b) data in the same section (Fig. 8c), the preferential vergence of the structures generated by D1 is confirmed to be toward NW. Phase D1 axial orientation can be clearly seen in the NW–SE sections, which are trans- versal to the Basin long axis. In several places, pencil structures formed by the intersection between the S1 foli- ation and the S0 bedding can be found (Fig. 9c). Fig. 6 a Clast-supported conglomerate of the Bau´ Formation, north of Gaspar. Imbricated clasts of gneisses, granites, vein quartz, quartzites and mylonites; b arkosic sandstone level in the Bau´ Formation; c proximal turbiditic rhythmites of the Ribeira˜o Carvalho Formation alternating medium- to fine-grained sandstones and shale and siltite layers. Ribeira˜o Carvalho Formation, outcrop along the BR-470 highway, between Ibirama and Apiu´na; d poorly sorted, medium-grained, immature arkosic sandstones with medium-scale cross- stratification, Ribeira˜o Neisse Formation, south of Apiu´na; e laminated silty-argillaceous sediments intercalated with decimeter- to meter-sized silty- sandy levels, Ribeira˜o do Bode Formation, south of Apiu´na 550 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 In the section of Fig. 10, phase D1 deformations are characterized by ample and open folds, represented by synforms and antiforms with vertical axial planes in the northern portion, which grade to inverse faults and thrust- ing close to the southern border of the Itajaı´ Basin, where the units of the Sa˜o Miguel Complex and Brusque Group overthrust the Basin younger units. Section CD, located in the proximity of the Ilhota municipality, and EF, close to the Gaspar municipality (Fig. 4), shows that the changes from one sedimentary unit to another are frequently tran- sitional. For bedding, strikes of ENE–WSW and dips of 15 to 40 SE predominate. In the northern border, the contact between the basal unit sediments and the gneisses of the Luı´s Alves Microplate basement (Santa Catarina Fig. 7 Stereograms (Schmidt diagrams, lower hemisphere) with attitudes of the poles of the main surface S0. Continuous girdles represent phase D1 folds; dashed girdles represent phase D2. The stereograms are drawn close to the areas where the data were collected Fig. 8 D1 cylindrical folds in a Ribeira˜o Neisse Formation sand- stones, and b Ribeira˜o Carvalho Formation rhythmites, representing the Itajaı´ Group first deformation phase—southern border, close to Faxinal da A´gua Fria; c oblique cleavage S1 along the Apiu´na- Faxinal da A´gua Fria section (concentrations represented in descend- ing order, from darker to lighter gray; total of 74 data; attitude of the maximum: N50E/42NW) Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 551 123 Granulitic Complex) is normal, whereas in the southern portion, the contact with the Brusque Group and the Sa˜o Miguel Complex is tectonic by inverse faulting (Fig. 9d). Here, the basement overthrusts the Basin sedimentary units and stratigraphic inversion also occurs, as seen between Apiu´na and Faxinal da A´gua Fria (sections a, b and c, d in Fig. 4). The amount and importance of the displacements related to the thrusts are hidden, in many cases, by shear planes parallel to the bedding surfaces (Fig. 9e). Fig. 9 Structural features— a Crest of phase D1, meter-sized fold, with NE-SW axial orientation. Siltites, south of Blumenau; b traces of S1 cleavage surface obliquous to S0 bedding in laminated siltstone; c pencil structures developed by S1/S0 interaction in siltstones, BR470, near Gaspar; d inverse faults in the contact between Itajaı´ conglomerates and Brusque metasediments, southern Itajaı´ border; e Sc/Ss relationship associated with fault movement parallelal to bedding plane with top displacement to NNW (right-hand side of the photo). Laminated siltites, Ribeira˜o do Bode Formation, South of Apiu´na Fig. 10 Geologic section between Apiu´na (NW) and Faxinal da A´gua Fria (SE). Stereographic projections (Schmidt-Lambert diagrams, lower hemisphere) of surface S0 for each unit. The colors for each unit correspond to those of the geologic map 552 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 The second deformation phase D2 is represented by ample and discontinuous folds of large wavelength and approximately N–S axial orientation, in general plunging slightly southward. The stereogram of Fig. 11a, con- structed with structural data for the Ribeira˜o Neisse For- mation south of Apiu´na, shows the interference of phase D2 (dashed girdle) on phase D1. This second folding of axial orientation S5 W/25 causes a dispersion both of bedding poles, represented by approximately N–S-trending layers, and the attitudes of the oblique cleavage S1 poles. The same interference pattern is seen in Fig. 11b, con- structed with data from the Ribeira˜o do Bode Formation siltites, from near Faxinal da A´gua Fria. Phase D2 axis strikes S5E/50, causing strong dispersion of bedding poles and of cleavage S1. The comparison between the deformations recognized in the Itajaı´ Basin sediments and in the Brusque Group leads to the correlation of the two deformation phases in the Itajaı´ Basin, respectively, with the Brusque Group defor- mational phases D4 and D5, which affected it after the metamorphic peak (Basei 1985). Lithogeochemistry The geochemical study of the sedimentary rocks was car- ried out using 23 samples (Table 1) collected along three sections traversing the Itajaı´ Group units. This study aimed at understanding the variabilities between different Itajaı´ Basin lithostratigraphic units. The chemical composition of the terranes that acted as source areas of the Itajaı´ Basin sediments is probably the major controller of the geo- chemical signature of the Basin rocks (Rollinson 1993). The diagram in Fig. 12a was used to classify the sam- ples into major sandstone classes, the SiO2/Al2O3 ratio serving to distinguish quartz-rich sandstones from Al-rich sandstones, and the Na2O/K2O ratio to distinguish wackes from arkoses (Pettijohn et al. 1972). In this diagram, the sandstones from the Bau´ Formation and the Ribeira˜o do Bode Formation are classified as arkoses, lithic sandstones and wackes, whereas the sandstones from the Ribeira˜o Carvalho and Ribeira˜o Neisse Formations are characterized as lithic sandstones. This classification is maintained in the diagram involving Fe2O3 ? MgO, Na2O and K2O contents (Fig. 12b), except for the sandstones of the Sa˜o Pedro and Ribeira˜o Neisse Formations, which plot in the arkose field. According to Fig. 12c, practically all samples plot on or above the Na2O/K2O = 1 line, indicating that they are quartz-rich. In Fig. 12d the SiO2/Al2O3 ratio is used not only to distinguish quartz-rich sediments, wackes, and ar- gillites but also to evaluate mineralogical maturity (Petti- john et al. 1972). In turn, the Fe2O3/K2O ratio is very useful to distinguish lithic feldspathic fragments present in sandstones. It is possible then to classify with this diagram the sediments of the Bau´ Formation as predominantly wackes; the sediments of the Ribeira˜o Carvalho and Ri- beira˜o Neisse formations as arkoses and shale, and the sediments of the Ribeira˜o do Bode Formation as predom- inantly shale with subordinate arkoses and wackes. It was also possible to characterize all the Itajaı´ Basin sediments as mineralogically immature. The ‘‘spidergrams’’ constructed using chondrite-nor- malized REE contents (McLennan and Taylor 1985) reveal a gradual increase in negative Eu anomaly and decrease in HREE fractionation from base to top. As can be seen in Fig. 13, the spidergram corresponding to the basal Bau´ Formation differs from those corresponding to the upper units. It shows a slight negative Eu anomaly, when com- pared to the intermediate values for the Ribeira˜o Carvalho and Ribeira˜o Neisse Formations and to the high values for the Ribeira˜o do Bode Formation. The Bau´ Formation shows the strongest HREE fractionation, which gradually decreases in the Ribeira˜o Carvalhos and Ribeira˜o Neisse Formations and is the weakest in the Ribeira˜o do Bode Fig. 11 Schmidt stereonet, lower hemisphere, demonstrating D2 folding and its overprint on D1. a Ribeira˜o Neisse Formation, south of Apiu´na, and b Ribeira˜o do Bode Formation siltites, close to Faxinal da A´gua Fria Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 553 123 Table 1 WR geochemical data (major, trace and rare-earth elements) IA-01 IA-02 IA-03 IA-08 IA-09A IA-09C IG-01 IG-02 IG-04a IG-05B IG-06B SiO2 76.2300 78.1200 72.8600 62.5100 64.1000 63.5200 69.3200 61.5600 60.9800 62.8400 63.4600 Al2O3 12.3200 10.7400 12.8600 17.8600 16.2600 17.2500 13.9000 17.9000 17.7900 17.7000 16.9500 MnO 0.0590 0.0830 0.0420 0.0630 0.0730 0.0630 0.0400 0.0950 0.1680 0.0900 0.1050 MgO 0.2300 0.4400 0.5200 1.5900 2.3000 2.2800 1.1600 1.8800 2.0200 1.9600 2.0400 CaO 0.0800 0.4100 0.8000 0.8900 0.3600 0.2900 1.6500 0.1100 0.0900 1.3000 0.6900 Na2O 3.6900 2.2900 2.0500 1.4000 2.4000 2.2400 3.0900 0.9900 0.8900 2.3700 1.8500 K2O 3.0500 3.4700 4.3700 4.8700 3.5700 4.1100 2.9800 5.0600 4.9900 4.3000 4.3000 TiO2 0.3050 0.3240 0.5240 0.8640 0.8020 0.8180 0.4880 0.9980 0.9210 0.8420 0.7210 P2O5 0.0240 0.0710 0.1070 0.1570 0.1720 0.1450 0.1140 0.0360 0.0260 0.1680 0.1550 Fe2O3 2.4400 2.1400 2.6600 5.6700 6.5000 5.9000 3.7200 7.4200 7.7700 5.9100 6.3300 Loi 1.1800 1.4200 2.4800 3.7900 3.0300 3.1000 3.0600 3.3600 3.8400 1.9400 3.0600 Total 99.6080 99.5080 99.2730 99.6640 99.5670 99.7160 99.5220 99.4090 99.4850 99.4200 99.6610 Ba 514.4000 575.3000 586.5000 470.8000 625.7000 618.5000 993.0000 1266.4000 884.5000 800.1000 576.5000 Ce 65.0000 56.4000 89.3000 106.6000 90.5000 88.5000 81.1000 76.2000 89.8000 91.7000 92.6000 Cl \50 \50 \50 \50 \50 \50 \50 \50 \50 \50 \50 Co 52.3000 63.0000 37.7000 25.1000 22.8000 18.8000 33.9000 25.5000 25.6000 22.0000 23.9000 Cr 26.3000 24.0000 29.3000 64.5000 76.7000 80.5000 98.6000 75.5000 95.5000 84.7000 75.3000 Cu 18.2000 8.9000 \5 30.1000 23.2000 5.4000 10.4000 \5 18.6000 23.7000 31.3000 F \550 \550 844.8000 1362.4000 1537.7000 1459.6000 \550 967.3000 929.8000 1091.0000 1210.9000 Ga 16.2000 13.8000 17.8000 27.1000 21.7000 24.3000 17.2000 25.0000 27.9000 25.5000 24.8000 La 29.3000 35.5000 50.7000 55.8000 39.1000 37.5000 46.1000 56.1000 40.6000 54.1000 41.4000 Nb 26.3000 23.1000 25.4000 26.4000 16.8000 16.6000 17.9000 21.5000 18.6000 23.5000 21.2000 Nd 39.9000 26.7000 41.7000 56.7000 49.6000 56.8000 36.6000 58.8000 61.1000 57.8000 48.6000 Ni 9.7000 10.9000 11.4000 28.5000 36.2000 35.3000 31.6000 37.0000 40.0000 35.4000 42.4000 Pb 25.7000 29.5000 32.6000 22.6000 12.4000 4.6000 16.5000 12.1000 32.7000 18.0000 18.5000 Rb 160.9000 155.5000 204.3000 251.3000 179.4000 198.8000 70.7000 234.9000 246.7000 210.5000 215.5000 S \300 \300 \300 \300 \300 \300 \300 \300 \300 \300 \300 Sc \14 \14 \14 17.8000 16.3000 15.7000 \14 17.7000 17.7000 16.8000 14.4000 Sr 85.1000 142.4000 149.1000 65.8000 75.7000 63.1000 368.1000 89.2000 50.1000 180.0000 124.8000 Th 20.8000 16.2000 25.4000 27.6000 12.7000 16.3000 15.8000 19.1000 16.4000 18.1000 12.7000 U 13.5000 12.4000 12.4000 13.7000 13.7000 15.8000 6.8000 16.1000 17.3000 11.6000 13.0000 V 25.8000 31.8000 41.0000 90.0000 103.1000 123.5000 63.1000 93.2000 83.2000 101.8000 84.6000 Y 45.6000 26.6000 38.6000 48.4000 38.0000 36.1000 17.7000 44.1000 38.2000 48.2000 37.9000 Zn 62.1000 37.7000 48.5000 99.1000 113.1000 100.0000 37.8000 86.2000 101.2000 99.4000 121.1000 Zr 184.6000 172.6000 358.9000 280.3000 214.3000 178.8000 179.0000 271.1000 221.5000 247.1000 213.4000 Sm 7.1946 5.8621 10.0652 10.1051 7.3379 6.3941 5.7650 7.0130 7.7255 8.7093 6.7026 Hf 6.7319 4.6484 10.7984 9.0700 6.5983 5.6438 5.3940 8.4414 6.9247 7.2027 6.3209 IG-07 CTI-01 CTI-03 CTI-06 CTI-08 CTI-12A CTI-18A CTI-22 CTI-28 CTI-29A CTI-37 SiO2 71.1300 62.9800 63.7100 61.8600 72.2300 63.6200 67.3200 72.4400 62.8200 70.7300 64.9400 Al2O3 14.8300 17.6000 16.7600 17.3000 12.7200 17.3600 16.1600 14.1300 17.4700 13.8200 15.6500 MnO 0.0540 0.0070 0.0400 0.0600 0.0500 0.0400 0.0400 0.0400 0.0900 0.0700 0.1100 MgO 1.1800 1.6400 1.9900 1.8000 1.0700 1.6100 0.6800 0.3500 2.1600 1.3600 2.0000 CaO 0.4400 0.2100 0.3700 1.0000 1.0800 0.3400 0.1700 0.3800 0.4400 0.3300 0.8900 Na2O 1.9000 1.6400 1.9100 1.4200 2.6200 1.9300 1.5100 3.4500 1.8600 2.7500 2.4500 K2O 5.1700 4.6300 3.9600 4.8900 3.8000 4.6200 5.6700 3.5400 4.3500 4.2300 3.3000 TiO2 0.2860 0.6900 0.7100 0.8400 0.5600 0.7800 0.5000 0.3300 0.8000 0.4400 0.7800 P2O5 0.0370 0.1100 0.1300 0.1800 0.1400 0.1500 0.0800 0.0700 0.1500 0.0900 0.1600 554 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 Formation. The lithogeochemical pattern yielded by the Bau´ Formation is similar to that obtained by Basei et al. (1998b) for Luı´s Alves Microplate basement rocks. Provenance of the sediments inferred from the lithogeochemical data First and foremost, the available geochemical data were treated in order to identify the possible sources of sedi- ments for the Itajaı´ Basin. Even considering the limitations inherent to this approach, e.g. materials coming from tec- tonically distinct settings yielding geochemically similar products (McLennan et al. 1990), our study allowed the definition of several parameters to characterize source areas for the Itajaı´ Group sediments. Taking into account that Th has affinity with differen- tiated continental crustal rocks (Faure 2005) and Sc is abundant in the mantle, Th/Sc ratios higher than 1 reveal a contribution of upper crustal rocks as source areas (Fig. 14a), favoring tectonic settings associated with con- tinental collision, passive margins, and magmatic arcs. In Fig. 14b (SiO2/Al2O3 vs. K2O/Na2O diagram), the prefer- ential involvement of passive margin, continental collision, and subordinately magmatic arc settings is also indicated. In this diagram, the field related to continental collision is the one that best matches with the data corresponding to the upper sequences of the Itajaı´ Basin, whereas the data cor- responding to the basal units are closest to the field related to the passive margin setting. The relationship between La/Th ratios and Hf contents (Fig. 14c) indicates for all the basin units an origin related to a magmatic arc setting with important contribution of sediments associated with a passive margin setting. This suggestion is possible because, due to the low La/Th ratios yielded by the Basin sediments, which indicate Th enrichment in relation to La, a provenance from the erosion of upper crustal rocks can be suggested (Floyd and Leveridge 1987). The comparison between present eNd values and Th/Sc ratios (Fig. 14d) indicates that the source area for the Bau´ Table 1 continued IG-07 CTI-01 CTI-03 CTI-06 CTI-08 CTI-12A CTI-18A CTI-22 CTI-28 CTI-29A CTI-37 Fe2O3 2.2800 5.3800 5.7900 6.0900 3.4100 5.4000 3.9400 2.7300 6.2800 3.5300 6.0200 Loi 2.1800 4.7000 4.4000 4.3000 2.0000 3.9000 3.7000 2.3000 3.3000 2.4000 3.4000 Total 99.4870 99.5870 99.7700 99.7400 99.6800 99.7500 99.7700 99.7600 99.7200 99.7500 99.7000 Ba 446.7000 1045.0000 558.0000 593.0000 656.0000 606.0000 741.0000 650.0000 620.0000 866.0000 610.0000 Ce 46.2000 90.2000 79.4000 92.1000 84.9000 128.5000 92.8000 84.8000 100.5000 71.6000 92.1000 Cl \50 Co 17.2000 49.8000 29.8000 24.3000 98.4000 27.2000 23.5000 38.4000 22.8000 59.3000 23.2000 Cr 16.5000 Cu 8.9000 24.4000 18.0000 30.2000 119.8000 22.8000 11.0000 5.0000 22.7000 4.1000 28.1000 F 1526.5000 Ga 23.6000 25.4000 22.1000 23.2000 17.0000 25.6000 22.9000 19.4000 23.7000 16.9000 20.4000 La 27.8000 38.6000 36.7000 40.6000 38.1000 58.3000 55.7000 36.6000 46.6000 34.0000 42.5000 Nb 29.2000 19.7000 19.4000 23.8000 25.5000 23.8000 27.0000 24.9000 20.1000 16.1000 20.2000 Nd 30.3000 38.1000 35.8000 44.8000 36.7000 55.5000 61.3000 41.9000 45.5000 26.5000 39.4000 Ni 7.2000 67.4000 33.0000 34.1000 20.1000 25.6000 12.5000 23.2000 42.8000 32.2000 35.5000 Pb 9.0000 11.4000 10.2000 17.8000 13.4000 8.5000 9.2000 13.9000 5.0000 8.6000 25.5000 Rb 299.7000 246.1000 205.9000 267.1000 176.3000 256.1000 327.3000 192.8000 206.5000 175.4000 174.3000 S \300 Sc \14 16.0000 15.0000 16.0000 10.0000 15.0000 12.0000 7.0000 17.0000 8.0000 14.0000 Sr 57.4000 76.2000 73.4000 83.1000 157.2000 84.4000 87.5000 89.4000 84.1000 187.1000 164.7000 Th 33.5000 15.1000 15.8000 25.9000 18.4000 19.2000 22.9000 23.0000 19.0000 10.5000 18.6000 U 17.6000 3.5000 3.4000 5.9000 3.9000 5.1000 6.8000 5.1000 4.7000 1.5000 3.7000 V 19.4000 104.0000 96.0000 102.0000 66.0000 102.0000 58.0000 35.0000 112.0000 55.0000 91.0000 Y 52.5000 43.6000 29.3000 46.1000 24.7000 41.9000 70.9000 52.6000 36.0000 15.4000 33.8000 Zn 83.1000 130.0000 86.0000 83.0000 42.0000 86.0000 100.0000 40.0000 86.0000 45.0000 90.0000 Zr 190.4000 155.1000 164.6000 248.4000 264.3000 221.9000 195.8000 194.9000 192.2000 143.2000 245.9000 Sm 8.4271 7.1200 6.4700 9.0300 6.5600 9.7900 13.3300 9.5700 8.2700 4.0500 7.2900 Hf 7.6535 4.7000 5.0000 7.6000 7.5000 6.5000 6.3000 7.5000 6.0000 4.3000 7.1000 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 555 123 Formation sediments (lower sequence) were rocks associ- ated with an old crust, whereas the source area for the Ribeira˜o Carvalhos, Ribeira˜o Neisse, and Ribeira˜o do Bode Formations (upper sequence) were rocks associated with more juvenile, upper crustal rocks. The geochemical studies of the Itajaı´ Basin sedimentary rocks helped characterize the rock types analyzed as min- eralogically immature, represented by wackes, arkoses, and shale. The interpretation of REE data shows that different samples coming from the same units yielded very homo- geneous results, whereas significant differences occur between samples from the continental unit and from the marine units, which attests for the reliability of the pro- posed lithostratigraphic column. As indicated by the present study, the continental col- lision, passive margin, and magmatic arc settings can be suggested as probable settings related to the source areas for the Itajaı´ Basin sediments. It was equally possible to characterize the predominance of sediments coming from an old crust to the basal unit (Bau´ Formation) and from a younger upper crust to the upper units. Isotopic Geochemistry The Nd, Sr, and Pb isotopic study was carried out using the same 23 Itajaı´ Basin stratigraphic sequence samples as for the lithogeochemical studies. For the 143Nd/144Nd and 207Pb/204Pb data (Fig. 15), more radiogenic values corre- spond to the Carvalho, Ribeira˜o Neisse, and Ribeira˜o do Bode Formations, whereas less radiogenic values corre- spond at least to the basal portions of the Bau´ Formation. This fact strengthens the lithostratigraphic organization proposed and supports the suggestion that the sandstone and conglomerate units of the Itajaı´ Basin southern border constitute, as indicated in the geologic map, the same Bau´ Formation described in the northern border, therefore rul- ing out a third unit as suggested by Appi (1990), Appi and Cruz (1991), Rostirolla et al. (1992, 1999); Fonseca (2004) and Guadagnin (2007). Still aiming at identifying the possible source areas for the Itajaı´ Basin sediments, eNd values for samples of the Itajaı´ Basin and the adjacent terranes were calculated for 580 Ma, which is the mean age estimated for the Itajaı´ Fig. 12 Classification of sedimentary rocks according to major element contents. a Geochemical classification of terrigenous sand- stones (Pettijohn et al. 1972); b Chemical classification of sandstones (Floyd and Leveridge 1987); c Classification according to quartz content in the sediment (Floyd and Leveridge 1987); d Geochemical classification of terrigenous sandstones and shale (Herron 1988) 556 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 sedimentation (Basei et al. 2008b). As seen in Fig. 16a, the calculated eNd values for the distinct crustal segments that host the Itajaı´ Basin are organized according their geo- graphic distribution along a NW–SE section. This figure shows the predominance of more negative eNd values in the Bau´ Formation. These values are similar to those obtained for the Santa Catarina Granulitic Complex gneisses and indicate that the source area for the Itajaı´ Basin basal unit are old rocks with long crustal residence, which is in agreement with the other geochemical-isotopic information that points to these gneisses as source for these sediments. On the other hand, the values obtained for the Itajaı´ Basin upper units are similar to those for the Brusque Group metasediments and granites, and even to those for the Floriano´polis Batholith. Comparing the eNd (580) and eSr (580) calculated for the Itajaı´ Basin sediments values, two distinct evolution trends are depicted (dashed arrows in Fig. 16b). The upper units yield approximately constant and slightly negative eNd values and eSr values falling in a large interval. These data plot close to the points corre- sponding to the Brusque Group and Floriano´polis Batho- lith. On the other hand, it is possible to suggest a second trend defined by the Bau´ Formation points that indicates more negative values, closer to the points corresponding to the Luı´s Alves Microplate basement gneisses. Thus, it is again suggested that the possible source areas for the Bau´ Formation are the Santa Catarina Granulitic Complex, the Camboriu´ Complex, and the Brusque Group granites. The same provenance relationships can be inferred from Fig. 16c, where the fields of Nd evolution through time (DePaolo 1988) are presented. The field defined by the Itajaı´ Basin completely overlaps the field defined by the Brusque Group metasediments and partially overlaps with the fields that represent the Santa Catarina Granulitic Complex, the Floriano´polis Batholith, and the Brusque Group granites. The field corresponding to the Camboriu´ Complex model ages is very ample and almost totally overlaps the other fields. Fig. 13 Chondrite-normalized REE distribution (McLennan et al. 1995). a Bau´, b Ribeira˜o Carvalho, c Ribeira˜o Neisse and d Ribeira˜o do Bode Formations, evidencing similar characteristics of samples from the same unit and differences between the Bau´ Formation and the upper units Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 557 123 In conclusion, the isotopic study indicates that the rhythmites and siltites of the Itajaı´ basin upper sequence (Ribeira˜o Carvalho, Ribeira˜o Neisse and Bode Formations) are isotopically homogeneous and but significantly differ- ent from the lower sequence (Bau´ Formation) constituted by the continental sandstones and conglomerates. For the Fig. 14 Geochemical characterization of the provenance areas for the Itajaı´ Group sediments. a Th/Sc diagram (McLennan et al. 1990); b SiO2 ? Al2O3 vs. K2O ? Na2O diagram (McLennan et al. 1990); c La/Th vs. Hf diagram (Floyd and Leveridge 1987); d eNd vs. Th/Sc diagram (McLennan et al. 1990) Fig. 15 207Pb/204Pb and 143Nd/144Nd ratios versus stratigraphic column, characterizing similar isotopic behavior between the upper marine units and differences between these units and the lower continental unit (Bau´ Formation) 558 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 upper sequence, the 143Nd/144Nd and 207Pb/204Pb ratios are always more radiogenic and the eNd values less negative than those yielded by the lower sequence. Model ages (Nd TDM) indicate for all the Basin units a long crustal resi- dence, with values similar to those observed in the Brusque Group, the Floriano´polis Batholith and the Camboriu´ Complex, and subordinately similar to those of the Santa Catarina Granulitic Complex. The isotopic data suggest the continental sandstones and conglomerates of the Bau´ Formation originated by the erosion of the basement, notably the Santa Catarina Granulitic Complex, and for the source area for the rhythmites, sandstones, and siltites of the upper marine pile it was the Brusque Group metavolcano-sedimentary sequence, with contributions from the Floriano´polis Bath- olith. This provenance is confirmed by field data. In the Bau´ Formation, centimeter- to meter-sized gneiss, granite, vein quartz, quartzite, and mylonite clasts, related to the Santa Catarina Granulitic Complex, and rare mica-schist fragments related to the Brusque Group are observed. In the upper units, the provenance associated with the Brus- que Group is observed in thin sections, where the pre- dominance of mica schists fragments is observed. Geochronology The first Itajaı´ Group geochronological results were pre- sented by Macedo et al. (1984) who, on the basis of Rb–Sr isochrons of whole rock fine fractions, placed the sedi- mentation and diagenesis around 560 Ma. Based on Rb–Sr ages and U–Pb (TIMS) zircon analysis, Basei 1985 and Basei et al. (1999) also confined the depositional history of the Itajaı´ Basin to the Neoproterozoic. In disagreement Fig. 16 Isotopic diagrams comparing eNd values for the Itajaı´ Basin and the main regional geologic units (Santa Catarina Granulitic Complex, Camboriu´ Complex, Floriano´polis Batholith, Brusque Group metasediments and intrusive granites), a values of eNd(580) for all regional units organized geographically according to a NW–SE section; b eNd (580) vs. eSr(580) indicating distinct evolutionary trends for upper and lower Itajaı´ Group units Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 559 123 with what was mentioned above, the identification of fossil traces and evidence of Chancelloria led Pain et al. (1997) to place the Itajaı´ sedimentation in the Cambrian, with the oldest possible age at 540 Ma. The deformation that affected the Itajaı´ Basin transformed to quartz-sericite schists by shearing the tuffaceous sediments intercalated with the basal arkosic sandstones yielded a 535 ± 11 Ma (Basei 1985). K–Ar fine fractions analysis (\2 lm) of two siltstone quarries located near Blumenau and Apiu´na show 517 ± 5.0 Ma and 535 ± 11 Ma, respectively Macedo et al. (1984). These two different groups of ages suggest diachronism among the low-temperature events that char- acterize the thermal evolution of the Itajaı´ Basin. A large detrital muscovite crystal of the Bau´ Formation conglomerates (BR 470 highway, in the proximity of Pedra de Amolar) were dated at Georg-August University, Got- tingen, Germany, yielding ages of 1,754 ± 37 Ma and 1,711 ± 39 Ma (Table 2). These ages reinforce the sug- gestion given by the isotopic geochemistry, which points to the Paleoproterozoic Luı´s Alves Microplate gneissic basement as source for the basal continental successions. Similar conclusion was obtained by Guadagnin et al. (2010) who, on the basis of Nd and Pb isotopes, also indicated the importance of the Brusque Group as the main supplier of material for the Itajaı´ Basin (Guadanin et al. 2010). It is interesting to stress that this author showed (main) concentrations of ages around 600 Ma and a second group of ca. 800 Ma for the detrital zircons from the sandy sediments. The first group can be easily attributed to the Brusque Group granitoids, whereas the provenance for the second is still uncertain, once rocks of such age are rare, restricted to the Parapente Suite A-type magmatism (Basei et al. 2008c) of very local expression in the region. For the zircon, SHRIMP ages presented in this paper, mineral separation was by standard gravimetric and iso- dynamic techniques, and the mounting of selected zircons into epoxy resin discs were carried out at the Instituto de Geocieˆncias, Universidade de Sa˜o Paulo. Prior to analysis, cathodo-luminescence (CL) images were obtained to pick sites for analysis. Age determinations were performed at the Beijing Shrimp Center, China and Research School of Earth Sciences, Australia, according to standard procedures (Compston et al. 1984; Williams 1998; Stern 1998; Sir- combe 2000). Data are portrayed in Tera Wasserburg diagrams generated by the program Isoplot/Ex (Ludwig 2001; Table 3). The SHRIMP method was applied to zircons from sample MBAN 1 of the same tuffaceous levels investigated by the Rb–Sr method (Fig. 18a). A weighted mean 206Pb/238U age of 596 ± 10 Ma (Fig. 17a) was obtained for the volcanogenic components and is the best estimate for the beginning of the deposition of the Itajaı´ Group basal portion. In two distinct localities, con- glomerate levels rich in felsic volcanic clasts (Fig. 18b, c) caused much controversy regarding the stratigraphic posi- tion of this felsic magmatism. Geochronologic studies using zircons extracted from centimeter-sized fragments of felsic rock clasts (from both outcrops resulted in 206Pb/238U ages around 609 Ma (Fig. 17b, c). Considering the age errors, these results are coeval with the MBAN 1 tuffa- ceous sample of Bau Formation and with those observed in the Campo Alegre Basin. It represents a volcanic event, whose products were already recycled by erosion, which occurred prior to the felsic magmatism that can be recog- nized in the Itajaı´ Basin and represented by lava domes. No relationship exists between the felsic rich clast conglom- erates and the late, felsic volcanism. The best age for the Itajaı´ Basin felsic volcanism (Apiu´na Formation) was obtained for the dome that occurs south of Apiu´na (Morro do Gravata´), composed of felsic rocks (Fig. 18d) that crosscut the basin units. The 206Pb/238U age of 558 ± 6.6 Ma (Fig. 17d) represents the youngest age possible for the Itajaı´ Group sedimentation. The Subida syenogranite (Fig. 18e), intrusive in the It- ajaı´ Basin sediments, represents the youngest anorogenic granitoid recognized in the region. Its 206Pb/238U age of 520 ± 5.5 Ma (Fig. 17e) is circa 80–60 Ma younger than the A-type granitoids of the Serra do Mar Suite (Kaul 1984, Vlach and Gualda 2007), with which it has always been correlated. Comparative analysis Considering the importance of the recently published paper by Guadagnin et al. (2010) to our manuscript, a brief comparison of both works is carried out here. In a general way, both works make use of stratigraphic, isotopic, and geochronologic information on the Itajaı´ Basin units and present a proposal for the Itajaı´ Basin tectonic evolution, on the basis of their own data. Despite the tools used (LA ICPMS and SHRIMP) led to comparable results, they were applied to distinct materials: detrital zircons (Guadagnin Table 2 K-Ar data of muscovite crystal Field number Geological unit Rock type Mineral K2O (wt%) 40 Ar* [nl/g] STP 40 Ar* (%) Age (Ma) 2 s Error (Ma) BR 24 Bau Fm. Conglomerate Muscovite 10.62 1015.53 99.47 1754.40 37.40 BR 25 Bau Fm. Conglomerate Muscovite 10.69 983.10 99.57 1711.00 39.00 560 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 Table 3 U-Pb SHRIMP analytical data Labels Site U (ppm) Th (ppm) Th/U ± Th/U Pb* (ppm) 204 (ppb) 238U/206Pb ± 38/6 MBAN-1—Siltstone with tuffaceous contribution—Bau´ Formation (corrected using measured 204Pb) 1.1 e,osc,p 285.51 263.56 0.92314 0.02286 34 2 9.83396 0.45643 2.1 e,osc,p 427.97 168.33 0.39332 0.00587 41 4 10.67875 0.52071 3.1 e,osc/hd,p 1203.27 596.74 0.49593 0.01932 113 36 11.03623 0.8314 4.1 e,osc,p 647.1 779.85 1.20515 0.01952 79 4 10.15616 0.43155 6.1 m,osc,p 304 288.41 0.94873 0.03036 33 3 10.64369 0.69462 5.1 e,osc,p 335.43 188.88 0.56309 0.01309 37 0 9.64532 0.59014 9.1 e,h,p 417.45 245.59 0.58831 0.01795 41 9 10.66171 0.70708 7.1 m,hd,p 1453.97 805.87 0.55426 0.07225 142 318 10.99862 1.87312 8.1 m,dd,p 2404.28 1700.25 0.70718 0.03159 115 945 23.08662 2.33238 10.1 e,osc,p 452.49 350.83 0.77534 0.01601 161 5 3.23886 0.17454 CT31 and CT 32—clasts of felsic volcanic—Itajaı´ conglomerates (corrected using measured 204Pb) 31-1.1 m,osc,p 124.58 40.74 0.32702 0.00351 16 6 7.4654 0.18198 31-2.1 m,osc,p,fr 61.81 40.19 0.65021 0.0095 6 0 10.62627 0.36401 31-3.1 e,osc,p,fr 46.95 37.11 0.79047 0.01219 5 2 10.1916 0.31442 31-4.1 m,osc,fr 127.87 97.83 0.76507 0.00808 14 0 10.12963 0.30119 31-5.1 e,osc,p,fr 200.21 146.29 0.73068 0.00689 23 6 9.48737 0.23723 31-6.1 e,osc/h,p 158.01 203.54 1.28816 0.02637 19 5 10.38479 0.4046 31-7.1 e,osc,p 139.27 192.63 1.38316 0.01961 17 5 10.30378 0.26595 31-8.1 m,osc,p,fr 181.77 54.4 0.29927 0.00537 18 2 9.72529 0.34106 31-9.1 e,osc,p,fr 116.64 135.94 1.16549 0.01266 14 2 10.13557 0.26576 31-10.1 e,osc,p 652.68 118.86 0.18211 0.0051 66 17 9.55815 0.75126 32-1.1 m,osc,p 90.66 158.56 1.74904 0.02591 12 1 10.40936 0.3242 32-2.1 e,osc,p,fr 154.2 238.14 1.54432 0.01988 22 1 9.49905 0.32357 32-3.1 e,osc,p 525.74 380.38 0.72351 0.01496 55 2 10.60783 0.414 32-4.1 e,osc,p 34.71 95.64 2.75507 0.06982 6 1 10.25406 0.39509 32-5.1 e,osc,p 321.15 211.03 0.65711 0.00774 37 3 9.44281 0.25074 32-6.1 e,osc,p 328.45 774.78 2.3589 0.03898 51 1 9.91756 0.18395 32-7.1 e,osc,p 184.03 263.48 1.43169 0.05636 23 4 10.11287 0.47959 32-8.1 m,osc/h,p 122.32 128.01 1.04657 0.01497 13 6 10.60417 0.32207 32-9.1 e,osc,p,fr 83.21 82.44 0.99071 0.00934 9 0 10.51133 0.2621 32-10.1 e,osc,p,fr 119.99 62.26 0.51888 0.00564 13 2 10.0703 0.18618 32-12.1 e,osc,p,fr 140.63 141.95 1.00942 0.02793 16 4 10.57562 0.60027 32-15.1 m,osc,p 426.95 187.19 0.43844 0.00398 44 13 9.87361 0.24513 32-17.1 e,osc,p,fr 52.75 78.5 1.48807 0.05665 7 2 10.30806 0.53613 32-18.1 m,osc,p 196.43 139.34 0.70933 0.00856 21 1 10.18354 0.29523 32-13.1 e,osc,p 159.89 178.36 1.11549 0.01255 82 6 2.43406 0.06579 32-14.1 e,osc,p 146.21 41.77 0.2857 0.00524 30 5 4.94949 0.23435 32-11.1 m,osc,p 194.58 64.51 0.33156 0.00359 25 2 7.79364 0.21668 32-16.1 e,osc,p 316.45 160.23 0.50634 0.00341 45 1 7.42249 0.1326 Felsic volcanic—Apiu´na Formation (corrected using measured 204Pb) API-1.1 e,h,p 40.83 29.13 0.71356 0.00871 4 0 11.03503 0.34407 API-2.1 e,h,p 47.7 49.1 1.02937 0.01716 5 0 10.90571 0.34625 API-4.1 e,h,p 83.14 92.11 1.10787 0.0134 9 0 11.00483 0.25872 API-5.1 e,h,p 54.64 34.69 0.63482 0.00933 5 0 11.03706 0.28964 API-6.1 e,h,p 59.91 63.18 1.05445 0.01317 6 1 11.33351 0.32143 API-3.1 e,h,p 34.65 34.36 0.9918 0.01666 4 2 11.2193 0.37863 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 561 123 Table 3 continued Labels Site U (ppm) Th (ppm) Th/U ± Th/U Pb* (ppm) 204 (ppb) 238U/206Pb ± 38/6 Subida Granite (corrected using measured 204Pb) A SUB-1.1 e,osc,p 205.44 125.59 0.6113 0.01425 19 5 11.51098 0.6656 A SUB-2.1 e,osc,p,fr 103.58 77.9 0.75212 0.02191 10 1 11.45334 0.67073 A SUB-3.1 e,osc,p 320.97 160.77 0.5009 0.01819 28 2 11.94992 0.96808 A SUB-4.1 e,osc,p 124.39 92.72 0.74543 0.01704 12 2 11.50705 0.64287 A SUB-5.1 e,osc,p 129.49 101.48 0.78368 0.01671 12 3 11.83973 0.78047 A SUB-6.1 e,osc,p 134.03 78 0.58197 0.01012 12 2 11.49571 0.52939 C SUB-7.1 e,osc,p 98.74 60.86 0.61638 0.01003 9 1 11.78418 0.60083 C SUB-8.1 e,osc,p 148.16 79.29 0.53518 0.00857 13 4 12.17256 0.66257 C SUB-9.1 e,h,p 143.7 99.08 0.68949 0.01244 13 2 12.15569 0.68554 C SUB-10.1 e,osc/hd,p 311.73 304.27 0.97607 0.00899 31 4 11.70655 0.50583 C SUB-11.1 e,hd,p 236.96 250.61 1.05758 0.0131 24 1 11.86382 0.6185 C SUB-12.1 e,hd,eq 553.05 1159.97 2.09741 0.02685 70 1 11.57709 0.56569 NC SUB-2.1 e,osc,p 182.44 151.48 0.83027 0.01486 17 18 11.95746 0.40462 NC SUB-3.1 m,osc,p 143.35 137.69 0.96055 0.01252 14 11 11.8394 0.38049 NC SUB-7.1 m,h,osc 146.48 126.41 0.86301 0.01224 14 17 11.99367 0.37179 NC SUB-1.1 e,osc,p 254.19 162.25 0.6383 0.00898 26 12 10.27715 0.28975 NC SUB-4.1 e,p,og 43.55 37.11 0.85209 0.01207 4 21 12.01428 0.54006 NC SUB-5.1 m,p,osc,h,fr 17.38 40.22 2.31356 0.05317 2 10 12.89028 0.69512 NC SUB-6.1 m,osc,p,fr 71.54 103.04 1.44038 0.02302 8 19 11.79446 0.43072 NC SUB-8.1 m,osc,p 111.72 110.32 0.98743 0.01806 10 12 12.9293 0.44761 Labels 207Pb/206Pb ± 7/6 Age 206/238 ± Age Age (207/235) ± age Age (207/206) ± age Conc (%) MBAN-1—Siltstone with tuffaceous contribution—Bau´ Formation (corrected using measured 204Pb) 1.1 0.05938 0.00185 624.3 27.7 615.0 27.6 580.9 69.3 107.5 2.1 0.0578 0.00123 577.1 27.0 566.1 24.4 522.1 47.3 110.5 3.1 0.05935 0.00144 559.2 40.5 563.3 36.1 580.1 53.7 96.4 4.1 0.06024 0.00127 605.4 24.6 606.8 23.0 612.3 46.2 98.9 6.1 0.05892 0.00188 578.9 36.2 575.9 34.0 564.0 70.9 102.6 5.1 0.06239 0.00118 635.9 37.2 647.4 32.2 687.6 40.8 92.5 9.1 0.05539 0.0019 577.9 36.8 548.5 33.8 428.1 78.5 135.0 7.1 0.06904 0.01105 561.0 92.2 633.1 124.1 899.8 370.8 62.3 8.1 0.05883 0.00685 273.4 27.1 305.8 44.1 561.0 276.3 48.7 10.1 0.10596 0.00089 1734.6 82.5 1733.0 47.3 1731.1 15.5 100.2 CT31 and CT 32—clasts of felsic volcanic—Itajaı´ conglomerates (corrected using measured 204Pb) 31-1.1 0.06128 0.00321 810.4 18.6 768.6 33.2 649.1 116.8 124.8 31-2.1 0.06078 0.00822 579.8 19.0 590.4 66.5 631.6 321.8 91.8 31-3.1 0.05483 0.00591 603.4 17.8 563.5 51.3 405.4 261.2 148.8 31-4.1 0.05884 0.00221 606.9 17.3 597.3 23.2 561.2 84.2 108.1 31-5.1 0.05734 0.00238 646.0 15.4 615.4 23.9 504.5 94.2 128.1 31-6.1 0.0543 0.00236 592.7 22.1 551.2 26.7 383.6 100.6 154.5 31-7.1 0.05331 0.00344 597.1 14.7 546.7 31.1 341.9 153.1 174.7 31-8.1 0.05841 0.0022 630.9 21.1 612.6 25.4 545.3 84.5 115.7 31-9.1 0.05593 0.00235 606.6 15.2 574.5 23.2 449.7 96.0 134.9 31-10.1 0.06426 0.00153 641.4 48.2 666.0 42.4 750.2 51.3 85.5 32-1.1 0.05898 0.00205 591.3 17.6 586.2 22.3 566.2 77.4 104.4 32-2.1 0.06123 0.00158 645.2 21.0 645.7 21.9 647.2 56.5 99.7 562 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 Table 3 continued Labels 207Pb/206Pb ± 7/6 Age 206/238 ± Age Age (207/235) ± age Age (207/206) ± age Conc (%) 32-3.1 0.06014 0.00101 580.7 21.7 586.5 20.0 608.7 36.8 95.4 32-4.1 0.05515 0.00612 599.9 22.1 563.3 54.1 418.2 269.1 143.5 32-5.1 0.06003 0.00111 648.9 16.4 639.1 16.3 604.5 40.5 107.3 32-6.1 0.06141 0.00135 619.3 11.0 626.7 14.4 653.7 47.9 94.7 32-7.1 0.05821 0.00168 607.9 27.6 593.3 26.7 537.8 64.5 113.0 32-8.1 0.05074 0.00287 580.9 16.9 514.5 27.6 229.1 136.3 253.5 32-9.1 0.06014 0.00351 585.8 14.0 590.5 30.1 608.5 131.5 96.3 32-10.1 0.05949 0.00247 610.3 10.8 605.0 21.9 584.9 92.8 104.3 32-12.1 0.05743 0.00382 582.4 31.7 567.5 41.1 508.0 153.2 114.7 32-15.1 0.05969 0.00132 621.9 14.7 615.6 16.4 592.4 48.6 105.0 32-17.1 0.0557 0.00561 596.9 29.7 565.4 52.9 440.5 241.2 135.5 32-18.1 0.05841 0.0013 603.8 16.7 591.6 17.5 545.1 49.3 110.8 32-13.1 0.13726 0.00102 2218.8 50.9 2205.4 26.4 2193.0 13.0 101.2 32-14.1 0.07592 0.00136 1186.3 51.5 1153.7 37.0 1092.9 36.2 108.5 32-11.1 0.06471 0.00101 778.2 20.4 774.8 18.3 765.0 33.1 101.7 32-16.1 0.06553 0.001 814.8 13.7 808.5 14.0 791.3 32.3 103.0 Felsic volcanic—Apiu´na Formation (corrected using measured 204Pb) API-1.1 0.05958 0.00494 559.2 16.7 565.0 40.8 588.2 191.0 95.1 API-2.1 0.05804 0.00288 565.6 17.2 558.7 27.1 531.1 112.4 106.5 API-4.1 0.06 0.00189 560.7 12.6 569.2 18.3 603.5 69.7 92.9 API-5.1 0.05946 0.00307 559.1 14.1 564.1 26.6 584.1 116.1 95.7 API-6.1 0.05621 0.00286 545.1 14.8 529.1 25.6 460.6 117.1 118.3 API-3.1 0.04842 0.00743 550.4 17.8 474.1 63.0 119.8 326.5 459.5 Subida Granite (corrected using measured 204Pb) A SUB-1.1 0.05413 0.00265 537.0 29.9 507.5 32.6 376.5 114.2 142.6 A SUB-2.1 0.05792 0.00302 539.6 30.4 537.2 35.3 526.9 118.4 102.4 A SUB-3.1 0.05594 0.00157 518.1 40.5 505.7 36.1 449.9 63.5 115.2 A SUB-4.1 0.05606 0.00278 537.2 28.9 521.7 32.8 454.6 113.9 118.2 A SUB-5.1 0.05566 0.00382 522.7 33.2 507.4 41.1 439.0 160.5 119.1 A SUB-6.1 0.05566 0.00227 537.7 23.8 519.3 26.9 439.0 93.6 122.5 C SUB-7.1 0.05866 0.00223 525.1 25.8 530.6 28.2 554.4 85.0 94.7 C SUB-8.1 0.05504 0.00205 509.0 26.7 492.0 27.6 413.9 85.7 123.0 C SUB-9.1 0.0556 0.00205 509.6 27.7 496.5 28.3 436.4 84.3 116.8 C SUB-10.1 0.05587 0.00172 528.4 22.0 513.4 22.9 447.2 70.0 118.2 C SUB-11.1 0.05624 0.00102 521.7 26.2 510.7 23.3 461.9 40.5 113.0 C SUB-12.1 0.05807 0.00053 534.1 25.1 533.8 21.3 532.4 20.1 100.3 NC SUB-2.1 0.05635 0.00398 517.8 16.9 508.4 33.4 466.4 164.6 111.0 NC SUB-3.1 0.05608 0.00474 522.7 16.2 510.4 38.5 455.4 199.3 114.8 NC SUB-7.1 0.0528 0.00607 516.3 15.4 481.7 48.2 320.3 284.7 161.2 NC SUB-1.1 0.05521 0.00318 598.6 16.1 562.8 29.5 420.7 133.9 142.3 NC SUB-4.1 0.04581 0.02987 515.4 22.3 429.0 261.7 0.0 0.0 0.0 NC SUB-5.1 0.02593 0.02533 481.7 25.1 248.6 244.4 0.0 0.0 0.0 NC SUB-6.1 0.03829 0.01468 524.6 18.4 375.6 130.4 0.0 0.0 0.0 NC SUB-8.1 0.05128 0.00714 480.3 16.0 442.9 54.4 253.4 292.0 189.5 Laboratory: A = RSES (Australia); C = BSC (China); NC = new data from BSC (China) Labels: x, y; grain number followed by analysis number Grain habit: p prism, anh anhedral, fr fragment Site: e end or edge, m middle, int interior, og overgrowth, c core CL image microstructure, osc oscillatory finescale zoning, rex recrystallised, h homogeneous (d dark, b bright) Data corrected with model Pb of Cumming and Richards (1975) for likely age of rock; all errors are 1 s Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 563 123 Fig. 17 a U–Pb diagram for the tuffaceous levels (sample MBAN 1) intercalated within Bau´ Formation arkosic sandstones (close to the Ribeira˜o do Russo, south of Blumenau). The age obtained from volcanogenic zircons constrains the oldest age limit possible for the sedimentation of the Itajaı´ Group lower unit; b, c U–Pb plots for zircons extracted from felsic volcanic rocks that occurs as sub- decimeter-sized (1–3 cm) in the Itajaı´ Group conglometares (b sample CT31—foot of Morro Grande, left bank of the Itajaı´ Ac¸u river, in the proximity of Apiu´na; c CT32 -thick conglomerate level in the upper Neisse river); d U–Pb diagram for the Morro do Gravata´ felsic volcanic rock. The age obtained constrains the youngest age limit possible for the Itajaı´ Group sedimentation; e U–Pb diagram for the Subida leucosyenogranite. The Cambrian age obtained for this granitoid intrusive in the Itajaı´ Group attests for its anorogenic character and rules out any relationship with the much older Serra do Mar Suite 564 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 et al. 2010) and zircons from igneous rocks (this manu- script), which means that the former results complement the latter. The interpretations based on (Sr, Nd, and Pb) isotopes presented in both papers are very harmonious, indicating that the Dom Feliciano Belt was the main source of material for the Itajaı´ Basin intermediate and upper sedimentary units. The Santa Catarina Granulitic Complex is indicated in both papers as the main candidate as source for the sandstones and conglomerates that composes the basal portion of the Itajaı´ Basin. Therefore, both groups of researchers agree with the classification of the Itajaı´ Basin as a peripheral foreland basin located between the Dom Feliciano Belt to the south and the stable and old terranes to the north. However, some divergences appear regarding the results achieved, when specific points are compared. The ages obtained for tuffs and acid volcanic rocks, which define the limit values for the beginning and the end of the deposition of the Itajaı´ Group sedimentary units, are not concordant. The interval between 596 and 560 Ma presented in this work is older than the 563–549 Ma interval proposed by Gaudagnin et al. (2010). A lower limit of 596 Ma is very close to the age of volcanism observed for the Campo Alegre Basin, which would place the deposition of both basins closer in time. This age is also closer to the well-controlled age of the basal portion of the Camaqua˜ Basin and also is in agree- ment with the recently determined deposition interval for the Arroyo del Soldado Formation in Uruguay (Basei, in preparation). The older age for the beginning of the Itajaı´ Group deposition is compatible with the age of detrital zircons presented by Guadagnin et al. (2010), the younger populations from lower units of the Itajaı´ Basin indicating values around 590 M. Only for the upper unit of the base of siltites, the younger population of detrital zircons yields ages around 563 Ma, both within the interval proposed in this paper. On the other hand, the upper limit for the deposition of the sediments is given by the age of the felsic rocks that affect the Basin sediments. The values for this magmatism were obtained in both papers by dating the Gravata´ dome felsic rocks (south of Apiu´na). The results were 558 and 549 Ma, the older presented in this paper. One of the possible causes for such difference can be attributed to the methods used—LA ICPMS by Guadagnin et al. (2010) and SHRIMP (our work). Other divergent points reside in the implications that result from the different stratigraphic columns presented in Fig. 18 Dated Rocks a Volcanic tuffs associated with sandy levels intercalated with Bau´ Formation conglomerates, south of Blumenau, close to Ribeira˜o do Russo; b Polymictic conglomerate with abundant felsic volcanic rock clasts; c Acid volcanic rock of Apiu´na Formation, Morro do Gravata, south of Apiu´na; d Pink facies of the Subida syenogranite Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 565 123 both works. In our paper, sandstones, conglomerates, and acid tuffs that occur on the southern border of the Itajaı´ Basin are interpreted as a tectonic recurrence of the Bau Formation (lower unit), whereas in Guadagnin et al. (2010) these rocks integrate the upper unit, which would indicate the return of continental conditions that predominated in the beginning of the Itajaı´ Basin evolution. Our stratigra- phy reflects the reading of the geological map presented in this paper, where the modifications introduced by the epi- dermal tectonics, which deforms the basin, characterizes it as a typical example of a thrust and fold belt, and explains the occurrence of the same rocks on both borders. The major deformation of the southern border units, the simi- larities observed in the sedimentary associations of both borders, a compatible isotopic signature (Nd and Pb) and comparable provenance ages, led us to consider that a more correct interpretation is that the rocks from both borders compose a single lithostratigraphic unit. Another point in favor of a proposal that involves the repetition of the lower unit in the southern border is the pattern yielded by detrital zircons presented by Guadagnin et al. (2010), which shows that the provenance of the zir- cons from sandstones and conglomerates attributed by these authors to the upper units is similar to the pattern presented by the lower units that occur on the northern border (Bau Formation) and quite different from the ages observed at the base of the siltite unit, which for us rep- resents the true top of the Itajaı´ Basin, that yields detrital zircon ages restricted to Neoproterozoic values. Conclusions The integrated approach, involving information coming from cartography, lithostratigraphy, structural geology, lithogeochemistry, isotopic geochemistry, and geochro- nology, helped reinforce a new and more detailed inter- pretation for the Itajaı´ Basin tectonic evolution. The proposed lithostratigraphic column assigns the Itajaı´ Group rocks into two major sequences: a basal continental and an upper marine sequence. The lower sequence (the Bau´ Formation) is represented by sandstones and con- glomerates deposited in alluvial and retrograding deltaic fan systems, with facies varying from gravelly and sandy deltaic plain, grading to proximal and distal deltaic front, to prodelta. This sequence grades laterally and toward the top to the upper sequence, constituted by the Ribeira˜o Carvalho Formation rhythmites, which represent the proximal chan- nelized and non-channelized turbiditic facies, the Ribeira˜o Neisse Formation arkosic sandstones, and laminated siltites of the Ribeira˜o do Bode Formation distal turbiditic facies. Based on the similarities between the sandstones and conglomerates that occur in both borders of the Itajaı´ Basin, it is emphasized that these rock types belong to the Bau´ Formation. Besides the similar geochemical-isotopic characteristics, the continuity of these rocks can be checked in the geologic map, which shows the Pedra de Amolar region as the junction between the units of both borders. The proposal that the sandstones with continental characteristics that occur in the southern border represent a third unit is thus ruled out. They in fact represent tectonic repetitions of the basal unit by inverse faulting. The structural studies indicate that the intensity of phase D1 was highest in the SE portion of the Itajaı´ Basin, close to the orogenic belt, with NE–SW axial orientation char- acterized by folds with vertical axial planes close to the northern border, grading to megafolds of inverse flanks, inverse faults and thrusting in the southern portion, with clear tectonic vergence to NW, toward the foreland. Thrusting with a NW direction of transport and preferen- tially affecting the southern border of the Basin is associ- ated with this phase. Phase D2 is restricted to discontinuous folds of large wavelength and approximately N–S axial orientation and slight southwards plunge. The interference of phase D2 on phase D1 is observed at various scales, in the outcrops and in the regional map. These phases are directly related to the deformational phases that followed the metamorphic climax in the Brusque Group. The study of the susceptibility anisotropy and remanent magnetization in two sites of the Gravata rhyolitic dome has shown that these igneous rocks were affected only by the Itajaı´ Basin second deformational phase, which places the first phase between 600 and 560 Ma and the second phase syn- to post-560 Ma. Additionally, this chronology of events indicates, in agreement with the information obtained by magnetostratigraphy, a short period between deposition and deformation phase D1, implying possible syn-tectonic sedimentation (Drukas 2009). The lithogeochemical (major, trace and rare earth elements) and isotopic (Sr, Nd and Pb) analyses of the sedimentary rocks gives support to the proposed lithostrati- graphic column. A very homogeneous behavior is observed in the units that compose the upper sequence, which is at the same time significantly different from that of the lower sequence. Among the various tectonic settings possible, it is proposed that the precursors of the Itajaı´ Group sedi- ments were generated in settings geochemically associated with continental collision, passive margins and magmatic arcs. The probable candidates to source areas of the upper sequence sediments, with marked contribution from the upper crust, are the Brusque Group and the Floriano´polis Batholith. The proposed candidates for the continental and lower units, whose geochemical signature shows consid- erable contribution from reworked old crust, are the terr- anes of the Luis Alves, Sa˜o Miguel, and Camboriu´ Complexes. 566 Int J Earth Sci (Geol Rundsch) (2011) 100:543–569 123 The Itajaı´ Basin is thus interpreted as a peripheral foreland basin directly related to the evolution of the Dom Feliciano Belt. The late-collisional shortening of the fold belt, represented by the Brusque Group, led to the forma- tion of the Itajaı´ Basin by flexural subsidence. The depo- sition of the basal continental sequence started with the erosion of its basement, notably the Santa Catarina Gran- ulitic Complex, with some contribution from the Dom Feliciano Belt. With the increasing proximity of the adja- cent Brusque Group orogenic belt and the Floriano´polis Batholith (magmatic arc), these became the main sources for the sediments of the upper, turbiditic marine sequences. The Itajaı´ Basin and the Brusque Group would then be situated in the lower plate of this passive margin context (Luı´s Alves Microplate southern border), whereas the Floriano´polis Batholith, representing the roots of a Neo- proterozoic magmatic arc, south of the Major Gercino Suture Zone, would be situated in the upper plate in the active margin setting. The generation of the Itajaı´ Basin occurred in a late-collisional setting that followed the ter- mination of the subduction of oceanic crust southeast- wards, around 600 Ma. The lack of records indicating a rift-type opening lead- ing to the development of an oceanic crust implies that the Itajaı´ Basin upper marine units were deposited in an environment similar to a restricted and internal sea. The geologic history of the Itajaı´ Basin must have started around 600 Ma, with the deposition of the lower units on the gneisses of the Luı´s Alves Microplate southern border. Around 560 Ma, the sedimentation ceased, as attested by the Apiu´na Formation felsic magmatism, expressed as dikes and domes crosscutting the whole sedimentary suc- cession. The emplacement of the felsic volcanism after the first deformation phase (Drukas 2009) implies a maximum time interval of 40 Ma for the deposition and the first deformation phase. In the Cambrian, close to 520 Ma, after the stabilization of the Itajaı´ Basin, the intrusion of the anorogenic Subida leucosyenogranite took place. Based on the available radiometric data, it is demonstrated that the deposition of the Itajaı´ Basin was exclusively restricted to the Neoproterozoic. Respecting the differences inherent to the details acquired during their evolutions, the Itajaı´ Basin can be temporally and tectonically correlated with the Camaqua˜ Basin in Rio Grande do Sul (Pain et al. 1990, Fragoso Cesar 1991) and the Arroyo del Soldado/Piria´polis Basin in Uruguay (Gaucher and Sprechmann 1998, Gaucher et al. 1996, 2009). It also presents several tectonic-sedimen- tary characteristics in common with the Nama Basin, its equivalent in Africa (Gresse et al. 1996, Frimmel and Miller 2009, Germs et al. 2009; Guadanin et al. 2010). Acknowledgments The authors are grateful to many colleagues of the Institute of Geosciences—USP for the fruitful discussions. Most of field and laboratory work were supported by grants from the Sa˜o Paulo State Foundation of Research Support (FAPESP—2005/58688-1). References Appi CJ (1991) Ana´lise estratigra´fica da sec¸a˜o metassedimentar do Grupo Itajaı´ no estadode Santa Catarina. 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