SPECIAL ISSUE Development and assessment of protective winter covers for marble statuaries of the Schlossbru¨cke, Berlin (Germany) Joerg Ruedrich • York Rieffel • Stephan Pirskawetz • Holger Alpermann • Ute Joksch • Christoph Gengnagel • Frank Weise • Rudolph Plagge • Jianhua Zhao • Siegfried Siegesmund Received: 25 May 2010 / Accepted: 26 September 2010 / Published online: 19 October 2010  The Author(s) 2010. This article is published with open access at Springerlink.com Abstract The present study documents the results of an inter-disciplinary model project that was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbru¨cke (Berlin). Such a system would need to fulfil the various require- ments for structural stability, aesthetics, climate and prac- tical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. The study is characterised by the use of complex scientific instruments such as special laboratory analysis and numerical simulation tools. The interaction between the environment and the artefacts in connection with the innovative winter covering structures were studied by extensive climatic monitoring. Keywords Marble sculptures  Marble weathering  Winter cover  Climate data  Numerical simulations Introduction The ‘‘Schlossbru¨cke’’, with its monumental sculptural groups made of Carrara marble, is situated in the centre of Berlin on the edge of the Museum Island, a UNESCO world cultural heritage site (Fig. 1a). As a result of their eventful history and exposure to the elements, these sculptures now show considerable signs of damage. The most significant deterioration is caused by thermally induced microcrack formation, which is characteristic of many marble types. For Carrara marbles this decay is expressed as a penetrative granular disintegration. Pro- gressive fabric decohesion leads to a sugar-like crumbling of isolated calcite crystals on the sculpture surfaces. A subordinate relief structure can be observed, which is caused by chemical solution processes close to the surface. In spite of numerous restoration attempts, significant dirt is still observable on the figures. This probably results from the high traffic volume (32,000 vehicles per day) along the boulevard Unter den Linden. Gaseous compounds, solid dirt particles such as soot, fine particles, rubber particles and microbiological colonisation are the main causes of the soiling and the pollution on the surfaces of the statues. Remedial action is essential and necessary for preserving these high quality sculptures as a historical ensemble. On the Schlossbru¨cke the Carrara marble is a particularly vulnerable material, which needs constant maintenance and care to ensure its long-term preservation in an outdoor set- ting. Because of their outstanding artistic, historical and urban design value, the continuous care of the sculptures on ‘‘Unter den Linden’’ is a central concern for conservators. Therefore, the Berlin Federal State Monument Conservation Authority has developed an inspection and maintenance concept, which has been implemented since 2009 and is the only such programme of its size in Germany. J. Ruedrich (&)  S. Siegesmund Geoscience Centre of the University Go¨ttingen, Goldschmidtstr. 3, 37077 Go¨ttingen, Germany e-mail: joerg.ruedrich@geo.uni-goettingen.de Y. Rieffel  U. Joksch Landesdenkmalamt Berlin, Klosterstraße 47, 10179 Berlin, Germany S. Pirskawetz  F. Weise Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin, Germany H. Alpermann  C. Gengnagel Universita¨t der Ku¨nste Berlin, Hardenbergstraße 33, 10623 Berlin, Germany R. Plagge  J. Zhao University of Technology Dresden, Institute of Building Climatology, Zellescher Weg 17, 01069 Dresden, Germany 123 Environ Earth Sci (2011) 63:1823–1848 DOI 10.1007/s12665-010-0765-2 The conservation programme involves covering the Schlossbru¨cke sculptures during the winter months. Empirical findings show that even a traditional wooden cover reduces the damage to the sculptures. No scientific study has been done on the weather-dependent moisture penetration and the climatic conditions in such protective enclosures or on the damages to marbles related to the effect of weathering processes. The bridge sculptures represent a special situation, since they are positioned on the bridge edges with exposure to the flowing water below. Presently no research has taken such a situation into account. This is compounded by the additional goal of making the marble sculptures on the Schlossbru¨cke visible to pedestrians even during the winter. Scientific studies are non-existent in regards to the protective effect of known enclosure systems covering such sculptures. Furthermore, the complicated structural requirement for covers situated on a bridge necessitates new design concepts. The inter-disciplinary model project focuses on the following main steps: • Determining the ‘‘state of the art’’ for winter covers in a national and international context • Defining the requirement profile for an innovative temporary winter cover • Analysing the present condition and the material characteristics of the bridge sculptures • Measuring the climatic conditions • Determining the hygrothermal material properties of natural stone and membranes • Comparative monitoring of the microclimate for the sculptures when exposed to the elements and when protected by temporary wooden covers and the newly designed winter covers • Development of an innovative winter cover, which is suitable for monument conservation • Weathering simulation to test the effectiveness of winter covers • Development of a prototype History of the structure and phases of restoration The Schlossbru¨cke was constructed between 1822 and 1824 in the classical style according to a design by Karl Friedrich Schinkel. Artistically, this is the most beautiful bridge in the city of Berlin (Fig. 1a). The sculpture assemblage was built from 1842 to 1857 and consists of eight groups of figures constructed of Carrara marble by sculptors from the Schadow and Rauch School (Fig. 1b–e). These sculptures, such as the goddesses of antiquity (Nike and Athena) with young heroes were also a part of the design plans of Schinkel. High pedestals of red granite were constructed on the stone pillars of the bridge and serve as the base for the larger-than-life sculptures. Between the pedestals there are wrought iron railings decorated with sea horses, tritons and dolphins. The bridge figures made of Carrara marble is reminiscent of the Angels Bridge in Rome, and represents an outstanding example of the world famous 19th century Berlin sculp- tural school. At that time, sculptures were seen as an important ‘‘official’’ art form, which fulfilled a purpose that was in the public interest. The designers wanted to provide Fig. 1 Schlossbru¨cke, Unter den Linden/Berlin: a Marble statuary ensemble on the southern side; b Sculpture group 1 ‘‘Nike educates the boy in history’’ by Emil Wolff, 1847; c Sculpture group 2 ‘‘Athena teaches the young man how to use a weapon’’ by Hermann Schievelbein, 1853; d Sculpture group 3 ‘‘Athena arms the warrior’’ by Karl Heinrich Mo¨ller, 1851 and e Sculpture group 4 ‘‘Nike crowns the hero’’ by Friedrich Drake, 1853 1824 Environ Earth Sci (2011) 63:1823–1848 123 an everlasting monument to what was noteworthy and noble (Bloch and Grzimek 1978). The figures on the Schlossbru¨cke, with their noble-mindedness and their striving for mythological ideals, were among the most sophisticated sculptural ensembles created in the 19th century. Schinkel wrote about his concept: ‘‘The subject requires much time to implement and a great deal of thought, because the aesthetic quality is the main purpose here’’ (Rave 1948). The Schlossbru¨cke over the Spree Canal provides a traffic link between Unter den Linden—the most important east–west artery in the city centre—and the Lustgarten (Pleasure Garden) and the former Berlin Palace. The Schlossbru¨cke was a counterpart to the Brandenburg Gate in the west and formed the eastern end of the boulevard Unter den Linden, as well as a point of transition to the most important square in the city, the Schlossplatz in front of the former palace. The bridge, with its monumental groups of figures, is a major element of the sculptural programme designed by Schinkel and Rauch. Together with the statues of General Scharnhorst and General Bu¨low in front of and opposite the Neue Wache memorial, they formed part of the city’s main street, which was designed as a victory road or ‘‘Via Triumphalis’’ in a decade long concept, which was unrivalled in Europe. Today, they line a busy inner city street which attracts many tourists, and is a major traffic artery and forms part of the buffer zone around the Museum Island. This circumstance, i.e. the location of the bridge in the city centre and the fact that it has been in the public focus since it was built, is the main reason why the sculpted figures have experienced such a turbulent history and a variety of restoration phases. Directly after the sculptures were assembled in 1855 and 1860, they were treated with a coating of soluble glass as a preventive measure against air pollution. For the same reason, the figures were treated with an emulsion wash roughly every 3 years until 1916. From 1881 to 1891 they were cleaned regularly with Venetian soap (saponified olive oil). As early as 1868, critical remarks were made about the soluble glass coating in correspondences between official bodies, noting that ‘‘in the denser marble statues such as the statues on the Schlossbru¨cke soluble glass cannot penetrate the surface, so it cannot have any effect’’. The sculptures were made of the ‘‘best second grade Carrara marble (Ravacione)’’. Already in 1877, the marbles showed ‘‘the unfavourable effects of the climate’’ due to the air pollution in the city centre (Goralczyk et al. 1988). Therefore, in 1892 it was recommended that the sculptures be replaced by bronze figures (Springer 1981). Up to 1943 no further work on the figures is documented, and a com- parison of historical photographs shows that regular cleaning and care of the statues was no longer carried out. The condition of the figures deteriorated progressively, and in places they were distinctly blackened. In 1943, the sculptures were disassembled to protect them from war damage, and they were stored in wooden coverings at various locations in the western part of the city. The poor storage conditions up to 1969 led to a drastic deterioration in the condition of the sculptures, with parts broken off. At the end of the 1960s, the sculptures were reassembled again and the missing parts were replaced. From 1978, they were stored in a ‘‘lapidarium’’. After the sculptures were returned from West Berlin to the GDR in 1981, compre- hensive scientific studies were carried out on the figures for the first time (Goralczyk 1984). In the subsequent resto- ration, the sculptures were cleaned, small missing parts were replaced with a polyester resin, and then reinforced with silicone resin and treated hydrophobically (Goralczyk et al. 1988). A year after they had been erected at the original location in 1983/84, they were again subjected to partial hydrophobic treatment (Goralczyk et al. 1988). In the course of the planned restoration work in 1992/93, the polyester resin was found to be brittle, and in places there was a distinct lattice of cracks in the marble surface. The silicone resin coating was removed abrasively by micro- blasting, and the cracks were partly sealed with epoxy resin. According to the restoration report, the sculptures were also coated with a solution of Paraloid B72, and several coats were applied in the most porous places. The restoration that began in 2007 was based on a minimal intervention concept. Previous measures were taken into account as far as possible and focused on the compatibility of the processes and the choice of conserving agents. A review of the history of the Schlossbru¨cke figures shows that in the 19th century, the normal practice was already in use for preventing the deterioration of the sculptures by regular cleaning and care, not only with chemical substances. However, this preventive work to preserve the substance of the sculptures was carried out less and less in the 20th century. In view of the many problems associated with the use of chemical conservation agents, especially in the preservation of natural stone, preventive conservation is becoming increasingly important today. This is especially true when significant cost-savings are taken into consideration. Trend-setting examples can be found throughout Europe (Castelli 1997; Accardo et al. 2003), which would be worth copying for the many historically valuable statuaries in Germany. State of the art winter covers for monuments Protective structures for works of art or antique artefacts have a long architectural tradition and have been known in Germany since the 19th century. The archives in the Environ Earth Sci (2011) 63:1823–1848 1825 123 Clemenswerth Hunting Palace (Lower Saxony) show that the stone sculptures, which form part of the structure of the central building were protected by canvas strips as early as 1832. Moreover, winter covers are also documented during the 19th century for the sculptures in the Tiergarten in Berlin and at the Prussian Cultural Trust. The initial motivation for temporary winter covers was primarily to protect cultural works against weathering processes and air pollutants. Very few meaningful microclimate measure- ments are available that relate mainly to sculptural works, which are firmly attached to the building. However, they do show that winter protection covers delay temperature equalisation, and thus reduce the critical peak values for temperature and condensation (Berry 2005; Blum 2002; Egloffstein and Franz 2005; Wo¨lbert 2005). The known winter cover systems can be classified as follows: (i) wooden structures, (ii) frame and membrane (textile/plastic sheeting), (iii) wrapping without a frame, with or without spacers, (iv) acrylic glass or polycarbonate glass and (v) individual structures made of different materials (Fig. 2). Traditional wooden winter covers are known to be one of the oldest methods of winter protection. The technical solutions range from primitive casings without any defined ventilation or a ground anchoring mechanism to technically sophisticated and proven models. More recently, frames made of standard framework mod- ules have also been used and covered with membranes, usually PVC-coated polyester fabric; these coverings are mainly experimental in character (Blum 2002). Directly covering the monuments with an (un)coated fabric, membranes or textiles is a development of the last 13 years. In 1999, at the Institute of Textile and Clothing Technology of the Technical University of Dresden, a winter cover of polyester fabric combined with Teflon was developed (Roedel 2005). Foam spacer elements are attached, which are directly mounted on the artefact and fixed to the building by Velcro fasteners. This system is now used in Saxony and Austria (e.g. Moritzburg Palace, Scho¨nbrunn Palace, Vienna). A covering known as Tyvek is used in the Versailles Palace gardens, Hampton Court Palace in England, the Indianapolis Museum of Art and other places. The material is a paper fleece fibre textile made of thermally-bonded fibres of high-density polyethylene (HDPE). Mechanically, the covering has paper-like characteristics and is not suit- able for use as a load-bearing membrane. However, according to the manufacturer (DuPont), the permeability is good in regards to water vapour. Between 1997 and 2003, a research project (Blum 2002) dealt with winter coverings for monuments of natural stone. The aim of the project was to develop a light-weight cover, which would be easy to assemble and visually attractive. The study focused on the palaces of Cle- menswerth (Lower Saxony) and Weikersheim (Baden- Wu¨rtemberg). During the research programme ‘‘Assessing the performance of protective winter covers for outdoor marble statuary—pilot investigation’’ (Berry 2005), vari- ous membranes were tested, such as Tyvek, polyurethane- coated nylon and polyester fabric with and without polyester insulation as well as a proprietary development consisting of three layers with insulation (Cliveden Winter Cover). Fig. 2 Different covering systems: a Rheinsberg Castle, typical wood board covering, which has been used in this form since 1930 by the Prussian Palaces and Gardens Foundation; b, c Moritzburg Palace, winter protection with a textile covering of polyester fabric and Teflon; d Salzburg, horse trough with polycarbonate winter cover 1826 Environ Earth Sci (2011) 63:1823–1848 123 Structures made of acrylic glass or polycarbonate glass are mainly used for prominent objects to ensure that they remain visible during the winter months. Sunlight enters the structures almost unhindered. This means that the light not only shines on one side of the object, but also that a greenhouse effect is created, which leads to increased condensation and a lack of ventilation. Therefore, these covers are detrimental to the natural stone. In 2009, a patented multi-layer light-weight housing was developed with walls manufactured as a sandwich structure (Schmidt 2009, 2010). The inner layer consists of foam; the outer layer is made of fabric-reinforced plastic with a UV protective coating (http://www.ciccum.de/ciccum1.htm). At present, no systematic scientific study has been under- taken on the effects of the different covering systems and the associated effects on the weathering processes for marble. Marble and its state of preservation Macroscopic damage phenomenon Due to their long exposition time and diverse history, the marble sculptures show various types of decay phenome- non (Fig. 3). The macroscopic damages are characterised by a few replacements of filigree body parts, e.g. substi- tutions for fingers, hands, wing parts, etc. Moreover, the original marble locally shows a pronounced surface roughness, which can be traced back to chemical solution processes. Sporadically, a sugar-like crumbling can be observed. In these parts, the marble fabric is strongly deteriorated (Fig. 4a). However, in most cases the back- weathering is moderate. Only one sculpture group repre- sents an exception. For this marble sculpture group, networking cracks like a craquelling can be observed. In areas of strong fabric decay, macrocracks and material break-outs are also common. Most of the damages can be traced back to marble weathering. Mechanical damages are also common, which can be traced to the incorrect trans- port and storage during and after the confusion generated by World War II. Marble weathering Thermal dilatation processes are responsible for the initial degradation of marbles. Kessler (1919) found that repeated heating of marbles may lead to permanent dilatations due to microfracturing (Fig. 4b, c) and that thermally treated marbles show a remarkable non-reversible change in length especially during the first heating cycle (Zezza et al. 1985; Sage 1988; Siegesmund et al. 2000). Even small temper- ature changes of 20–50C may result in damage (Battaglia et al. 1993). Marble has a very simple mineralogical composition. It consists of calcite and/or dolomite with other accessory phases (e.g. quartz, mica, etc.). Calcite and dolomite exhibit a pronounced anisotropy of the ther- mal expansion coefficient at different crystallographic Fig. 3 Main macroscopic damage phenomenon: a intensive cracking, b replacements, c complex cracking with break-outs and d new distinct crack growth starting from an older replacement Environ Earth Sci (2011) 63:1823–1848 1827 123 directions (Kleber 1959) leading to stresses within the sample during heating (Fig. 5a–d). When these stresses exceed the threshold of cohesion, a thermally induced deterioration is observed (cf. Sage 1988; Weiss et al. 2002, 2004). The rock fabric, which includes grain size, grain aspect ratios, grain shape preferred orientation, lattice preferred orientation (texture) and the microcrack popula- tions, significantly controls the material’s behaviour during thermal stress (e.g. Siegesmund et al. 2008; Shushakova et al. 2010). The increase of residual strain and thus the progressive deterioration of marbles stops after a few heating cycles if moisture is absent (e.g. Sage 1988 or Koch and Sieges- mund 2004). Therefore, Winkler (1996) pointed out the importance of moisture in the weathering process of marbles. Detailed measurements of progressive residual strain on Carrara marbles were performed by Koch and Siegesmund (2004). Five dry cycles up to 90C were followed by additional wet cycles on drilling cores with a sample size of [15 mm 9 50 mm. The wet cycles were carried out in such a way that at the end of the heating stage, the samples in the climate chamber were run until totally dry. The result was an increasing residual strain, which did not stop during the experiments (Fig. 5e). This thermo-hygric process results in progressive crack opening (Siegesmund et al. 2007, 2008). To acquire more information about the deterioration by cooling, comparable Carrara samples were treated in the following way. Four dry cooling cycles up to -14C were followed by 10 additional wet cycles in drilling cores with Fig. 4 Microphotographs of deteriorated Carrara marble: a CT-image of a drill core shows the strong microcrack deterioration parallel to the surface (sample from figure group 4); b, c SEM-images (fractography) shows the penetrative granular disintegration along grain boundaries of the calcite single crystals (reference sample) Fig. 5 Marble deterioration: a Thermal dilatation coefficients of the calcite single crystal with respect to the crystallographic orientations, b schematic illustration of a calcite crystal at initial conditions, c volume change by heating and d by cooling, e progressive residual strain under dry and following wet conditions induced by heating and f by cooling measurements 1828 Environ Earth Sci (2011) 63:1823–1848 123 the same sample size. For the first dry cooling cycle a strong residual strain also occurs (Fig. 5f). In the experi- ment the residual strength is the half compared to heating. But also the absolute temperature difference was the half. Thus, in the initial dry thermal deterioration the residual strain is a function of the absolute temperature difference. For the further dry loading cycles a slight increase of residual strain is detectable, which is also comparable to the heating situation. In contrast to the dry behaviour, the cooling of wet samples only shows a slight increase of residual strain. This implies that for the investigated sam- ples freeze–thaw action only plays a secondary part. Other experiments have shown that if cracks are open to a certain extent, the capillary water uptake increases and weathering processes like chemical solution or freeze–thaw action plays a more important role for marble decay (Ondrasina et al. 2002; Ruedrich 2003). Rock fabrics The samples for fabric and petrophysical investigations were drilled from sculpture 2 and 3 on the south side of the bridge. Drill cores from both sculptures with a diameter of 40 mm were obtained from the plinth. The macroscopic fabrics of the marbles are more or less characteristic for Carrara material. They are bright white in colour and contain irregular dark grey veins. The veins are folded and show a streak-like distortion. They usually range in width from 0.3 to 1.0 cm. A preferred orientation of the veins is not clearly detectable. The samples show a medium decay in the form of granular disintegration. The investigated Carrara marbles show a nearly equi- granular polygonal grain fabric (Fig. 6a, d) with straight grain boundaries and frequently 120 triple-point junctions. The grain size in the white areas is between 20 and 600 lm, whereas the maximum is about 180 lm (Fig. 6b, e). In the XY- and the XZ-plane of the samples, a preferred grain boundary orientation (subparallel Y-direction) can be observed (Fig. 6c, f). The grey veins are fine grained (average grain size = 50 lm) and the grains have a very strong undulose extinction. Grain boundaries are interlobated and a high amount of fluid inclusions or graphite occurs, which probably causes the grey colour of the veins. Pore space properties The porosity and pore radii distributions were analysed in order to obtain more information about the preservation state of the marbles. Hydrostatic weighing was used to measure the porosity. Both samples show an effective porosity of about 0.5 vol% (Fig. 7). In comparison with fresh marbles which show porosities around 0.2 vol% (e.g. Weiss et al. 2000), the pore space volume is significantly enlarged. The pore size distribution of the samples was deter- mined by using mercury porosimetry (cf. van Brakel et al. 1981). The pattern of the pore radii spectrum exhibit for both investigated marbles an unequal porous bimodal distribution of pore sizes (Fig. 7). The main maximum is marginally below 0.01 lm, and thus in the domain of mi- cropores where no capillary activity is present. In contrast, Fig. 6 Fabric properties of the investigated marbles: a, d grain fabric; b, e grain size and c, f preferred orientation of grain boundaries, a–c drilling core 1 (sculpture 2) and d–f drilling core 4 (sculpture 3) Environ Earth Sci (2011) 63:1823–1848 1829 123 the second sub-maximum is about 0.1 lm, and therefore in the pore space range of capillary soaking. In the present state of preservation, the capillary water uptake is assumed to be relatively low (cf. Ruedrich 2003). With progressive crack opening caused by further weathering, the water uptake should also increase, and thus the chemical solution at the internal surfaces of the marbles will increase. Magnitude of fabric disintegration Ultrasonic velocities were increasingly used as a non- destructive tool for assessing the structural disintegration of the marbles. The basic principle is that the decrease of compressional waves (Vp) is correlated with progressive crack growth during weathering. Ko¨hler (1991) presented a Vp damage classification (Table 1) based on numerous measurements at sculptures made of Carrara marble. In order to analyse the fabric cohesion, the Vp was measured in the drill cores. The transient times of ultrasonic pulses (piezoceramic transducers, resonant frequency of 350 kHz, point coupling) were measured using the transmission technique (Birch 1960, 1961). The measurements were carried out in two directions (X,Y) perpendicular to the length axis of the drill core. To simulate the field condition the analysis was performed under dry and completely water-saturated sample conditions. The measuring points were defined for different distances along a depth profile (Fig. 8) in order to obtain information about the preser- vation state from the surface to the rocks interior. The measured ultrasonic velocities at dry sample con- ditions are between 3.25 and 4.50 km/s (Fig. 8a, b). The mean value is around 3.90 km/s, which can be designated as increasingly porous after the classification by Ko¨hler (1991). At water-saturated conditions, Vp varies between 5.80 and 6.60 km/s and are characteristic for Carrara marbles (Fig. 8a, b). Water-saturated weathered marbles are known to show nearly the same Vp properties as the original values with fresh conditions (e.g. Weiss et al. 2000; Siegesmund et al. 2009). The Vp distribution along the depth profile at dry sample conditions for drill core 2 exhibits conspicuous changes. Near the surface, a relatively high Vp of 4.75 km/s is detectable. At about 17 mm, depth Vp is strongly reduced to 3.60 km/s and increases with depth up to 4.00 km/s. The same pattern can be determined for the second drill core but the Vp changes are less pronounced. Commonly Vp should be the lowest near the surface because weathering intensity is highest at the surface. This indicates a sec- ondary fabric stabilisation of areas close to the surface. The cause could be chemical solution/precipitation reactions or former consolidation works. Compressional wave velocities during the drying experiments are given in Fig. 8c, d. The results show a strong correlation between water saturation degree of the marble pore space and the compressional wave velocities. Beneath a saturation degree of about 40%, the influence of water on Vp is strongly reduced. Ultrasonic tomography (on-site analysis) To detect the damage of the rocks interior, detailed two- dimensional tomographic investigations with ultrasound (250 kHz) were carried out on-site. The results of sculpture group 3 are given in Fig. 9. Measuring points are defined in order to achieve a tight grid of measuring tracks for each profile (Fig. 9a–c). The analyses were carried out at three different horizontal slices at the shoulder (profile I), the thigh (profile II) and the shackle (profile III) of the warrior. For better signal transmission, a special clay was used between the transmitter and the marble. The calculations of the tomographic inversions were compiled with the pro- gramme Migratom (cf. Jackson and Tweeton 1994; Rued- rich et al. 2001; Siegesmund et al. 2009). Fig. 7 Pore radii distribution of a sample from sculpture 2 and b sculpture 3 Table 1 Structural damage classification on the basis of Vp for marble from Ko¨hler (1991) Damage class Vp (km/s) Condition Porosity (vol%) Class 0 [5.0 Fresh \0.5 Class I 3.0–5.0 Increasingly porous 1.3–0.5 Class II 2.0–3.0 Sugar-like disintegration 3.0–1.3 Class III 1.5–2.0 Fragile 5.3–3.0 Class IV \1.5 Crumbling rock [5 1830 Environ Earth Sci (2011) 63:1823–1848 123 For the chosen example the ultrasonic velocities in the tomographic profiles vary between 2.0 and 4.1 km/s. The lowest velocities are observable for profile III between 2.0 and 2.8 km/s. This indicates that the smaller sculpture parts are strongly deteriorated than the voluminous parts, and is in agreement with the macroscopic damage observations. The velocity distribution patterns are different for all profiles (Fig. 9d–f). For profile I and III, the areas of lower velocity are exposition-controlled. More deteriorated parts are non-protected by other sculpture parts, and thus subjected to stronger weathering. Profile III shows a low velocity channel from southeast to northwest. Since the Vp differences are low, this velocity pattern may only be affected by the marble anisotropy. Ruedrich (2003) found an increasing Vp anisotropy up to 30% for Carrara marbles with progressive fabric decay. Comparable ultrasonic velocities in intensity as well as in its distribution pattern are observable for all sculpture groups of the Schlossbru¨cke. Acquisition of the climatic conditions with or without a covering Although the protection of art works by winter covers has a long tradition, there are only a few studies documenting the effect of such covers (Berry 2005; Blum 2002; Egloffstein and Franz 2005; Wo¨lbert 2005). Therefore, the climate monitoring system was designed to create a dense database for the numerical prediction of the effect of protective systems, and to compare the given climate conditions to the known factors influencing the marble deterioration. In December 2007, the climate monitoring system started operation in order to study the influence of the microclimate on marble sculptures on the Schlossbru¨cke in Berlin. The first system was installed at sculpture 2 (Fig. 1), followed in 2008 by two systems each at sculptures 1 and 3. General local climate data like air temperature, relative humidity, wind speed and global radiation as well as surface temperatures and surface humidity at the sculptures are measured and stored every 15 min. In December 2008, additional marble reference samples with integrated temperature sensors were attached directly to the sculptures. Temperature distri- butions can thus be collected inside a marble without damaging the sculptures. The monitoring system has been designed for long-term operation and is still being maintained. Combined with the hygric and thermal characteristics of the marble, the mea- sured data are a valuable foundation for simulating the effectiveness of different protection systems. Fig. 8 a, b Ultrasonic wave velocities (Vp) of drilling core 1 (sculpture group 2) and 4 (sculpture group 3) in a depth profile at dry and water- saturated conditions. c, d Correlation between Vp and water saturation, e drill cores Environ Earth Sci (2011) 63:1823–1848 1831 123 Effect of the local climate on weathered sculptures The recording of the local climatic conditions on the Schlossbru¨cke comprise more than 2 years of data. Figure 10 shows the air temperatures measured during this time span. To verify the reliability of the data, they have been compared to data from the weather station Berlin–Tempelhof, which is operated by the German Meteorological Service (2010). This comparison shows a good correlation but the temperatures measured on the Schlossbru¨cke tend to be little higher than the temperatures at Tempelhof. Especially the lowest tem- peratures at Tempelhof are lower than the lowest tempera- tures on the Schlossbru¨cke. The reason is a distinctive microclimate in the high-density area of the city centre and the special location over the river Spree. This is confirmed by long-term averages of the temperatures in the period from 1961 to 1990 at both locations. In Tempelhof, the average temperature ranges from 9 to 9.5C, whereas the average temperature at the Schlossbru¨cke ranges from 10 to 10.5C. The main wind direction is southwest. The climate data recorded until now show that the temperatures of the sculptures range from -20C in winter up to 40C in summer. This represents a temperature span of about 60C. In combination with wet and dry cycles, this may cause marble deterioration. The temperature of the sculptures is determined by the temperature of the sur- rounding air and by the global radiation. The humidity of the material depends on the relative humidity of the air. In addition, the infiltration of liquid water from rain or dew increases the humidity of the materials. The influence of direct sunlight on the surface temper- ature of the marble can be verified by comparing the Fig. 9 Tomographic reconstruction of three profiles for sculpture group 3: a–c transmitter/receiver positions and associated ray paths, d–f tomographic inversions 1832 Environ Earth Sci (2011) 63:1823–1848 123 temperatures of the massive parts of the sculptures on the south and north side. Figures 11a and 12a show examples for measured surface temperatures on sculpture 2 in com- parison to the air temperature. In winter, the highest tem- peratures were measured on the south side of the sculptures, where the influence of direct solar radiation is the highest. In the period shown in Fig. 12a, the differences of the surface temperatures on the north and on the south side of the unprotected sculpture are lower than 4C. Without direct solar radiation, no temperature difference can be seen. Moreover, the increase of the surface tem- perature by solar radiation in the summer is not very high. In the period investigated, the highest temperatures were measured on the west side. The maximum temperature difference between the north and the south side is below 6C. The maximum surface temperature difference since the beginning of the measurements is below 10C. The main reason for the low influence of direct solar radiation on surface temperature is the high reflectivity of the bright marble. A further reason could be a relatively high thermal conductivity and the high density of the material. The heat which develops on the surface is transferred and spread inside the material. The most interesting observation of solar radiation and temperature occurred on the 3rd of July 2008. The air temperature on this sunny day as well as the surface tem- perature increased from about 20C in the morning to about 30C in the afternoon. At the same time, the surface tem- perature on the west side increased from 20 to 35C. Around 12:30 pm, overcast conditions occur for 1 h, and therefore the surface temperature on the west side tempo- rarily decreased to 30C. Beginning at 3:30 pm, the tem- perature on the west side suddenly decreased to 27C within 1 h. At the same time, the temperature on the north side fell to 20C. The reason is a sudden rain shower. After the rain, the temperature again reached up to 30C and the surfaces dried. Events like this are significant for marble deterioration. On the afternoon of the 4th of July 2009 it started raining again, but due to the temporarily overcast condition, the temperature drop is less abrupt. Figure 11a shows the temperature profile measured on a reference sample with one exposed surface oriented to the Fig. 10 Air temperature at the Schlossbru¨cke Berlin during the period of the project Fig. 11 Influence of the microclimate on the marble temperatures in summer: a temperatures measured at sculpture group 2, b temperatures in a depth profile from a reference sample with one exposed surface, c solar radiation and rainfall and d exposed reference sample with temperature sensors at different depths Environ Earth Sci (2011) 63:1823–1848 1833 123 southwest (Fig. 11d). The other surfaces of the reference sample exhibit a heat insulation in order to evaluate the thermal behaviour of massive sculpture parts. As expected, the development of the surface temperature in general equates to the temperature profile measured on the west side of sculpture 2. Due to the high thermal conductivity of the marble, the temperature at a depth of 1 cm follows the surface temperature fast. Higher surface temperatures only occur in times of direct solar radiation. In the period from the 1st to 6th July 2009, the highest temperature difference between the surface and the backside of the sample is about 5C (Fig. 11b). If the environmental temperatures rise, the surface temperature is always the highest. The temperature profile is inverted, if the ambient temperature drops. Effect of the conventional wooden cover during the winter A wooden cover was erected in January 2008 around sculpture 2 and it was removed in May 2008. The cover was open below and it had wide vents under the roof. Sculpture 1 wasn’t covered in this period. Figure 12 shows a comparison of the microclimate on sculptures 1 and 2 during 5 days in March 2008. Due to the wide vents in the wooden cover, the air temperature effect around the sculpture is insignificant. However, the amplitudes of the surface temperature are slightly lowered compared to the temperatures on sculpture 1. Inside the cover, there is no difference between the surface temperatures on the south side and the west side of the sculpture. Furthermore, inside the cover the surface temperatures follow the ambient air temperature more slowly, and therefore a temperature difference of up to 3C occurs. The reason might be the reduced heat transfer due to the lower wind speed. The dew point inside the cover during the period shown in Fig. 12 is just a little lower than the surface temperature. During the entire time when the sculpture was protected, the surface temperatures fell below the dew point for a period of 430 h. This equates to about 13% of the 133 days when the sculpture was covered. At the same time, precipitation occurred on 51 days. Unfortunately during this time period, the dew point temperature outside the cover was not being measured. It is probable, however, that the effect of the wooden cover is limited as a protec- tion against rainfall. Effect of the modern cover with a PVC membrane during the winter Since February 2009, a steel framework with a white PVC membrane has been erected around sculpture 1 and is still being used on this figure. The area below the cover is open and has no additional vents. This protective cover shows a similar climatic effect in the interior as the wooden cover. Surface temperatures on the north and on the south sides show no difference, which is similar to the interior climate of the wooden cover. This is caused by the shadowing effect of the cover. During a sunlit day, the air temperature inside the cover increases slightly. In the winter, the weather station is in the shade cast by the modern cover, and thus the solar radiation shown in Fig. 13c does not represent the direct solar radiation. However, the data from the DWD show that the 19th and 20th of December 2009 were both the days in which the sun shone in Berlin. Fig. 12 Influence of climate and the wooden cover on the marble temperatures in winter 1834 Environ Earth Sci (2011) 63:1823–1848 123 Inside the membrane cover, the surface temperatures can also fall below the dew point. In Fig. 13, these periods are represented by the pale blue boxes. If the temperatures are below the freezing point, this leads to hoarfrost on the sculp- tures. Not until the temperatures rise above the freezing point does the surface of the marble get wet. This occurred on the morning of the 22nd of December 2009 as shown in Fig. 13. The surface temperature is still below the dew point. During the period from October 2009 to February 2010, the surface temperature of the unprotected sculpture 2 is below the dew point of the ambient air in an overall time period of 960 h. This equates to about 27% of the entire period of 147 days. Inside the modern cover, the surface temperature of sculpture 1 is just 694 h below the dew point. This equates to about 20% of the considered time. Precipitation occurred on 63 days in this period. The time of direct infiltration of water to the sculpture is shortened by the modern cover, although an intensive air exchange is possible through the opening below. In addi- tion, moisture infiltration can be reduced by closing the opening below the cover. Moreover, more dust accumu- lates on the sculptures inside the cover than when the sculptures are freely exposed. This is another important reason for closing and sealing the cover completely. Numerical simulation of microclimate with or without a covering Numerical simulation of heat and moisture transport phe- nomena has become a widely accepted and commonly applied investigation method (Galbraith 1992; Grunewald 1997; Kuenzel 1994). The application allows the evalua- tion of possible environmental effects on resultant damage processes to the marble sculptures. The analysis of the climate inside the cover that affects the marble sculpture requires the implementation of air transport induced by air pressure differences. Bear and Bachmat (1991) give a general physical and theoretical description of the ther- modynamic principle. Grunewald (1997) introduced a physical model of couplet Heat Air and Moisture transport (HAM), which fulfils the simulation requirement and is used in the present paper. The transport processes and transmission between solid, liquid and gaseous phases are given for a multiphase system in porous materials. The actual code used for the simulations is called DELPHIN 5.6, as described in Nicolai et al. (2008a, b). The accuracy and reliability of the numerical results highly depends on the quality of the input data, and thus it requires the setting of highly defined boundary conditions (Hagentoft et al. 2004). Since the microclimate situation at the marble sculptures with or without a covering has been measured, the boundary conditions are also well known for specific positions at the different sculptures. Hygrothermal material properties of the investigated Carrara marbles The required hygrothermal material properties have been analysed by laboratory techniques and are supported by a few in situ measurements. The hygrothermal characterisa- tion of the marble is a difficult task. Having a very low porosity, moisture transport and moisture storage, the determination of characteristic material parameters Fig. 13 Influence of climate and the cover with PCV membrane on the marble temperatures in winter. The pale blue boxes represent periods where the surface temperature falls below the dew point Environ Earth Sci (2011) 63:1823–1848 1835 123 becomes highly time consuming and requires high preci- sion techniques and methods. A general description of the experimental methods used is given by Plagge (2005, 2007). A selection of the basic hygrothermal material properties, including the variation of a Carrara marble is listed in Table 2. The application of numerical simulation software requires complete material functions, able to describe vapour permeability, the liquid conductivity, both func- tions of moisture content, and the moisture storage func- tion, specifying the relationship between moisture content and moisture potential. This leads to the task of material modelling, which provides a set of material functions with experimentally determined coefficients. The procedure used is described by Scheffler and Plagge (2009). Since a complete characterisation requires numerous samples of different size, the valuable original Carrara marble of the sculptures cannot be sampled in the required amount. Based on mineralogical examinations, suitable Carrara marble from the original quarry deposit in Italy has been selected for measurement, representing the inner parts of the sculptures. Only two specimens from a previous sampling (see Fig. 8) could be used for experimental analysis, representing the marble surface of the sculptures. Due to climate induced deterioration, followed by some previous conservation treatments, the marble surface shows different physical properties. The hygrothermal material properties of both marble types are shown in Fig. 14. The results show remarkable differences between the deteriorated parts of the marble sculpture and the fresh marble sample. The comparison of sorption isotherm and moisture retention indicates an increase of large pores for the weathered marble, whereas the quantity of small pores decreases from 0.0075 to 0.0020 m3/m3 by 75%. The increase of moisture transport of around 80% relative humidity can be explained by perfect penetrative granular disintegration along the grain boundaries of planar pores in the calcite crystals. The improvement shows a *50 times greater transport rate. The increase of large pores from 0.004 to 0.008 m3/m3 leads to a higher moisture transport rate, which is *103–104 times greater at a higher degree of saturation. Water vapour permeability increases by 15%. Simulation of free exposed sculptures Due to the complex geometry of an original sculpture, it is not possible to simulate all the details. The calculation effort would be too large. Thus, the sculpture is represented by the massive torso and the strong legs. The arms and head show smaller diameters and have a more complex geometry. The idealised shape of a sculpture is depicted in Fig. 15. Figure 16 shows the results for an exposed marble sculpture, where the yearly fluctuation of climatic con- ditions influences the hygric status of the marble. The data are given for the 15th of each respective month. During the spring and summer seasons, dry conditions dominate. After the duration of a long drying period (see May), the surface layer has dried. Occasional precipita- tion leads to periodic wetting of the surface regions, but moisture can continuously evaporate. The intensity of the rainfall and humidity causes the moisture to penetrate into the marble at a certain depth, which fluctuates between a few mm up to 35 mm. During the colder sea- sons in autumn and winter, the sculpture is dominantly wetted, leading to higher moisture contents and an increasing penetration depth. Large differences also exist between different marble thicknesses. Thinner parts of the sculpture, like the extremities, show regular water saturation, whereas the massive body never gets fully moistened. During colder periods, drying conditions are poor whereby moisture can penetrate the marble sculpture up to a depth of 200 mm. Since marble has a large thermal conductivity, the transmission of temperature is quite fast. The simulation results indicate that the outer temperature conditions can easily penetrate the marble. Thus, nearly all marble sur- faces show the same temperature behaviour. The surface temperature is independent from the diameter of the sculpture geometry. Only at greater depths within the sculpture, daily or weekly changes of temperature are observable. The temperature difference between the outer layer and the core marble never exceeds a maximum of 8C. For the actual cases, the temperature differs between 2 and 4C. Table 2 Basic hygrothermal material parameters of Carrara marble (total sampling collective n = 125 specimen) Parameter Symbol Unit Mean Std Dev Min Max Bulk density q kg/m3 2,614 17.5 2,515 2,644 Specific heat capacity c J/kgK 728 18.8 687.9 766.7 Thermal conductivity kdry W/mK 2.27 0.103 2.03 2.49 Total porosity Opor m3/m3 0.0137 0.0066 0.0024 0.0509 Capillary saturation Ocap m3/m3 0.0101 0.0023 0.0085 0.0117 Water uptake coefficient Aw kg/m2s05 0.0015 0.00028 0.0013 0.0017 Water vapour diffusion ldry – 353 243 75 737 1836 Environ Earth Sci (2011) 63:1823–1848 123 Simulation of wooden shelter as a protective winter cover When developing a new and innovative covering system, it is important to evaluate conventional and multiple used systems. In this respect, two wooden winter covers were compared: 1. an airtight design with reduced air circulation and 2. an air-ventilated design with defined openings at the bottom and top of the housing. To simulate air circulation within the housing around the marble sculpture, different air exchange rates are used. The velocity of air movement is defined by the pressure dif- ference between upper und lower openings. In the present paper, the differences in pressure used to lie between 0.5 and 5.0 Pa. When wind blows around the protective shelter chimney effects are created, where air passing the upper opening generates air suction through the lower opening. In this manner, air is continuously flowing along the marble sculpture (see Fig. 17). The pressure between the upper and lower entry varies between 0.5 and 5.0 Pa. In Figs. 18 and 19, different wooden winter covers are compared. To understand the operation of the wooden shelter on the marble sculpture, the mean moisture content of the statue is shown. Relatively airtight constructions lead Fig. 14 Hygrothermal material property function on samples of Carrara marble and the sculpture Fig. 15 Idealised simulation scheme of a marble sculpture Environ Earth Sci (2011) 63:1823–1848 1837 123 to smaller moisture contents in the marble. Assuming hygric and thermal dilatation is proportional to the ampli- tude of moisture and temperature, the relatively airtight wooden shelter is preferred. The variation of moisture for non- and low-circulating systems is 3–5 kg moisture, whereas air-ventilated systems deliver a variation of 2–7 kg. The daily amplitudes are much larger, leading to substantial dilatation in the marble. In spring time, the daily fluctuations are extreme. During sunny days, warm outside air is laden with moisture and passes over the cold sculpture. This results in surface condensation and a moistening of the marble. Since the conditions for con- densation have a long duration, the moistening is a domi- nant process in February and March. In the case of an airtight and non-ventilated shelter, only little moisture enters the protective winter cover. Increas- ing temperature within the shelter leads to a decrease of relative humidity in the air allowing the marble to dry. Not every wooden shelter is beneficial, as this investigation has shown. Fig. 16 Moisture distribution within the idealised sculpture influenced by climatic conditions during the year Fig. 17 Simulation scheme of the idealised sculpture having a wooden shelter as a protective winter cover. The air ventilation openings can be opened and closed Fig. 18 Total moisture content of the idealised marble sculpture having wooden protective winter covers. Comparison of an airtight and an open winter cover system with ventilation 1838 Environ Earth Sci (2011) 63:1823–1848 123 Simulation of membrane winter covers The requirement profile for a sculpture adapted cover has been defined in the project. The central aspects are light- weight, durability, easy construction, simple transport and storage (cf. Will 2009). In view of all the requirements, different cover materials, e.g. glass, acryl, plastics and membranes have been analysed. Based on these investi- gations, membrane systems were selected because they fulfil most requirements. From various possible membrane systems, a moisture adaptive system has been chosen. All simulation results have been carried out using this mem- brane type. Three simulations for different winter covers utilising a membrane system are given below. The different systems compared are: 1. an airtight membrane design 2. a diffusion open membrane design, allowing air ventilation only from a basal opening 3. a diffusion open membrane design, with defined openings at the bottom and top of the shelter allowing air ventilation of 1 and 5 Pa circulation rates Figure 20 presents the relative humidity of the airtight membrane design and a diffusion open design with a ventilation rate of 5 Pa. The results are shown for 3 days, December 15th, February 1st and March 15th. The com- parison shows that the airtight solution has the lowest moisture content than the ventilated case. Analogous to the wooden shelter, surface condensation leads to higher moisture levels in the marble. An increasing ventilation rate results in a higher moisture content, as presented in Fig. 21. At the end of March both systems show compa- rable results, since enough drying potential exists, but the system stays sensitive. As far as surface condensation is concerned, moisture content in the marble will increase. Figure 21a compares the membrane shelters using the mean moisture content in the marble sculpture. The dis- tribution of moisture within the sculpture is very relevant, since the dynamic course influences the damage processes and the intensity of damage depends on the amplitude of state variables. A comparison of the relative humidity on the sculpture torso surface at different ventilation rates is shown in Fig. 21b. The ventilation rate leads to a different behaviour, since it is dependent on the outer climatic conditions. Drying conditions are present, if the cold and dry outside air is combined with the warm marble. Wetting conditions are present, if warmer and moist outside air circulate around a cold marble. If a continuous large cir- culation rate exists, the marble sculpture will cool down during long freeze periods and increase the risk of deterioration. Because of the large mass of the marble body, the temperature behaviour is more inert than in a small arm, the head or a wing. In that case, the marble can cool down very quickly, reducing condensation events. Design and development of an object-related shelter system Cover requirements The design of statue covers must satisfy an extensive set of criteria including aesthetic, structural and physical perfor- mance (cf. Gengnagel 2005). From an aesthetic point of view, there are two fundamentally different approaches: first, the covering serves as an intentional act of disguise Fig. 19 Comparison of relative humidity calculated for two wooden protective winter covers in the early spring: relatively tight (left) and having air ventilation openings (right) Environ Earth Sci (2011) 63:1823–1848 1839 123 and second, the covering serves as an ‘‘invisible’’ protec- tion (where the degree of invisibility depends heavily on design and materials). The disguise approach can act as a cover for the statue while providing a clear reference to its original form and cultural significance. The cover can also be a totally new and neutral entity, a box for example. In both cases, the covering will result in a new object with its own aesthetic identity. The intended effect of transparent coverings is to preserve the viewer’s impression of the original statue as far as possible. However, the impact of the still necessary structure can lead to a different end result. Finally, both types of coverings should not only serve as an extension of the existing statue but also as a design object itself. The covering provides an environmental barrier for the statue. Specific requirements for covering vary with dif- ferent applications. Each solution provides varying degrees of structural stability, load distribution, water resistance, insulation, vapour and solar irradiation control. All cover- ings need to sustain applied loads from wind and snow and distribute these to the primary structure and supports. Structurally there are two basic systems: skin or shelter. While the skin system transfers external loads directly to the statue, a shelter protects the statue from exposure to external loads. The skin system does not improve the overall stability of the statue, but in fact increases the area exposed to wind loads, which can lead to serious stability problems of the Fig. 20 Distribution of relative humidity within the protective winter covers using a membrane shelter. The results are for December 15th, February 1st and March 30th, membrane cover relatively tight (diagrams at the top) and open air ventilation (diagrams at the bottom) 1840 Environ Earth Sci (2011) 63:1823–1848 123 statue or parts of it. Another critical issue with skin systems is the risk of damage to the statue caused by concentrated loading during the skin assembly. The performance of skins with respect to complex environmental control is limited. The main advantages being that these membrane skins are light, comparatively inexpensive and can be fol- ded into small volumes allowing the membrane to be transported and erected easily and quickly. Shelter systems can be differentiated into two types. Type 1 uses a skeleton as the primary structural system and a mostly soft surface as a secondary structural system. Type 2 uses units or hard shells, where the stiff surface is an integral part of the structure. Both types protect the statue from external loads and climatic influences. In general, shelters are exposed to higher wind loads due to the larger surface com- pared to a skin. The shelter can be supported on the base of the statue or the ground. As shelters often have only few supports, the support forces are high. This affects the preservation of the historical monument as a whole, which demands the design of reversible fixing solutions or the reduction of permanent fixing points to a minimum. Until recently and for most applications, the protective climatic requirements for shelter systems were of lesser importance. Often, shelters fulfilled only the requirement of water tightness. Generally, shelter systems provide more freedom in optimising the internal environment of an enclosure by using insulated materials or multifunctional elements like sandwich constructions. Sculpture adapted system The covering of the marble statues on the Schlossbru¨cke presents a complex and unique challenge due to their exposition, their dimensions and cultural significance in an urban context. The statues are placed on a base 4.00 m above street level and about 8.00 m above the river Spree. Since their reconstruction in the 1880s, the plinths are no longer monolithic blocks. The plinths now consist of a core made of pre-fabricated concrete elements encased in a curtain wall of marble. The statues themselves are around 4.50 m tall and some suffer from serious stability prob- lems. Most of the statues have very delicate and exposed extremities. Initial design concepts (Fig. 22) struggled to satisfy all the design constraints. The use of a skin would enlarge the area of the statue exposed to wind loads resulting in magnified stability problems. Shelter-based design con- cepts proved unfeasible as the shelters may not be fixed to the plinth. Stable and usable support surfaces for the shelter exist only below the plinth and subsequently below street level. On the water side of the statues, sandstone blocks extend underneath the marble plinths, which can be used for anchoring structural supports. A further anchor point is available on the street side at the pedestrian level; however, an expansion of the covering system into this strongly frequented public area leads to functional and also aesthetic deficits. A support on the pavement was therefore eliminated. The constraints described above result in a 9 m high structure, which must be installed below street level and from the water side. The use of technical aids (such as a crane) is therefore indispensable. Concept of the covering system The shelters can be developed for individual geometric requirements of each statue or as an overall solution for all statues. Individualised solutions would facilitate the mini- misation of exterior surfaces and resulting wind loads. A single shelter solution for all statues would result in a larger design but batch production will incur lower costs. Choosing between an individual and overall solution depends on the geometry of the statues. A study of the statue geometry shows that despite the different motives, the dimensions and proportions of all figures are very Fig. 21 Comparison of different membrane protective winter cover systems: a no ventilation, small ventilation (base open) and high ventilation (5 Pa pressure difference). b Relative humidity at the torso of the sculpture: no ventilation, small (0.5 Pa pressure difference and base open), medium (1.5 Pa pressure difference) and large ventilation (5 Pa pressure difference) Environ Earth Sci (2011) 63:1823–1848 1841 123 similar. Individual solutions for all figures would therefore result in only small deviations and would not reduce the wind loads significantly. On account of this, an overall solution was developed for the statues on the ‘‘Schloss- bru¨cke’’ bridge. In order to facilitate the development of a generalised covering system, basic 3D geometric profiles of the statues were compiled and superimposed with one another to serve as reference geometry data. The generated superposition does not identify any primary orientation. The cross section of the figures in plan is slightly larger than the upper sur- face of the plinth. The geometric constraints, used in developing the cov- ers, were defined by adding a buffer offset to the super- imposed 3D profiles. In order to evaluate what impact the cover’s cross sectional profile (in plan) has on design and wind resistance, a variety of sections were examined (namely square, polygonal and circular). On the grounds of aesthetic and climatic design, an early decision saw the extension of the cover to a height below that of the foot of the statue. Another major design decision was the selection of a conical form as a preferred shape for the cover system. The selection is justified by three struc- tural advantages: primarily, the conical form facilitates a constant geometrical transition from the larger figure to the smaller base. Subsequently and secondly, the dead weight and the wind forces are minimised where possible. Third, the buffer offset between the cover and statue is suitably largest at the top of the cone where deflections are also the biggest. Analysing wind forces to different section profiles shows that a circular section results in the smallest wind resistance and only a very small stress factor (Fig. 23). A further advantage of the circular section is the continuous curvature for the use of a mechanically pre-stressed membrane. Method of assembly The method of assembly and disassembly of the statue covers is governed by the following conditions: (i) the assembly and disassembly takes place ever year, (ii) the assembly and disassembly must be achieved simply and quickly with minimal technical aids (i.e. machinery) and (iii) while the statues’ plinths are reasonably resistant to light bumps and scrapes during the erection process, the statues themselves are fragile and can be damaged easily. The last constraint is particularly important for the assembly and disassembly of the statue covers. Gaining precise control over the movement of all components of a 9 m high structure during its erection is extremely demanding, all the more so, because of restricted accessi- bility to the statues on the bridge. In order to guard against the risks of potential movement of the structure or parts of it during assembly, there are two basic solutions: (i) to select a large structural footprint with sufficient tolerances for movements and deformations and (ii) to remotely control the assembly of the structure and thereby gaining precise control of the kinematic system. The first solution leads to large dimensions and subse- quently heavy parts, which makes assembly and disas- sembly unfeasible. For this reason, a remotely controlled system was investigated and developed as a solution to the assembly and disassembly problem. The proposed solution is a two-step process. The first step involves mounting and assembling all the components and component groups onto the anchor points and to each other, during which large movements can be expected. The second step involves erecting the kinematic system to its final position through application of external loads. As such, any movements are a direct result of the (controllable) kinematic system. The basic concept of the remotely controlled solution is to isolate all manual assembly processes within the lower Fig. 22 Different design concepts: a soft skin stabilised by underpressure, b stiff framework with soft surface and c stiff modular surface 1842 Environ Earth Sci (2011) 63:1823–1848 123 and more robust plinth base, where damage cannot be so easily incurred. Then the structure can be assembled upwards encasing the statue from below. Finally a lid is craned into position to close the system from above. Mounting the lid from above poses a low risk since the fragile statue is already encased and protected at this point. Kinematic system The proposed kinematic system can be basically repre- sented by two pin-jointed members that connect upper and lower ring beams. An applied force is required in order to induce movement in the system. This force should be applied vertically and directly between the ring bars. Such a force can be achieved using hydraulic pistons or a rack and pinion system. In order to prevent an uneven erection, the force application must be controlled by an electronic or visual feedback system. Only vertical members, and not diagonal members, can be used for the kinematic system. If the diagonal members are used in the erection process, they would induce hori- zontal reaction loads resulting in tangential rotation of the upper ring. Therefore, only vertical members are to be used to stabilise the kinematic system, whereas tensile diagonal members (cables) will be used to stiffen the static system. Pre-stressing the cables and membrane can be carried out by the erection. In order to complete the transformation from a kinematic system to a static one, the articulated joints in the middle of the vertical members must be made rigid. Assembly steps The final housing system is comprised of aluminium truss members, which will be pre-fabricated into a set of units for assembly (each of which weighs no more than 80 kg, Table 3). The structure would double in weight if it were made out of steel. Therefore, a crane would be required for the assembly of a steel version. The complete assembling process consists of four main steps (Fig. 24). Step 1 All three pre-fabricated V-columns are to be mounted onto the anchor points and bolted to one another. The first V-column requires a temporary support during construction. The second and third V-columns will be stabilised by the first and second columns, respectively. When all three V-columns have been mounted, the system will be statically determinate and the temporary support can be removed. Step 2 The three ring elements (each split into two halves) are to be mounted on top of the existing structure. The membranes will be secured to one half of the ring and when the rings are fixed, the membrane can be pulled through into the other half of the ring. Step 3 The rings are to be erected vertically starting with the bottom ring and ending with the top ring. Step 4 The fully pre-fabricated lid (with pre-stressed membrane) is to be mounted on top of the existing structure and secured with bolts. The disassembly of the structure is a repeat of the above steps in reverse. Structure and covering The shelter can be divided into two structural subsystems. The first subsystem consists of three ring elements and a roof (Fig. 24a). This subsystem is axisymmetric and equal for all statues, and its structural behaviour equates to a shell. The second subsystem consists of V-columns, which statically behave as a framework. The V-columns start at the rectangular plinth and end at the circular ring elements. Due to the irregular balustrade geometry, the V-columns and support points are non-symmetrical and differ for all corner statues and the group of centre statues. The V-columns are sufficiently adaptable to fulfil the different geometric constraints at every statue. The four Fig. 23 Drag coefficient and stress factor (drag coefficient/section modulus) of different geometries Table 3 Weights of the different covering elements V-columns 3 elements 176 kg Weight ring 2 2 elements 111 kg Weight ring 3 2 elements 108 kg Weight ring 4 2 elements 105 kg Weight roof 1 element 79 kg Total weight 579 kg Environ Earth Sci (2011) 63:1823–1848 1843 123 shelters in the middle of the bridge have only anchor points on the water side, whereas the corner shelters have anchor points on the water side and on the pedestrian walkway. The difference in height between these points is about 50 cm and leads to additional changes in the geometry of the V-columns. The V-columns are pinned to threaded steel bars, which are cemented into the plinth base. These pins remain permanently. The structure consists of aluminium hollow sections. The V-columns are intended as round pipes with a diameter of 6 cm, and the ring beams as rectangular cross sections 6 cm 9 4 cm. The covering of the structure consists of a mechanically pre-stressed membrane. The membrane is stabilised by its two-way curvature to avoid noise by beating and flapping. The geometric design puts the membrane inside of the skeleton structure. The decisive load case combines dead weight, wind loads and snow loads. This load combination produces a substantial horizontal deformation of up to 12 cm. Due to the asymmetry of the V-columns, the deformations vary around a factor of two depending on the wind direction (Fig. 25). The influence of geometrical imperfections at the sup- port points was also examined. Differences between the intended and the actual structure geometry can result from inaccuracies during fabrication, deformations caused due to inappropriate storage, transport and assembly and devia- tions in plinth geometry. The imperfections can be mini- mised but not avoided completely. A deviation of 2.5 cm at one support point leads to additional stresses of 10%, and a deviation of 5 cm to additional stresses of 25%. These distances are small in relation to the total height of 9 m, and therefore the geometrical imperfections must be considered. Proper handling, transportation and assembly of the components must be carried out in order to avoid causing further imperfections as much as possible. An examination of accuracy to size at regular time intervals can offer suf- ficient security. Since imperfections in mobile structures cannot be avoided completely, the dimensions of the structure have been calculated with appropriate reserves. Fig. 24 a Kinematic system and b concept of erection process of the covering shelter (step 1–4 from left to right) Fig. 25 Deformation of the different shelters depending on the wind direction 1844 Environ Earth Sci (2011) 63:1823–1848 123 Discussion and summary The investigation presented in this paper deals with a culturally and historically significant group of valuable sculptures made from Carrara marble and displayed in an urban environment. Conservation of cultural assets con- structed from natural stones requires regular inspection and maintenance as an effective instrument in preventive monument preservation. Winter coverings are part of the conservation procedures for exposed monuments and consist of highly complex systems. These systems have to be adapted to the climatic conditions, the structural and technical circumstances and the material properties of the statues as well as being applied in a practical way. More- over, the inventory and restoration history needs to be taken into consideration in regards to the decade’s long use of preserving agents, because these can change the nature of the original material as well as the technical/physical properties. The importance and central location of the Schlossbru¨cke in the periphery of the world heritage site known as the Museum Island, requires a constructive as well as aesthetic and sophisticated assembly for covering these valuable bridge sculptures. The design demands for the Schlossbru¨cke winter cov- ers were particularly challenging. The geometry of the sculptures, the balustrades and the side walls differs from figure to figure, requiring each winter cover to be cus- tomised, respectively. Structural elements of a shelter system may not be fixed to the marble plinth directly below the figures, but instead must extend 4 m further down to the sandstone base. The structure is subsequently 9 m high and so the assembly, which must be carried out above water, presents a significant challenge. Furthermore, the statues are particularly delicate and could therefore be easily damaged with incautious assembly. The proposed shelter system has been developed to satisfy requirements for aesthetic design, structural stability and protection of the sculptures (Fig. 26). The structure is sufficiently adaptable to meet the varying geometric con- straints at each figure, while maximising component stan- dardisation. Assembly of the aluminium framework and pre-stressed membrane has low-tech demands. The use of a remotely controlled system will facilitate precise erection with high geometric tolerances. The general requirements for winter covers of outdoor stone statuary are to provide protection against external environmental factors (liquid water, humidity, solar irra- diation, frost, strong variations in surface temperatures), chemical factors (acid pollutants, salt damage) and bio- logical factors (invasive flora and fauna). As well as pro- viding sufficient environmental protection, the winter covers must also satisfy further demands on aesthetic performance, structural stability and for transportation, safe assembly and storage. Since some of these constraints conflict with one another, the winter cover cannot satisfy all the demands simultaneously. Instead, a balanced solu- tion must be found by prioritising the criteria. The climate data presented on some examples are a valuable basis for numerical simulations, for the assess- ment of protective winter covers and their effect on the microclimate at the sculptures. The data have been col- lected on sculptures exposed to the weather and on Fig. 26 View of the shelter systems from the street and river Environ Earth Sci (2011) 63:1823–1848 1845 123 sculptures inside two different protective covers. By means of these measurements, the influence of the covers on the microclimate near the sculptures can be shown. The collected data show that the temperature of the sculptures is determined mainly by the temperature of the ambient air. The influence of direct sunlight on the surface temperature is relatively low. Due to the high thermal conductivity, the temperature gradient inside the material is small. A fast drop of the surface temperature can be caused by sudden rain in summer. Due to the wide openings of the studied covers, no signif- icant difference between the inside and the outside air tem- perature has been measured. However, the effect of shading and the lower wind speed causes the surface temperature of the massive parts of the sculpture within the cover to show smaller temperature peaks than the surface temperature of weathered sculptures. Besides the protection against the rain, the mem- brane cover reduces the infiltration of water by dew. This effect might be increased by closing and sealing the cover completely. Furthermore, to avoid the accumulation of dust deposits the cover should remain closed. The measurements will be continued even when the project is finished in October 2010. An additional mea- surement system will be installed at a sculpture that will be covered by a new protective system in October 2010. Meanwhile, numerous simulations of the marble and the protective systems have been carried out. Induced by the climatic conditions at the ‘‘Schloss- bru¨cke - Unter der Linden’’ the exposed marble sculptures become moistened to a penetration depth of 200 mm. Thus, the smaller parts, e.g. legs, arms, head and wing, can become completely moistened. During the spring and summer, the marble can dry completely. Thin and filigree parts of the sculpture have large surface areas, e.g. the feathers of wings will completely dry out and then become completely wet again. Therefore, these sculpture parts are subjected to extreme climatic loads. Wooden winter housing always brings protection from rainstorms, but there are some other aspects to pay atten- tion too. While airtight wooden protective systems and small air exchanges keeps the marble dry, a large air exchange leads to a wetting caused by condensation. The load by condensation can be very similar in magnitude as from a heavy rain. Membrane winter covers can be an efficient means for protection against downpours, but analogous to wooden housing the ventilation rate can moisten the marble. The moisture balance of the sculpture is a complex relationship between temperature, relative humidity and acting climatic conditions as well. The exchange of air can lead to both a drying potential as well as to a dampening of the marble. Moisture distribution in different parts of the sculpture, e.g. body, leg, arm, head, wing, is very complex. A climatic change can produce a slight load in the torso part but results in a strong load in the filigree sculpture parts. Thus, one has to define priorities of the sculpture and to optimise them. The investigations on membrane materials for winter covers have shown positive effects when they are used as a type of insulating membrane. The usage of a double lay- ered membrane, e.g. bubble membrane, could further support the insulation effect. The numerical results also make clear that the air exchange should be reduced. During the cold months, air circulation leads to moistening. On the other hand, a con- trolled air exchange can support the drying of the sculpture. This leads to an improvement of a protective winter housing and creates a climate-controlled air circulation. From a geoscientific point of view, marbles represent a very special building stone, because they show positive and negative properties (e.g. translucent appearance, work- ability, weathering behaviour, etc.). The extreme aniso- tropic dilatation behaviour of calcite and dolomite single crystals especially leads to stresses in the rock fabric during changes in temperature, which results in an initial micro- cracking. Moisture is considered to be a key parameter concerning the marble decay process (Schouenborg et al. 2000, 2003) and can lead to unlimited residual expansion of certain marble types. Many authors (e.g. Sage 1988; Siegesmund et al. 2000; Ruedrich 2003) have demonstrated that the increase of residual strain stops after a few heating cycles if moisture is absent. To discuss these effects in more detail, Koch and Siegesmund (2004) performed measurements of progressive residual strain of different marbles under slightly different conditions (Fig. 27). Eight dry cycles up to 90C were followed by 25 additional wet cycles altogether, whereby the first six wet cycles were carried out in a way that at the end of a heating cycle the Fig. 27 Progressive increase of residual strain of a Carrara marble as a function of the number of heating cycles under dry (cycles 1–8) and wet (cycles 8–33) conditions. From cycles 8–14, the samples remain humid; from cycle 14 samples run dry after each cycle. The colours of the curves indicate different directions of the sample reference system 1846 Environ Earth Sci (2011) 63:1823–1848 123 samples in the climate chamber remained slightly humid but still in contact with water. In the following 19 cycles, the samples were run until totally dry. The findings from this approach are: (i) the progressive residual strain indeed proceeds continuously; the increase is constant even after 25 cycles under wet conditions and (ii) the moisture con- tent after a heating cycle apparently influences the intensity of marble degradation. The strain versus cycles curve (Fig. 27) tends to get flat as long as water is still available during the test cycles. As soon as samples totally dry up after each heating cycle, the durable marble expansion accelerates again. The thermal expansion behaviour in Fig. 5f also shows a progressive increase of residual strain by freezing marble samples under wet conditions. For freezing under dry sample conditions, no further residual strain occurs. Thus, the decay behaviour for heating as well as for cooling is more or less the same. Accordingly, the worst scenario will be drying during temperature changes. Although the decay magnitude induced by the heating process seems to be more important, the winter period should also cause pro- gressive fabric decay. Consequently, for a winter cover the moisture content should only show a slight variation in range. Situations of drying/wetting induced by ventilation and condensation processes should be avoided from a material point of view. Acknowledgments Our work was supported by the Deutsche Bundesstiftung Umwelt. Open Access This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which per- mits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited. References Accardo G, Altieri A, Cacace C, Giani E, Giovagnoli A (2003) Risk Map: a project to aid decision-making in the protection, preservation and conservation of Italian cultural heritage. 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