SPECIAL ISSUE Granitic dimensional stones in Uruguay: evaluation and assessment of potential resources Manuela Morales Demarco • Pedro Oyhantc¸abal • Karl-Jochen Stein • Siegfried Siegesmund Received: 23 April 2012 / Accepted: 12 September 2012 / Published online: 10 November 2012  The Author(s) 2012. This article is published with open access at Springerlink.com Abstract In Uruguay commercial granite varieties com- prise mafic rocks, granitoids, and syenitoids. There is a long tradition in Uruguay, as well as worldwide, of using dimensional stones in architecture and art, specially gra- nitic ones. Some of the present applications of these dimensional stones are as fac¸ade cladding, countertops, and outdoor and indoor floor slabs. The color spectrum of the Uruguayan granitic dimensional stones varies from black to light gray, covering a wide variety of red and pink and minor greenish-gray. The de´cor of these granitic dimen- sional stones is mainly determined by their fabric, funda- mentally the grain size and the color distribution between the different minerals that compose the rocks. In the present research the most important commercial granites were sampled to analyze their petrography and petro- physical properties. A detailed structural analysis has been performed in several deposits, as well as the application of the software 3D Block Expert for modeling the possible raw block size distribution. Other factors controlling the mining viability of the deposits were also studied (e.g., homogeneity/heterogeneity of color and de´cor) and the possible reserves were calculated. Keywords Granitic dimensional stones  Petrophysical properties  Petrography  Deposit characterization  Uruguay Introduction Terms and standards Granitic dimensional stones are widely used in architec- ture. Some examples include paving tiles, monuments, interior and exterior wall cladding (Montani 2008) (Figs. 1, 2). Its share of the market of dimensional stones has doubled in the period between 1995 and 2007 (Montani 2008). Due to their durability, granite represents one of the preferred natural materials when deterioration risk is present. Commercially, the term granite is used for dimensional stones consisting of all the hard rocks, even when their lithology strongly differs from that of true granite. In the Earth Sciences, the use is stricter and the name granite only applies to a plutonic rock containing quartz, alkali feldspar, and plagioclase. These rocks plot in a specific field defined by the QAPF classification triangle (Streckeisen 1976). Granitoid is a superordinate category designating a plutonic rock that has between 20 and 60 percent quartz in the QAPF classification (Streckeisen 1976; Le Maitre et al. 2002; Allaby and Allaby 1990; Jackson 1997). It includes the alkali feldspar granites, granites sensu stricto, granod- iorites, and tonalites. Syenitoid is a term used for plutonic rocks with a quartz content ranging between 0 and 20 % and a feldspar ratio (alkali feldspar/plagioclase ? alkali feldspar) between 35 and 100 % (Streckeisen 1976; Le Maitre et al. 2002; Allaby and Allaby 1990; Jackson 1997). Gabbroids include all the plutonic rocks showing a feldspar M. Morales Demarco (&)  S. Siegesmund Geoscience Center of the Georg-August University Go¨ttingen, Goldschmidtstrasse 7, 37077 Go¨ttingen, Germany e-mail: manugea@gmail.com P. Oyhantc¸abal Departamento de Geologı´a, Facultad de Ciencias, Universidad de la Repu´blica, Igua´ 4225, C.P. 11400 Montevideo, Uruguay K.-J. Stein Natursteininformationsbu¨ro, Am Schulzensee 3, OT Waldsee, 17258 Feldberger Seenlandschaft, Germany 123 Environ Earth Sci (2013) 69:1397–1438 DOI 10.1007/s12665-012-2027-y ratio between 0 and 35 % and quartz contents between 0 and 20 % (Streckeisen 1976; Le Maitre et al. 2002; Allaby and Allaby 1990; Jackson 1997). Mafic rock is a term that includes gabbroids but also other igneous rocks (e.g., basalt) composed chiefly by mafic minerals (Jackson 1997). Fig. 1 Uses of Uruguayan commercial granites in the city of Montevideo; a outdoor fac¸ade cladding using Moderate Black Dolerite and flooring slabs using Cufre´ Granite in the Antel Tower; b outdoor sculpture (Vizconde de Maua´) using La Paz Granite; c outdoor fac¸ade cladding using polished and unpolished slabs of Violeta Imperial Syenite; d outdoor sculpture using Moskart Granite; e different sorts of outdoor flooring slabs using granite; and f outdoor socle and columns using Isla Mala Tonalite in the Central Train Station (Estacio´n Central AFE) Fig. 2 Global main uses of dimensional stones (in percentage) after Montani (2008) a global uses in 1995 (total finished production: 25 million tons); and b global uses in 2007 (61 million tons) 1398 Environ Earth Sci (2013) 69:1397–1438 123 At the beginning of the 21st century, the European countries decided that dimensional rocks must be correctly named according to the petrological description and the standards of international geological terminology (e.g., DIN EN 12407, 2007; DIN EN 12670, 2000; DIN EN 12670, 2001). Outside Europe the American standards are normally used (e.g., ASTM C119 2011). These standards allow the naming of granite as granular igneous rocks, which includes granitoids, syenitoids, and mafic rocks (gabbros, dolerites), but also some granular metamorphic rocks such as gneisses and schists (Quick 2002). In Uruguay, what is commercially known as ‘‘granite’’ includes a wide variety of lithologies such as granitoids (granodiorite, tonalite, granite s.s.), syenitoids (quartz syenite, alkali feldspar syenite and quartz alkali feldspar syenite), and mafic rocks (gabbro-norite and dolerite) (Table 1). The colored commercial granites include sye- nitoids and granites s.s., whereas the gray granites com- prise granites s.s., granodiorites and tonalites. The rocks that are commercially known as black granites are basically dolerites and gabbro-norites. Production The mining of dimensional stones in Uruguay began during the first settlements with the construction of fortifications and citadels between the end of the 17th and the beginning of the 18th centuries. Examples are the fortress of Santa Teresa, built from the porphyritic facies of the Santa Teresa Granite and the citadels of Colonia del Sacramento and Montevideo constructed from local granitic and metamor- phic rocks. Since the beginning of the 20th century until today, commercial granites have been used for a wide variety of architectural and artistic purposes. The dimensional stone sector had a very important productive phase at the beginning of the 20th century. Syenitoids of the Pan de Azu´car-Piria´polis area and gran- ites of La Paz provided material for the construction of the most important cities of the region, especially for Monte- video and the neighboring city of Buenos Aires. The international trend of using commercial granites mainly for decorative purposes and not only for structural ones is a practice used by the architects and construction companies in Uruguay. Commercial granite is used in Uruguay for fac¸ade cladding, as paving tiles, for interior floor and wall cladding, countertops, stairs, columns, sculptures, monuments, and precision tables, among other applications (Fig. 1). The dimensional stone market is particularly sensitive to fashion trends and economic constrains. Beginning in the year 2000 the economic crisis in South America led to a severe decline in the construction industry, and thus, in the dimensional stone production. The world production of all types of dimensional stone in 2007 was 103 million tons (Montani 2008). The leading productive countries in that year were China, India, Tur- key, Italy, and Spain, which together produced almost 60 % of the dimensional stone (Montani 2008). In 2007 Latin America produced 6.5 million tons, with Brazil being the main producing country with 5.75 million tons, fol- lowed by Argentina with 0.35 million (Montani 2008). Uruguayan production in the same year was of 7,048 tons (DI.NA.MI.GE. 2008), just 0.11 % of the total Latin American production. The most important countries in the granitic dimensional stone sector are China, India, Spain, and Portugal as illustrated in Fig. 3, where the dimensional and granitic stone production in million tons is shown. The importance of granitic rocks in this production is visible in Fig. 4, where the total dimensional stone production is divided into three main stone varieties: commercial granites, mar- ble and travertine, and slate and others. Worldwide pro- duction of commercial granites has almost quadruplicated in 82 years (Montani 2008). The production of dimensional stone in Uruguay today is mainly represented by granite, slates, and sandstone with a marginal proportion of marble (Fig. 5). The most important variety in the commercial production of granite is the black granite (dolerite), mainly the Moderate Black variety. In order to gain a better idea of the importance of each commercial variety, the production (in m3) was cal- culated using the original data in tons from DI.NA.MI.GE. (2008) for the year 2007 and the density values obtained in this research. Dolerites showed a production of 1,810 m3, representing 81 % of the commercial granite production, gray granites represent 10 %, greenish-gray granite 5 % (Soca or Moskart), and pink granite 4 % (La Paz or Car- amel Pink). The economic geological evaluation of dimensional stone deposits essentially relies on two factors (e.g., Peschel 1977; Singewald 1992): (i) the presumable occurrence of raw blocks (referring to the proportion of raw blocks suitable for industrial processing) and (ii) the petrophysical properties (tested according to EN norms), which provide information about the rock behavior under the influence of deterioration forces. The production of raw blocks of adequate de´cor and size is a major factor in the economic evaluation of a deposit. An optimal block size is required for economical pro- cessing using modern cutting techniques (e.g., a minimum block size of 2.5 9 1.3 9 1 m is necessary when using the gang saw blade). This optimal size must also take into account the associated processing losses (e.g., oddments). This is essentially controlled by the structural elements (e.g., the spatial distribution of joint systems and their frequency) and the homogeneity of the rock deposit. Environ Earth Sci (2013) 69:1397–1438 1399 123 Currently, no models exist for sustainable mining of these types of deposits, which reduces the waste material gen- erated when producing an optimal block size. Scope of the article and state of art Uruguay has a wide variety of dimensional stones in terms of color and de´cor; however, petrophysical properties and deposits has not been sufficiently studied. The present study aims to contribute to the economic geological development of the granitic dimensional stones of Uruguay with respect to further exploration, evaluation, mining, and marketing. Another important goal of the present study is to eval- uate the petrophysical properties of the different granitic dimensional stones of Uruguay to determine the best potential uses of these rocks. Furthermore, the deposits are characterized according to color and de´cor, so that the distribution of commercially interesting stones can be determined as well as the factors controlling the deposits. These factors are the volume of the deposit, the lithological aspects, and the structural elements present. In order to provide a steady product for the market the volume of material available is important. However, the waste mate- rial is also of secondary economic value in the operation of dimensional stone deposit. Structural elements control the Table 1 List of commercial granites from Uruguay (Data source Bossi and Navarro 2000; DI.NA.MI.GE. 2011; Comunita` Economica Europea, no date; author’s database) Rock Id Commercial type Commercial name Locality Department Dolerite U8 Black granite Sacramento (Comercio Exterior S.A.) A Pichinango Colonia Dolerite U11A Black granite Absolute (Black Stone S.A.) A de la Quinta San Jose´ Dolerite U11O Black granite Moderate or Oriental (Black Stone S.A.) A de la Quinta San Jose´ Dolerite U66 Black granite Oriental (Pimafox) A Polonia Colonia Gabbro-norite U87 Black Granite Mahoma Black Mal Abrigo San Jose´ Basalt U49 Black granite Arapey Black Arroyo Valentı´n Chico Salto Granite U2 Gray granite Maldonado Gray Maldonado Maldonado Granodiorite U4 Gray granite Chamanga´ Gray Arroyo Chamanga´ Flores Granite U53 Gray granite Cuchilla del Perdido Gray Blue Chuchilla del Perdido Soriano Granite U70 Gray granite Cerro A´spero or Gray Rocha Arroyo Sauce de Rocha Rocha Granite U73 Gray granite Cufre´ Gray Blue Cufre´ Colonia Granite U80 Gray granite Cerro de Carmelo Gray El Cerro. Carmelo Colonia Granite U81 Gray granite Ismael Cortinas Gray Ismael Cortinas Flores Granite U82 Gray granite Loyner Gray Flores Granite U83 Gray granite Gon˜i Gray Gon˜i Florida Granite U85 Gray granite Iguazu´ or Garzo´n Gray Garzo´n Rocha Granite U89 Gray granite Losten Gray Soriano Granite U90 Gray granite Dionisio Gray Cuchilla de Dionisio Treinta y Tres Granite U93 Gray granite Santa Teresa Gray Santa Teresa Rocha Tonalite U94 Gray granite Isla Mala Gray 25 de Agosto Florida Granite U95 Gray granite Northern Garzo´n Gray Garzo´n Maldonado Granite U7 Dark green granite Labradorita Oriental or Moskart Soca Canelones Granite U74 Red granite Caramel Pink or La Paz La Paz Canelones Granite U75 Red granite Asperezas A Asperezas–A Malo Cerro Largo Granite U76 Red granite Guazunambı´, Montevideo or Iguazu´ Arbolito Cerro Largo Granite U77 Red granite Luja´n or Santa Clara Santa Clara del Olimar Cerro Largo Granite U84 Red granite Sarah Pink Lavalleja Granite U88 Red granite Mahoma Red Mal Abrigo San Jose´ Quartz alkali feldspar syenite U15 Red granite Salmon Red or Guazubira´ Sierra de A´nimas Maldonado Alkali feldspar syenite U46 Red granite Artigas Pearl or Artiqas Piria´polis Maldonado Quartz–syenite U47 Red granite Violeta Imperial Sierra de A´nimas Maldonado Quartz alkali feldspar syenite U92 Gray granite Pan de Azu´car White Piria´polis Maldonado 1400 Environ Earth Sci (2013) 69:1397–1438 123 deposit by the joint system present, whereby their distri- bution determines the shape and volume of the blocks being mined. Lithological aspects define the suitability of a granitic rock for use as a dimensional stone, since it con- trols the color and de´cor. The mineral composition and fabric are important for the characterization of a dimen- sional stone with respect to the petrophysical properties of the rock, as well as its resistance to weathering. Similar investigations on granitic dimensional stones in Thailand were carried out by Hoffmann (2006), Hoffmann and Siegesmund (2007), in Argentina by Mosch et al. (2007) and in Uruguay by Morales Pe´rez and Muzio (2005) and Oyhantc¸abal et al. (2007). Some examples of detailed research in exotic granitic rocks include an investigation on the larvikites of Norway (Heldal et al. 2008), on dolerites from Uruguay (Bossi and Campal 1991; Morales Demarco et al. 2011), and on a granitic batholith in Sa˜o Paulo, Brazil (Artur et al. 2001). Geological setting Uruguayan geology is characterized by an igneous-meta- morphic basement and several basins distributed in differ- ent regions of the country (Fig. 6). The crystalline basement was originally divided into two domains by Ferrando and Ferna´ndez (1971), the western domains belonging to the Transamazonian Cycle (Paleoproteozoic) and the eastern one to the Brasiliano Cycle (Neoproterozoic). Today the western domain is known as Rio de la Plata Craton (Almeida et al. 1973; Bossi and Ferrando 2001; Oyhantc¸abal et al. 2010), which extends westwards into Argentina. The eastern domain is divided into the Nico Pe´rez and Punta del Este Terranes (Bossi and Ferrando 2001; Oyhantc¸abal et al. 2010). A mobile belt known as the Dom Feliciano Belt is located between these two terranes (Fragoso Ce´sar 1980; Oyhantc¸abal et al. 2009, 2010). The boundaries between these tectono-stratigraphic units are from west to east: the Sarandı´ del Yı´ Shear Zone (SYSZ) and Sierra Ballena Shear Zone (SBSZ). Since the Neoproterozoic the Uruguayan continental area was quite stable, but was interrupted in the Lower Cretaceous by the opening of the South Atlantic Ocean. In this major event, rift basins with associated bimodal magmatism opened and flood basalts were deposited over a wide area of South America, known as the Parana´ Basin, which also includes northwestern Uruguay. Regionalization of commercial granite deposits The commercial granite deposits found in Uruguay occur in three tectono-stratigraphic units: the Dom Feliciano Belt (DFB), the Rı´o de la Plata Craton (RPC), and the Punta del Este Terrane (PET) (Fig. 6). The main tectonic events did not negatively affect the petrophysical properties and the possibility of mining these intrusive rocks. Exceptions can be found locally in some deposits, where a brittle regime Fig. 3 Examples of dimensional stone production in million tons for the year 2001 (Sources Spain: Federacio´n Espan˜ola de la Piedra Natural 2008; India: Centre for Development of Stones—Jaipur 2011; Portugal: Direcc¸a˜o Geral de Energia e Geologia (DGEG) and Divisa˜o de Estatı´stica 2011; China: Jorge Quiroz C Consultores Asociados 2006) Fig. 4 World dimensional stone production classified by rock type (in percentage) after Montani (2008) a production in 1926 (total production is 1.79 million tons); and b production in 2007 (total production is 103.5 million tons) Environ Earth Sci (2013) 69:1397–1438 1401 123 developed cataclastic zones where no mining can take place. Most of the dimensional stone deposits in Uruguay are located in the DFB and many of them are granitic rocks. Syenitoid deposits, for example, are located in the Sierra de A´nimas Complex (Coronel et al. 1987; Bossi and Navarro 2001; Morales Pe´rez 2004; Oyhantc¸abal et al. 2007). The commercial varieties are characterized by their light red, pink, violet, and gray colors. The commercial varieties Artigas Pearl (Fig. 7e) and Pan de Azu´car White are located in the southernmost portion of this complex (See Fig. 6), whereas the Salmon Red (Fig. 7g) and the Violeta Imperial (Fig. 7h) are in the central part. In the central part of the DFB (Preciozzi et al. 1985; Bossi and Navarro 2000; Bossi and Ferrando 2001; Mor- ales Pe´rez 2004) deposits of red granites are located, e.g., the Luja´n or Santa Clara Granite. Further to the north in the DFB a red granite deposit is located: the Guazunambı´ Granite (See Fig. 6) (Preciozzi et al. 1985; Bossi and Navarro 2000; Bossi and Ferrando 2001; Morales Pe´rez 2004). The rock shows a gentle foliation since this region experienced a progressive deformation toward the Sierra Ballena Shear Zone (SBSZ). The deformed gray granite deposits are associated with the SBSZ. Maldonado Gray is one of these granites, which shows the most developed features of synmagmatic deformation of all the commercial granites analyzed, having a very well-developed foliation and mineral lineation. In the RPC, a dolerite dike swarm crops out in an area of 20,000 km2 (Bossi and Campal 1991; Morales Demarco et al. 2011). The mined dolerite is commercialized as high quality black granite consisting of two varieties, based on the intensity of their black color: Absolute Black and Moderate Black (Fig. 7a, b; Coronel et al. 1987; Bossi and Campal 1991; Morales Demarco et al. 2011). Absolute Black is mined from dikes that have a fine-grained zone wide enough to produce marketable blocks. Two other mafic rocks with increasing importance are also located in the Piedra Alta Terrane (PAT): belonging to the Guaycuru´ Complex (Bossi and Schipilov 2007) is the gabbro-norite known as Mahoma Black and belonging to the Arapey Group is the Arapey Basalt. The Arapey Group is com- posed of six different lithostratigraphic units (formations), each one interbedded with several lava flows that show variations in the geochemical and mineralogical composi- tion (Bossi and Schipilov 2007). Since the Paleoproterozoic the Rı´o de la Plata craton remained relatively tectonically stable, with no indication of deformational events or moderate ones. Evidence of high-grade metamorphic overprinting in the intrusions is absent. The lack of these structural elements in this craton makes the extraction of commercial granites possible. Gray granites, tonalites, and granodiorites are very common in this craton. Some examples of commercial gray granitoids are the Chamanga´ Gray, Gon˜i Gray, and the Cuchilla del Perdido Gray Blue granites (Fig. 7c). In the locality of Cufre´ is found a granite with a moderate folia- tion determined not only by the biotite (Preciozzi et al. 1985), but also by the alignment of the mafic enclaves: the Cufre´ Gray Blue (Fig. 7f). In the city of La Paz is located the La Paz Granite (Preciozzi et al. 1985; Oyhantc¸abal et al. 1990a) (Fig. 7i), whose porphyritic facies is known as the Caramel Pink Granite and together with the Mahoma Red and Moskart Granites (Fig. 7d), they illustrate exam- ples of colored granites s.s. in this unit. In the PET only gray granite deposits have been mined. Some of them are fine-grained like the Cerro A´spero and Garzo´n granites (Preciozzi et al. 1985). Moreover, very coarse-grained granites showing oriented alkali feldspar phenocrysts occur (Preciozzi et al. 1985; Muzio and Artur 1999), and these are known as the Santa Teresa Gray Granite. Lithological inventory Previous authors have studied the granitic rocks of Uru- guay that are used as dimensional stones by paying special attention to the dolerites, syenitoids, greenish-gray gran- ites, and some of the red and gray granites (Scheer 1964; Caruso 1987; Bossi and Navarro 2000; Morales Pe´rez 2004; Spoturno et al. 2004a, b, c; Techera et al. 2004a, b, c). The different commercial granites of Uruguay are classified according to their mineralogical and geochemical composition into mafic rocks, granitoids, and syenitoids. In Fig. 8 the modal composition of the commercial granites is plotted using the QAP diagram proposed by Streckeisen (1976). In Fig. 9a the geochemical analyses are plotted in the R1–R2 diagram (De La Roche et al. 1980) and in Fig. 9b in the TAS diagram (Middlemost 1997; Best 2003). Fig. 5 Production of dimensional stone in Uruguay in 2007 (in percentage) (total production is 5,322 m3) (Data source DI.NA.- MI.GE. 2007) 1402 Environ Earth Sci (2013) 69:1397–1438 123 Fig. 6 Geological map of Uruguay with deposit localities (redrawn after Oyhantc¸abal et al. 2010; Sa´nchez Bettucci et al. 2010) Environ Earth Sci (2013) 69:1397–1438 1403 123 Tables 2 and 3 shows the geochemical analyses for the commercial granite varieties. Mafic group The rocks belonging to the mafic group are characterized by their black color resulting from their mineralogical com- position and grain size. The Uruguayan mafic rocks have SiO2 values between 48.6 (Mahoma Gabbro, Bossi and Schipilov 2007) and 55.43 wt% (Absolute Black Dolerite), FeOt values between 8.82 and 14.50 wt%, MgO between 3.04 and 7.13, and CaO between 6.97 to 9.74 wt%. These rocks belong to the basic to intermediate field (Table 2). The mafic rocks in this category all have a tholeitic affinity and their intrusion occurred in an extensional regime (Bossi and Campal 1991; Bossi and Schipilov 2007). The dolerites have been extensively studied by Bossi and Campal (1991) and Morales Demarco et al. (2011). Bossi and Campal (1991) determined two geochemical and petrographic groups. The rocks of Group A are composed of plagioclase and lower amounts of augite, granophyric intergrowth, amphibole, and opaques; and are character- ized by high TiO2 contents and an andesitic composition (Bossi and Campal 1991; Morales Demarco et al. 2011). Group B has a low TiO2 content and an andesitic-basalt composition. In both groups the opaques are magnetite, ilmenite, and hematite, although they differ in the total amount (Table 4). Fig. 7 Polished slabs of Uruguayan commercial granites (slab length = 10 cm) a Absolute Black Dolerite; b Moderate Black Dolerite; c Cuchilla del Pe´rdido Gray Granite; d Moskart Granite; e Artigas Pearl Syenite; f Cufre´ Gray Granite; g Salmon Red Syenite; h Violeta Imperial Syenite; and i Caramel Pink Granite 1404 Environ Earth Sci (2013) 69:1397–1438 123 Mahoma Black is classified as a gabbro-norite according to geochemical and petrographical analyses (Oyhantc¸abal et al. 1990b; Bossi and Schipilov 2007). The mineralogy is composed of plagioclase, orthopyroxene, clinopyroxene, olivine, and spinel, and as accessories pyrrhotite, pent- landite, chalcopyrite, pyrite, marcasite, valleriite, violarite, magnetite, ilmenite, and magnetite (Oyhantc¸abal et al. 1990b; Bossi and Schipilov 2007). Arapey Basalt belongs to the Arapey Group, which is composed of several lava flows that show variations in the geochemical and mineralogical composition. In general, the rocks are medium-grained and composed of plagioclase and pyroxene with a subophitic texture (Fig. 10c). Some of the lava flows also contain olivine, granophyric intergrowths, and opaques (Bossi and Schipilov 2007). The analyzed rock belongs to the Itapebı´ formation (Bossi and Schipilov 2007). Its mineralogy comprises plagioclase, augite, opaques (mag- netite and hematite), limonite, and a minor amount of quartz. The augite is partially transformed to limonite; however, finely disseminated limonite is also homogeneously distrib- uted throughout the rock (Table 4). This leads to the assumption that the rock is already partially weathered. Granitoids This group of rocks can be classified by their color in gray, red, and greenish-gray and by their grain size in fine-, medium, coarse-, and very coarse-grained. They have SiO2 values that range from 66.67 to 75.34 wt%, classifying them in the field of acid rocks. FeOt varies from 1.31 to 3.49 wt%, MgO from 0.11 to 1.21, and CaO from 0.93 to 4.35 wt%. The total alkalis range from 5.63 to 9.4 wt%, thus these rocks can be classified as transalkaline to calc- alkaline or tholeitic (Table 2; Fig. 9). The mineralogy of the granitoids is represented by alkali feldspar (microcline and orthoclase), sometimes containing perthites (Moskart Granite), plagioclase, quartz, biotite, muscovite, and hornblende (Table 4; Fig. 10). Accessories are magnetite, pyrite, hematite, epidote, apa- tite, titanite, garnet, stilpnomelane, chlorite, and calcite. Isla Mala is the only granitoid that contains ilmenite. Pyrite is always found as traces. Chamanga´ Granite is classified as a granodiorite and Isla Mala as a tonalite; the other granitoids that compose this group are classified as granites s.s. (Fig. 8). Some of these granites show signs of deformation. Cufre´ Granite shows a complete recrystallization of quartz, evi- denced by the very fine-grained texture of this mineral and the absence of undulose extinction (Fig. 10f). The alkali feldspar (microcline) shows incipient recrystallization at the borders of the crystals, but also in thin cracks filled by very fine-grained feldspar crystals along larger crystals. A gentle foliation is observable in the quarry and in extracted blocks, which is determined by the lineation of biotite Fig. 8 QAP diagram of Uruguayan commercial granites (modified after Streckeisen 1976) Environ Earth Sci (2013) 69:1397–1438 1405 123 crystals and mafic microenclaves. The Maldonado Granite has undergone a more intense synmagmatic deformation related to the activity of the SBSZ as described by Oyhantc¸abal (2005). This granite has a very well-devel- oped foliation, with alternating bands some more rich in biotite and others rich in feldspar and quartz (Fig. 10h). Fig. 9 a Distribution of commercial granites in Uruguay a R1–R2 diagram (after De La Roche et al. 1980), and b TAS diagram (modified after Middlemost 1997; Best 2003). Data of La Paz Granite after Oyhantc¸abal et al. (1990a, b, 2010); Isla Mala Complex after Preciozzi (1993); Soca Granite after Oyhantc¸abal et al. (1998); Santa Teresa Granite after Muzio and Artur (1999); Pan de Azu´car Pluton and Maldonado Granite after Oyhantc¸abal et al. (2007); Mahoma Gabbro-norite and Arapey Basalt after Bossi and Schipilov (2007); Dolerites after Morales Demarco et al. (2011); Cufre´ and Mahoma Granite after Oyhantc¸abal et al. (2010); Basalt, granitoids, and syenites this study 1406 Environ Earth Sci (2013) 69:1397–1438 123 Table 3 Trace element composition of the commercial granites (in ppm) Sample Ba Cr Ga Nb Ni Rb Sr V Y Zn Zr U11A 485 54 20 11 31 52 207 381 37 115 212 U11O 453 25 21 10 25 47 211 404 34 132 195 U66 275 175 16 6 115 16 187 201 16 72 106 U49 384 45 22 23 39 15 439 481 35 143 238 U2 225 22 19 14 12 300 50 14 60 41 168 U4 680 27 22 8 11 42 620 29 12 56 224 U53 854 32 21 9 11 37 703 36 14 66 189 U70 569 25 17 9 12 164 152 29 22 23 143 U71 590 21 19 6 14 184 137 31 23 36 160 U73 1,160 24 17 13 16 88 160 18 19 49 196 U83 1,119 16 18 12 14 57 645 9 9 47 161 U93 293 13 23 21 12 336 72 12 34 48 164 U94 536 24 20 11 23 34 487 42 13 53 128 U95 608 18 17 18 19 170 183 20 26 30 114 U7 1,853 20 22 39 12 106 161 \9 91 137 672 U74 449 15 23 18 10 212 129 9 33 40 187 U76 2,238 18 22 12 19 151 1,002 20 10 35 190 U88 1,426 29 25 11 21 176 588 26 9 9 191 U15 725 23 23 42 10 152 174 13 39 62 407 U46 2,288 14 23 48 9 53 523 9 39 112 878 U47 164 19 24 42 9 80 33 \9 34 74 557 U92 50 9 36 71 20 122 15 9 69 144 1,068 Table 2 Major element composition of the commercial granites (in wt%) Sample SiO2 TiO2 Al2O3 FeOt MnO MgO CaO Na2O K2O P2O5 Fe2O3 H2O CO2 Mg # U11A 55.43 1.73 12.94 12.54 0.17 3.04 6.97 2.58 1.75 0.22 13.93 0.63 0.13 0.20 U11O 53.22 2.33 12.16 14.50 0.18 3.07 7.25 2.56 1.64 0.25 16.11 0.59 0.09 0.17 U66 53.19 0.74 14.98 8.82 0.15 7.13 9.74 1.87 0.91 0.10 9.80 0.82 0.29 0.45 U49 49.27 3.51 12.38 13.96 0.21 4.72 8.67 2.44 1.33 0.46 15.51 1.14 0.08 0.25 U2 75.34 0.24 12.48 1.58 0.04 0.27 0.93 2.77 5.22 0.07 1.76 0.56 0.11 0.15 U4 67.75 0.46 16.45 2.66 0.05 0.99 3.45 4.74 1.83 0.14 2.95 0.78 0.17 0.27 U53 66.67 0.52 16.34 3.11 0.06 1.21 3.73 4.60 1.84 0.17 3.46 0.92 0.17 0.28 U70 70.71 0.34 14.23 1.97 0.05 0.73 2.22 2.69 4.53 0.10 2.19 1.24 0.79 0.27 U71 71.59 0.34 13.94 2.02 0.05 0.60 1.87 2.65 4.76 0.13 2.24 1.18 0.49 0.23 U73 72.8 0.25 13.70 2.21 0.03 0.38 1.66 3.58 3.87 0.07 2.45 0.73 0.19 0.15 U83 71.9 0.23 15.00 1.85 0.03 0.41 2.51 4.48 1.98 0.07 2.06 0.66 0.34 0.18 U93 73.00 0.28 13.70 2.03 0.06 0.36 1.16 2.94 4.84 0.18 2.26 0.79 0.20 0.15 U94 67.8 0.42 16.00 2.97 0.05 1.15 4.35 4.41 1.22 0.12 3.30 0.70 0.18 0.28 U95 71.9 0.26 14.50 1.69 0.04 0.53 2.24 2.91 4.29 0.08 1.88 0.87 0.31 0.24 U7 72.3 0.36 12.22 3.49 0.05 0.11 1.59 2.34 5.54 0.07 3.88 0.67 0.37 0.03 U74 73.7 0.23 13.30 1.80 0.03 0.17 1.33 3.48 4.72 0.05 2.00 0.45 0.23 0.09 U76 71.3 0.27 14.40 1.31 0.02 0.47 1.15 3.71 5.69 0.10 1.45 0.47 0.34 0.26 U88 70.2 0.36 14.10 1.85 0.01 0.64 1.56 3.86 4.87 0.14 2.05 0.68 1.15 0.26 U15 69.2 0.26 15.49 2.09 0.06 0.21 1.09 4.55 5.65 0.06 2.32 0.64 0.11 0.09 U46 61.48 0.61 17.72 4.17 0.14 0.48 2.36 5.82 5.17 0.14 4.63 0.59 0.20 0.10 U47 65.06 0.33 16.41 4.19 0.16 0.04 1.44 5.34 6.76 0.03 4.66 0.71 0.13 0.01 U92 66.6 0.29 15.10 3.94 0.13 0.01 0.62 6.11 5.44 0.02 4.38 0.47 0.24 0.00 Environ Earth Sci (2013) 69:1397–1438 1407 123 The Guazunambı´ Granite shows deformation features suggesting that it also intruded during the activity of the SBSZ (Bossi and Navarro 2001). In this granite the feld- spars are all aligned and define a gentle foliation. Syenitoids This group is characterized by coarse- to very coarse- grained size, normally showing an inequigranular texture and different shades of red and pink color. The geochem- istry of the four syenitoid deposits studied is very similar, with values of SiO2 ranging from 61.5 to 69.2 wt% (i.e., intermediate to acid rocks; Table 2). The values of Al2O3, TiO2, MgO, CaO, and P2O5 are always higher in the Art- igas Pearl. In the Pan de Azu´car White, the Na2O content is higher than in any other syenitoid or rock from the other groups considered. The syenitoids are characterized by low amounts of quartz and plagioclase and high alkali feldspar contents (Table 5). The syenitoids are composed mainly of orthoclase, micro- cline, and amphiboles, the latter are normally hornblende, but in the Pan de Azu´car White, sodic amphibole (probably rie- beckite or arfvedsonite) is the main amphibole found. Other minerals that occur in these rocks appear as accessories: plagioclase, quartz, biotite, chlorite, pyroxene (normally aegirine–augite), ferristilpnomelane, calcite, epidote, tour- maline, magnetite, and zircon. Artigas Pearl shows traces of pyrite. Based on their mineralogical composition, these rocks can be classified as alkali feldspar syenite, quartz alkali feldspar syenite, and quartz syenites (Fig. 8). Technical aspects Color and de´cor The black and dark gray color characterizes the mafic rocks mined in Uruguay. Other mafic rocks with different colors Fig. 10 Thin section images of black and gray commercial granites, image width approximately 8.7 mm. a Fine-grained Absolute Black Dolerite (U11A) in plane polarized light (PPL) with a subophitic texture between Pl and Aug; b Moderate Black Dolerite (U11O) of Group A (high TiO2) in PPL, medium grain size and subophitic texture; c Arapey Basalt (U49) in PPL with medium-grained subophitic texture; d Cerro A´spero Granite (U70) in cross polarized light (CPL), fine- to medium-grained texture with Or and Qtz; e Chamanga´ Granite (U4) in CPL medium-grained texture with Qtz, Pl, Or, and Bt; f Cufre´ Granite (U73) in CPL, to the right recrystallized Qtz (fine-grained) and to the left a Mc phenocryst; g Cuchilla del Perdido Granite in CPL, medium-grained texture, Qtz, Pl, Or, and Bt; and h Maldonado Granite in CPL, phenocrysts of Or and Mc in recrystallized matrix of Qtz with Bt. Abbreviations after Kretz (1983) except the ones marked with asterisk: Aug augite, Bt biotite, Lm limonite, Mc microcline, Or orthoclase, Pl plagioclase, Qtz quartz Table 4 Modal composition of the commercial granites studied Abbreviations after Kretz (1983) except the ones marked with asterisk: Ab albite, Amph* amphibole, Aug augite, Bt biotite, Cal calcite, Chl chlorite, Festil* ferristilpnomelane, Gr. Int.* graphic intergrowth, Hbl hornblende, Lm limonite, Mc microcline, Ms muscovite, Op* opaques, Or orthoclase, Pl plagioclase, Qtz quartz ID Commercial name Modal analysis (vol%) U11A Negro Absoluto Dolerite 37Pl, 33Aug, 20Gr.int., 9Op U11O Negro Oriental Dolerite 41Pl, 29Aug, 3Hbl, 22Gr.int., 5Op U66A Pimafox fine-grained 58Pl, 42Aug, Op U660 Pimafox coarse-grained 47Pl, 42Aug, 6Gr.int., lOp U49 Arapey 3Qtz, 40Pl, 31Aug, 17Lm, 9Op U2 Maldonado 5lQtz, 34Mc, 10Pl, 5Bt U4 Chamanga´ 31Qtz, 9Or, 7Mc, 38Pl, 15Bt U53 Cuchilla del Perdido 33Qtz, 26Or, 29Pl, l0Bt, lAug, lHbl U70 Cerro A´spero 30Qtz, 36Or, 6Mc, 8Pl, 12Bt; 7Ms, ICal U73 Cufre´ 40Qtz, lOr, 29Mc, 24Pl, 6Bt U83 Gon˜i 45Qtz, 28Or, 24Pl, 3Bt U92 Pan de Azu´car 8Qtz, 80Or, 11Hbl U93 Santa Teresa 18Qtz, 63Mc, 10Pl, 9Bt U94 Isla Mala 42Qtz, lMc, 53Pl, 4Bt U95 Garzo´n Granite 46Qtz, 32Or, 6Mc, 13Pl, 3Bt U7 Moskart 41Qtz, 46Mc, 8Pl, lHbl, 2Festil, 2Op U74 La Paz 25Qtz, 60Mc, 7Pl, 7Bt, lHbl U76 Guazunambı´ 27Qtz, 15Or, 16Mc, 36Pl, 4Bt, lAug, ICal U88 Mahoma Red 41Qtz, 7Ort, 63Mc, 30Pl, 6Bt U15 Salmon Red 12Qtz; 71Or, 13Pl, 2Hbl, IChI, lFestil U46 Artigas Pearl 86Or, 5Pl, 4Hbl, 5Festil U47 Violeta Imperial 11Qtz, 67Or, 7Pl, 8Hbl, 1Lm, lAug, 2Op, 3Festil c 1408 Environ Earth Sci (2013) 69:1397–1438 123 Environ Earth Sci (2013) 69:1397–1438 1409 123 have never been mined. The black and gray colors are determined by a relatively high proportion of mafic min- erals (e.g., pyroxenes, amphiboles, opaque minerals). Bossi and Campal (1991) classified the dolerites according to their grain size and their black color quality. The most valuable dolerite is the Absolute Black variety (Fig. 10a), which is defined by its deep black color and a fine-grained subophitic texture. Its color is very homogeneous not only due its texture but also due to the lack of veins. It has only been found in a small proportion of the deposits in Group A (Morales Demarco et al. 2011). The dark gray variety, which is characterized by a medium-grained subophitic texture, is known as Moderate Black, Negro Oriental, or Sacramento (Fig. 10b) and is found in groups A and B. Its de´cor is sometimes interrupted by white spots due to the presence of millimeter-sized granophyric intergrowths. Light gray aplitic veins up to five centimeter in thickness are sometimes observable, but these can be easily avoided during the mining process. Mahoma Black is a dark gray fine- to medium-grained gabbro-norite (Oyhantc¸abal et al. 1990b). The presence of sulfides in this rock (Oyhantc¸abal et al. 1990b; Bossi and Schipilov 2007) limits its use as a dimensional stone to indoor applications, where weathering processes do not alter its color or change the petrophysical and petrome- chanical properties. The granitoids can be further classified according to two specific fabric features: grain size (fine, medium-, and coarse-grained) and the relationships between the mineral components (equigranular, porphyritic, etc.). The gray granitoids owe their color to the relatively high amount of limpid and gray feldspar, quartz, low amounts of mafic minerals, and the absence of iron hydroxides (e.g., limo- nite). They can be sub-classified into: (i) fine-grained (Cerro A´spero and Garzo´n), (ii) medium-grained (Cha- manga´, Cuchilla del Perdido and Cufre´), and (iii) very coarse-grained (Maldonado and Santa Teresa). Cufre´ Granite shows recrystallization of quartz grains and a gentle foliation. The coarse-grained granites also have a porphyritic texture with a preferred orientation of the phenocrysts (Muzio and Artur 1999; Oyhantc¸abal 2005). The Uruguayan red granites show a color range between carmine red and carmine pink, with small variations within a same variety. The red color in granitoids has been related to the presence of ferric iron oxides in the alkali feldspars, especially hematite (Boone 1969; Taylor 1977; Nakano et al. 2002; Putnis et al. 2007; Plu¨mper and Putnis 2009). Plu¨mper and Putnis (2009) studied the re-equilibration of feldspars in the presence of a fluid phase in gray and red stained granites from southeast Sweden. They determined a three stage feldspar replacement within these rocks: (i) the first stage consists of a replacement of original microcline by oligoclase due to fluid circulation (in the late magmatic stage) with a concomitant porosity development within the oligoclase; (ii) a second stage is characterized by the cir- culation of Na-enriched hydrothermal fluid leading to a replacement of the oligoclase by albite and sericite for- mation within the albite pores; and (iii) the third stage includes fracturing and infiltration of a K-rich fluid that causes the K-feldspathization of sericite and albite with hematite precipitation in the orthoclase pores that produces the red coloration. Table 5 Block volume calculated using different methods * Cufre´ Granite quarry data may not be representative of the whole deposit Quarries ID Block size Vb (m3) Singewald method Palmstrøm method Sousa method Sacramento Dolerite lower floor U8_lf 3.73 4.12 2.51 Sacramento Dolerite upper floor U8_uf 1.03 1.15 0.65 Maldonado Granite lower floor U2_lf 0.35 0.38 0.12 Maldonado Granite upper floor U2_uf 0.43 0.41 0.17 Chamanga´ Granite U4 13 12 8 Cerro A´spero Granite (quarry 193) U70_193 2.81 3.01 0.86 Cerro A´spero Granite (quarry 192) U70_192 6.16 6.84 3.27 Cufre´ Granite* U73 689 756 163 Moskart Granite U7 10.6 8.0 1.8 Salmon Red Syenite (quarry 075) U15_075 1.14 1.23 0.40 Salmon Red Syenite (quarry 079) U15_079 8.83 9.38 4.89 Artigas Syenite lower floor U46_lf 1.53 1.71 0.20 Artigas Syenite upper floor U46_uf 5.60 6.21 2.14 Artigas Syenite boulder zone U46_b 37.1 38.3 38.1 Violeta Imperial Syenite U47 2.64 2.78 0.47 1410 Environ Earth Sci (2013) 69:1397–1438 123 In all the Uruguayan red granites evidence of these feldspar replacements can be observed. In the Mahoma Red Granite, for example, the plagioclase contains sericite and calcite inclusions, as well as microcline relicts. The pla- gioclase is partially replaced by perthitic orthoclase and both feldspars show a red stain, probably due to precipi- tation of hematite (Fig. 11). The red granites are either medium-grained, with equigranular texture (Mahoma Red Granite, equigranular facies of the La Paz Granite) or medium to coarse-grained, with porphyritic texture (por- phyritic facies of the La Paz Granite, Preciozzi et al. 1985; Oyhantc¸abal et al. 1990a) and eventually show a slightly orientation of their phenocrysts (Guazunambı´ and Luja´n Granites). Moskart Granite is greenish-gray to brownish-gray and very coarse-grained (Fig. 11c, d), with small variations of color in the area of the deposit. Bossi et al. (1965) attributed its color to the growth of biotite and chlorite in the cleavage planes of microcline. On the other hand, Oyhantc¸abal et al. (1998) suggested that a secondary paragenesis (stilpno- melane, chlorite, calcite, and bluish green amphibole) related to the activity of the SYSZ generates the color. The rock actually shows evidence of similar feldspar replace- ment as described for the red granites but without the pre- cipiatation of hematite. It can also be observed in the gray non-commercial variety and the greenish-gray variety (commercialized as Moskart Granite) (Fig. 11c, d). The main difference between these two color varieties is not the proportion of the feldspar replacement. The greenish-gray color of the commercial variety (Moskart Granite) is related to the presence of microcracks filled by chlorite, sericite, calcite, and limonite. The differences in the distribution and proportions of these minerals determine the color variations observed in the quarries and in the commercialized Moskart Granite varieties. All these granites can show structural elements that disrupt their de´cor. The most frequent disruptions are due to mafic enclaves, biotite accumulations, mafic and aplitic dikes, schlieren, synmagmatic and convolute layering. As already described and illustrated by previous authors (Comunita` Economica Europea—Uruguay no date, Bossi and Navarro 2000; Oyhantc¸abal et al. 2007) the colors of the syenitoids are dark salmon, pink salmon, and terracotta with white spots (Salmon Red), pale red–violet (Violeta Imperial), and light gray with black spots (Pan de Azu´car White). Artigas Pearl shows a distinct de´cor and color, where bluish-gray feldspar crystals (up to 35 mm), some- times showing iridescence, are surrounded by a pink to intense crimson rim in their contact with the agglomera- tions of mafic minerals (up to 1 cm). This kind of color combination is relatively seldom in magmatic rocks. It optically attenuates and softens the intense coarse-grained texture, so that this rock will be preferably used for eye- catching applications such as countertops and fac¸ades. In these rocks the same feldspar replacements are observable as in the red and greenish-gray granites (Fig. 11e–h). Other evidences of hydrothermal alteration are the presence of biotite partially altered to chlorite, epidote, and calcite (e.g., in the Red Salmon Syenite). Salmon Red, Violeta Imperial, and Pan de Azu´car White are coarse-grained, whereas Artigas Pearl is very coarse- grained and has a porphyritic texture (Fig. 11e, f). The texture is seriated in Salmon Red (Fig. 11g, h), Violeta Imperial, and Pan de Azu´car White syenitoids, with feld- spar crystals between 4 to 15 mm in size. All the syenitoid deposits show occurrences of narrow schlieren (up to 5 mm), thin mafic dikes, or aplitic veins, but only the Salmon Red and Violeta Imperial contain mafic enclaves. Due to the special de´cor of these rocks, small changes in mineralogy and alteration (hydrothermal and weathering) can lead to very visible changes in color and fabric. The case of the Artigas Pearl is a good example, since its de´cor varies from the more typical variety (Fig. 12a) to the very intense red or darker gray varieties (Fig. 12b, c), which modifies the market value of this rock. Petrophysical and petromechanical properties The potential uses of the dimensional stones can be deduced from their physical and mechanical properties, which in turn are closely related with their petrography and degree of weathering. As discussed in detail in numerous publications (See Siegesmund and Dahms 1994; Stroh- meyer 2003; Ru¨drich 2003; Koch 2005; Hoffmann 2006; Mosch 2008), the majority of the rocks when considering their fabric are anisotropic, and therefore, some of their physical properties are directionally dependent. In order to identify possible anisotropies these properties were mea- sured in three orthogonal directions. In the following sub- chapter just their mean values will be discussed. All the other data are listed in the appendix (Tables A.1–A.4). Density and porosity The bulk density of the Uruguayan commercial granites, measured using the Archimedes method, as described in Monicard (1980), vary from 2.61 g/cm3 for the Salmon Red Syenite and 3.02 g/cm3 for the Moderate Black Dol- erite (Table A1). All other Uruguayan commercial granites are in the above given range and in accordance with the values given in the compilation by Mosch and Siegesmund (2007) (Fig. 13a) and Siegesmund and Du¨rrast (2011). The mafic rocks show the higher matrix density values Environ Earth Sci (2013) 69:1397–1438 1411 123 determined by the higher proportion of heavier elements (mainly iron, calcium, and titanium) forming minerals such as plagioclase, mafics, and opaque minerals. The granitoids and syenitoids have lower amounts of these elements and higher proportions of the lighter elements (such as silicon and sodium), and therefore, show lower matrix densities. 1412 Environ Earth Sci (2013) 69:1397–1438 123 The water that a dimensional stone is capable to absorb and retain in the pore spaces, as well as its mobility within the pore network plays an important role in the weathering process and the petrophysical behavior (Peschel 1977; Weiss 1992; Siegesmund and Du¨rrast 2011). Porosity, pore radii distribution, water uptake and capillary water uptake, and water vapor diffusion were determined in the samples studied to evaluate their durability when applied for con- structive purposes (Table A.1). The porosity was also measured by the method descri- bed in Monicard (1980). In respect to this property all the mafic rock and syenitoid samples analyzed are outliers in the distribution of their respective groups as determined by the statistical compilation of Mosch and Siegesmund (2007) (Fig. 13b). The lower values, between 0.03 and 0.12 %, are registered by the dolerites (e.g., Absolute Black). They have a very compact fabric, where the interstitial space of the fine-grained subophitic texture is completely filled by granophyric intergrowths. The Arapey Basalt with a similar fabric shows a porosity of 0.98 %, the highest value in the mafic rock group. This fact is con- sidered to be a consequence of the relatively altered or weathered condition of the Arapey Basalt samples studied as indicated by the presence of limonite and microcracks in plagioclase and pyroxene. The granitoids have intermediate porosities, showing values between 0.27 (Chamanga´ Gray Granite) and 0.80 % (Cerro A´spero Granite). The syenitoids show the highest porosity values of the different commercial granites considered, where the highest porosity value was registered by the Violeta Imperial Syenite: 1.34 %. This rock, as in the other syenitoids studied, shows a more open interstitial space, where the feldspars show a com- plex replacement history (e.g., relict microcline in pla- gioclase showing albitization). The matrix is composed of a mixture of amphibole, pyroxene, chlorite, ferristilpno- melane, and epidote, which indicates hydrothermal alteration and accounts for the higher porosity values measured. The pore size distribution determined by mercury injection porosimetry shows a low variation between the different groups considered (Table A1). The porosity of the dolerites is so small that the pore radii distribution is dif- ficult to measure; these rocks have mean pore size values between 0.032 (Arapey Basalt) and 0.209 lm (Pimafox Oriental Dolerite). Granitoids and syenitoids show a simi- lar mean pore size, e.g., the fine-grained variety Cerro A´spero Gray has an average pore radius of 0.09 lm and Artigas Pearl Syenite 0.08 lm. The most frequent pore radii are also very similar between all the rocks analyzed: between 0.008 (Artigas Pearl Syenite and Moskart Granite) and 0.335 lm (Violeta Imperial Syenite). The pore size distribution has a significant influence on the water uptake and the capillary water uptake. The capillary water absorption, which was determined following the DIN EN 13755 (2008) and DIN EN 12670 (2001) is the main mechanism acting in pores with a radius between 0.1 lm and almost 1 mm (Siegesmund and Du¨rrast 2011). Since there is no water circulating in the pores the interactions between the rocks and the building materials (e.g., mortar) are insignificant, as well as the weathering processes that leads to the decay of the com- mercial granites. This is especially true for the dolerites and granitoids, which show extremely low porosity and capillary water absorption. The water absorption (or water uptake) of the studied commercial granites is very low, in accordance with the very low porosity (Table A.1). The dolerites show extre- mely low unforced water absorption values between 0.01 and 0.03 wt%, whereas the basalt has 0.28 wt% due to its higher porosity. The granitoids show intermediate values between 0.07 and 0.27 wt% and the syenitoids between 0.30 and 0.43 wt%. Water absorption values for granites are between 0.1 and 1.5 wt% (Peschel 1977). The DIN 52008 defines that rocks with water absorption at atmospheric pressures (or unforced water absorption) less than 0.5 wt% are weathering resis- tant, as is the case for all Uruguayan commercial granites. Fine-grained gray granites like the Cerro A´spero Gray (U70) are in demand because of their low water absorption (0.12–0.09, See Table A.1). The market for this kind of rock is led by the Chinese commercial granite Padang Light (G3533/G633). The data available for this granite are doubtful (Bo¨rner and Hill 2010) and lower (0.36 wt%; Table A.1) than in the unpublished reports from different Chinese providers, where the water absorption of Padang Light Granite ranges from 1.5 to 3.0 wt%. The comparable granite from Uruguay, Cerro A´spero Granite, develops a lower amount of staining or spots due to its lower water absorption. Fig. 11 Thin section images of colored commercial granites. a Ma- homa Red Granite (U88) in cross polarized light (CPL), Or has partially substituted Pl, as evidenced by sericitization in the center of the image; b close-up of the previous image where Mc relicts partially surrounded by Cal are recognized in new formed Or; c gray variety of Moskart Granite in CPL, Pl with intense sericitization, and relicts of Mc; d Moskart Granite (U7) in CPL, Qtz, Mc, and Pl compose the rock, intra and intercrystalline microcracks are filled by Chl, Bt, Ser, Cal, and Lm; e Artigas Pearl Syenite (U46) in plane polarized light (PPL), observe the reddening of Or crystals in contact with ferromagnesian agglomerations; f same as e but in CPL; g Salmon Red Syenite (U15) in PPL, Pl with sericitization and partially altered to Or, in top of image Bt partially altered to Chl, and numerous Op grains; and h same as g but in CPL. Abbreviations after Kretz (1983) except the ones marked with asterisk: Ab albite, Amph* amphibole, Aug augite, Bt biotite, Cal calcite, Chl chlorite, Festil* ferristilpno- melane, Gr. Int.* graphic intergrowth, Hbl hornblende, Lm limonite, Mc microcline, Ms muscovite, Op* opaques, Or orthoclase, Pl plagioclase, Qtz quartz; *Ser sericite b Environ Earth Sci (2013) 69:1397–1438 1413 123 The saturation coefficient S is the relation between the unforced water absorption and the forced water absorp- tion, as defined by Hirschwald (1912). The author related this value with the capacity of a rock to resist weathering and freezing. All Uruguayan commercial granites show a very high S value, but as described in Siegesmund and Du¨rrast (2011), this coefficient has little application in the case of plutonic and metamorphic rocks with a bulk density higher than 2.6 g/cm3. This assumption is derived from the fact that the porosity of these rocks tends to be very low, and therefore, their capacity to interact with water. This lack of interaction between the rock and water leads to a better rock stability against weathering and freezing. Water vapor diffusion The highest vapor diffusion value indicates the higher resistance of the rock to the transmissivity of water, therefore the lowest permeability. The dolerites show the highest mean values, between 5,472 for Moderate Black and 6,713 (dimensionless) for Absolute Black (Table A.2). Granitoids and syenitoids show similar values, with the exception of the Maldonado Granite, which has the lowest value of 83 in the x-direction due to its fabric anisotropy. The other rocks in these groups show values between 374 (Moskart Granite) and 1,508 (Salmon Red Syenite). The values obtained in the present research for granitoids and syenitoids are in the range of those published by Fig. 12 Different colors and de´cors in the Artigas Pearl Syenite (slab length = 10 cm) 1414 Environ Earth Sci (2013) 69:1397–1438 123 Siegesmund and Du¨rrast (2011) which measured values between 811 and 3,869 for plutonic rocks. In applications where the water vapor diffusion can have an impact, such as fac¸ades and fountains, the anisotropy of this petrophysical property should be taken into account. One example is the Maldonado Granite, which has an anisotropy of 1:3:3 in the x-, y-, and z-direction. Therefore, considering the direction of the cut is necessary. Ultrasonic wave velocities In addition to the static Young’s modulus, it has become commonplace to determine the dynamic Young’s modulus by measuring the ultrasonic velocity for evaluating the degree of structural damage in dimensional stones (Ko¨hler 1991; Siegesmund and Du¨rrast 2011). Under dry conditions the Vp (compressive waves) velocities should be above 5 km/s in unweathered granitoids (Illiev 1967). The Uruguayan commercial granites show ultrasound velocities (Vp) between 3.38 km/s (Cerro A´spero Granite in z-direction) and 6.49 km/s (Moderate Black Dolerite in y-direction). The mafic rocks show the higher ultrasound values, between 5.41 and 6.49 km/s and the granitoids and syenitoids intermediate ones, between 3.38 and 5.85 km/s. The only samples showing anisotropy values higher than 10 % are Maldonado Gray Granite, with around 10 % anisotropy and around 21 % in the Cerro A´spero Gray Granite. Sampling was carried out in quarries, exclusively in fresh rocks, with the exception of the Arapey Basalt, where this was not possible. The values presented here can be used as standards for comparative measurements of fresh and unweathered rocks. Dolerites show the most remarkable values, where the anisotropy is very low (2–3 %) as indicated by the homogeneous fabric in these rocks. Fig. 13 Box plots of some petrophysical properties of commercial granites worldwide (redrawn after Mosch 2008) and Uruguay (each colored dot represents an average value) a bulk density; b porosity; c uniaxial compressive strength (UCS); d flexural strength; and e tensile strength Environ Earth Sci (2013) 69:1397–1438 1415 123 Thermal expansion Numerous dimensional stones have a weathering sensitiv- ity/vulnerability against thermal stresses, caused by an expansion of the material at high temperatures and a con- traction with subsequent cooling. The thermal expansion is essentially controlled by the mineralogical composition and fabric of the rock (Koch and Siegesmund 2004; Koch 2005; Siegesmund et al. 2008). In granites the thermal expansion and its associated processes (e.g., progressive microcracking leading to bowing) are more complex than in marbles. This is mainly due to the monomineralogical composition of marbles (calcite or dolomite), in contrast to granites that have at least three minerals present or generally more. Each min- eral has a different thermal expansion and some of them are anisotropic with respect to this property. Quartz has the lowest thermal expansion coefficient (a) parallel to the c-axis (7.7 9 10-6 K-1) and the highest perpendicular to it (a = 13 9 10-6 K-1) (Siegesmund et al. 2008). Biotite is also anisotropic with (a = 17.3 9 10-6 K-1) parallel to the c-axis and 9.7 9 10-6 K-1 perpendicular to it (Sieg- esmund et al. 2008). High plagioclase contents lead to low a values, due to the extremely small volume expansion of this mineral (Weiss et al. 2004). Castro de Lima and Paraguassu´ (2004) analyzed the thermal expansion coefficient (a) of 19 commercial gran- ites and concluded that an increment in porosity leads to a decrease in a, whereas an increment in grain size or quartz content increases a. These authors also analyzed the directional dependency of a, concluding that for the sam- ples studied there is no dependency. The thermal expansion coefficient (a) for the commer- cial granites varies from 5.74 (Artigas Pearl in the x-direction) to 9.47 9 10-6 K-1 (Moskart in the y-direc- tion) (Table A.2). The range of values obtained is compa- rable with those reported for magmatic rocks by Strohmeyer (2003), Hoffmann (2006), Weiss et al. (2004), Siegesmund et al. (2008), and Va´zquez et al. (2011). The mafic rocks show the lowest mean a, since these rocks show the lowest Fig. 14 Statistical values of some petrophysical properties of com- mercial granites worldwide (gray dots and ellipses after Mosch (2009). The ellipses represent 80 % of the expected values for each rock group) and Uruguay (each colored dot represents an average value of a commercial granitic stone) a bulk density versus uniaxial compressive strength (UCS), b porosity versus uniaxial compressive strength, c bulk density versus flexural strength, and d porosity versus flexural strength 1416 Environ Earth Sci (2013) 69:1397–1438 123 mean grain size and quartz content, and the highest pro- portion of plagioclase. Granitoids show the highest mean a value and the highest quartz content. The syenitoids, with intermediate a values, show a low proportion of quartz and the highest porosity values. These relationships are in accordance with the observations made by Castro de Lima and Paraguassu´ (2004) and Va´zquez et al. (2011). Generally, the samples show anisotropies lower than 11 % in their thermal expansion, but there are two cases where higher anisotropies were measured: Artigas Pearl Syenite (15 %) and Moskart Granite (18 %). Both com- mercial granites are very coarse-grained. A similar behavior was reported by Va´zquez et al. (2011) in three coarse- to very coarse-grained commercial granites. Differential deterioration can occur in light-colored granitoids with dark-colored enclaves or xenoliths due to the albedo effect or differential thermal response to inso- lation (Go´mez-Heras et al. 2006; Steiger et al. 2011). The deterioration will generally be expressed by the spalling of enclaves or xenoliths (Go´mez-Heras et al. 2006). The thermal expansion behavior of a dimensional stone is closely related to its bowing behavior when applied as slabs for outdoor fac¸ade cladding (Siegesmund et al. 2008; Va´zquez et al. 2011). For bowing the same factors influ- encing thermal expansion are relevant: coarse- to very coarse-grained texture, mineral shape-preferred orientation and porosity (Va´zquez et al. 2011). When considering a building application with thermal exposure from one direction (e.g., fac¸ades), the rocks showing a high anisotropy in thermal expansion and flex- ural strength should be used in the most favorable direction (the one showing higher resistance to deterioration pro- cesses). The potential bowing behavior of a commercial granitic rock must be examined prior to its use as a building element. Petromechanical properties Uniaxial compressive strength (UCS) According to Mosch and Siegesmund (2007), uniaxial compressive strength (UCS) values in plutonic rocks vary from 60 to 292 MPa; the values for the gabbro-diorite subgroup are always in the upper quartile (Fig. 13c). In Fig. 15 a Stereogram of the Salmon Red Syenite deposit; b theoretical model of the joint sets affecting the Salmon Red deposit; c raw block resulting from the presence of the joint sets and possible block resulting from its squaring; d stereogram of the Moskart Granite deposit; e theoretical model of the joint sets affecting the deposit; and f raw block and finished block as a result of squaring Environ Earth Sci (2013) 69:1397–1438 1417 123 Uruguayan commercial granites, whose UCS was deter- mined following the DIN EN 12372 (1999), the same behavior can be observed (Table A.3; Fig. 13c). Absolute Black Dolerite shows an extremely high value of 369 MPa, whereas the mafic rock with the lower UCS value is the Arapey Basalt with 228 MPa. The granitoids belong to the granite and granodiorite–tonalite groups determined by Mosch (2008). They show higher UCS values than the median for both groups, for some granite this value is higher than the upper quartile (197 MPa for Cuchilla del Perdido and Cerro A´spero Granites). The syenitoids (monzonite-syenite group of Mosch 2008) also show higher or similar values that the median for this group, with the exception of the Artigas Pearl Syenite that has an UCS value lower than the lower quartile (137 MPa). The only rock analyzed showing a distinct rock fabric and a stretching lineation is the Maldonado Granite (Oyhantc¸abal 2005). However, this rock also shows no anisotropy in the compressive strength. Young’s modulus The maximum Young’s modulus E value is 32.9 GPa for the Absolute Black Dolerite in the x-direction and in the y- direction for the Chamanga´ Gray Granodiorite (Table A.3). The Cuchilla del Perdido Granite shows the lowest value: 11.9 GPa in the z-direction. A general trend, similar to that described by Hoffmann (2006), can be observed in the relationship of the Young’s Modulus E and the UCS. The samples that have the higher UCS also have the higher Young’s Modulus E. Indirect tensile strength The indirect tensile strength values for all commercial granites considered are lower than the lower quartile determined by Mosch (2008) and most of the values are outliers in the normal statistical distribution (Fig. 13e). The higher values are those of the mafic rocks, where the dol- erite Absolute Black has the highest value (17.9 MPa), followed by Moderate Black and Pimafox dolerites, with 15.6 and 14.5 MPa, respectively. Artigas Pearl Syenite shows the lowest value (5.8 MPa), followed by Moskart granite (7.7 MPa) (Table A.3). Flexural strength Comparing the flexural strength values, determined according to the DIN EN 12372 (1999), with those of Mosch (2008) (Fig. 13d), it can be seen that the dolerites lie far above the highest values, being outliers in the dis- tribution determined by the aforementioned author. The granitoid groups show values that are either higher than the upper quartile (Cuchilla del Perdido and Maldonado granites, with 20.2 and 20.4 MPa, respectively) or lower than the lower quartile (Moskart Granite, with 8.3 MPa) (Table A.4). Chamanga´ Granodiorite shows a flexural strength that is higher than the upper quartile (20.4 MPa). Fig. 16 Block sizes of the different quarries analyzed using three different methods Singewald (1992), Palmstrøm (1982, 1996, 2001), and Sousa (2010) 1418 Environ Earth Sci (2013) 69:1397–1438 123 The syenitoid group shows very different values. Salmon Red is in the upper quartile (15.6 MPa), the Violeta Imperial value is lower than the lower quartile (10.0 MPa), and Artigas Pearl is 8.3 MPa. Breaking load at dowel hole Values obtained for breaking load at the dowel hole (DIN EN 13364 2002) vary between 1.8 kN (Moskart Granite) and 4.7 kN (Absolute Black Dolerite) (Table A.4). Mafic rocks show the highest values, followed by the granitoids with the exception of Moskart Granite and then the sye- nitoids, with the lowest values, in particular Artigas Pearl Syenite with 1.9 kN. Due to its fabric anisotropy, the Maldonado Granite was tested in three different directions according to the standard procedure. It shows a variation between 2.8 (Type IIa, dowels parallel to foliation) and 3.5 kN (Type IIb, dowels perpendicular to foliation). Accord- ing to the data of Rohowski (2001), mafic rocks can be compared with mafic volcanics and tephrite (basalt lava) with breaking load values around 4 kN. The granitoids and syenitoids can be compared with the granite and gneiss of Rohowski (2001), with values around 3 kN. A slab with a thickness of 30 mm composed of coarse- grained or very coarse-grained granitoids or in particular syenitoids, can eventually be represented by only two or three crystal grains. This kind of slab can thus have a limited strength (flexural, indirect tensile and compressive strengths, and breaking load at the dowel hole) and durability. Abrasion strength The abrasion strength was determined as described in the DIN 52108 (1988). The lower values of abrasion strength show the higher resistance of the rock to abrasion, therefore the rock most resistant to abrasion is the Pimafox Dolerite, with a value of 2.1 cm3/50 cm2 (Table A.4). The less resistant rock is Arapey Basalt, with a value of 3.8 cm3/ 50 cm2. All Uruguayan commercial granites have lower values than those discussed in the literature (Peschel 1977; Strohmeyer 2003; Siegesmund and Du¨rrast 2011). The difference in the mechanical strength values observed between the various rocks considered can be explained by the fact that they differ in their mineralogical composition and fabric (Strohmeyer 2003). The mafic rocks show the highest strength values and this is related to specific characteristics of their fabric that make them more resistant: a fine- to medium- grain size, subophitic texture, and in the case of the dolerites the graphic intergrowth that seals the interstitial spaces between the crystals making the rock very cohesive. This is well illustrated when comparing the UCS and flexural strength values with the bulk density and porosity (Fig. 14).T a b le 6 W o rl d w id e k n o w n co m m er ci al g ra n it es (S o u rc e B o¨ rn er an d H il l 2 0 1 0 , ex ce p t v al u es m ar k ed w it h * S tr o h m ey er 2 0 0 3 ) S am p le O ri g in L it h o lo g y D e´c o r* * P et ro g ra p h y (% ) D en si ty (g /c m 3 ) U C S (M P a) F le x u ra l st re n g th (M P a) W at er ab so rp ti o n (w t% ) R ef er en ce o b je ct S h an x i B la ck (G 1 4 0 1 ) C h in a D o le n te B la ck , F G 3 .0 4 3 5 0 0 .3 3 D u¨ ss el d o rf A ir p o rt Im p al a D ar k S o u th A fr ic a G ab b ro /N o ri te D ar k g ra y , F G – M G 3 2 9 0 – 3 0 0 0 .1 B u n d es p ra¨ si d al am t in B er li n P ad an g H el l o r G 3 5 3 3 C h in a G ra n it e L ig h t g ra y , F G 2 .6 3 1 1 7 .6 1 5 .3 0 .3 6 ? K u ru G ra y F in la n d G ra n it e M id d le g ra y , F G 3 5 Q tz , 3 6 O r, 2 1 P l, 8 A cc 2 .6 6 2 9 4 – 2 9 7 2 4 .5 – 2 5 0 .1 1 S er iz zo A n ti g o ri o * It al y G n ei ss D ar k g ra y – b la ck , M G 3 2 Q tz , 1 1 K fs , 3 8 P l, 1 3 B t, 5 M s, 1 C h l, ac c: E p , tu r* 2 .7 2 * 1 6 9 * 1 4 – 1 7 0 .3 4 – 0 .3 9 B ia n co S ar d o It al y G ra n it e L ig h t g ra y , C G 2 .5 8 – 2 .6 2 1 5 9 – 2 1 3 1 2 – 1 4 0 .5 8 K o¨ ln m es se , C o lo g n e V er d e B u tt er fl y B ra zi l M o n zo n it e G re en , v C G 5 0 O r- p er t, 3 0 O lg , 1 2 Q tz , 8 O p x 2 .6 7 1 0 1 9 0 .1 5 F la sh B lu e In d ia A n o rt h o si te D ar k g re en , v C G 6 5 1 6 0 .4 R o sa S an ta E u la li a P o rt u g al G ra n it e G ra y – P in k , M G -C G 2 .6 4 1 6 5 – 1 6 7 2 0 0 .1 6 R o sa v el S p ai n Q u ar z– S y en it e P in k , v C G 2 .6 3 – 2 .6 5 6 2 – 6 3 1 7 – 1 8 0 .7 H o to -T o w er . Z ag re b . C ro ac ia M ar ro m G au ch o B ra zi l S y en it e B ro w n . M G 2 . 6 0 – 2 .6 5 1 5 8 – 2 0 4 1 0 W as h in g to n P la za in P ar is A b b re v ia ti o n s af te r K re tz (1 9 8 3 ) ex ce p t th e o n es m ar k ed w it h as te ri sk : A cc * ac ce so ri es , B t b io ti te , C h l ch lo ri te , E p ep id o te , K fs K fe ld sp ar , M s m u sc o v it e, O lg * o li g o cl as e, O p x o rt h o p y ro x en e, O r o rt h o cl as e, O r- p er t* p er th it ic o rt h o cl as e, P l p la g io cl as e, Q tz q u ar tz , T u r to u rm al in e Environ Earth Sci (2013) 69:1397–1438 1419 123 Generally, the very coarse-grained rocks show the lowest strength values; this is the case in the Moskart Granite and Artigas Pearl Syenite. This is probably related to the presence of microcracks and the cleavage of the large alkali feldspar present in these rocks. The strength of a rock can also be correlated with the apparent density and effective porosity: the higher density of a rock and the lower its porosity determines higher strength values (Morales Demarco et al. 2007; Mosch 2008). This corre- lation can be observed in all commercial granites consid- ered in the present study (Fig. 14). Deposit characterization The evaluation of the mineral deposit was carried out fol- lowing the International Framework Classification of the United Nations/UNFCR (UN 2009). The classification is based on three categories: (i) degree of favorability of social and economic conditions (e.g., market prices, relevant legal, and environmental conditions) (E-axis); (ii) maturity of studies and commitments to implement mining plans that determine the feasibility of the mining project (F-axis); and (iii) level of confidence in the geological knowledge and potential recoverability of the quantities (the G-axis). Com- mercial projects are the ones feasible from a technical, eco- nomic, and social point of view. Dimensional stone deposits are not representative of typical mineral deposits as for example massive mineral deposits (construction aggregates, e.g., sand, gravel). The industrial requirements in de´cor and block volume (or size, or dimensions) determine the selection of a section inside a deposit, in which these requirements are achieved and are at the same time demanded by the market (Stein 2007). Basically, some aspects of the evaluation of aggregate deposits can be applied in the case of dimensional stones (Kelter et al. 1999). An example is the application of mining techniques (e.g., diamond wire saw) that have proved to be effective in comparable dimensional stone deposits. The geological and mining knowledge of the analyzed deposits exhibits a highly differentiated state of the art. This ranges from a general assignment of a lithological unit (Cu- chilla del Perdido Granite) to many years of geological investigations in active mining districts (dolerite deposits, e.g., Moderate Black Dolerite U8, U11O, U66). Both the growth of the international market for dimensional stone and the industrial development in the production requires more intensive research into the feasibility of mining the deposits: (1) The selection of the de´cor, especially the color is determined by international trends, which are not constant. Some trends are cyclical for decades, but others are acyclical. Rocks with colors outside of the prevailing trend are temporarily or only partially usable (e.g., the pink facies of Artigas Pearl Syenite). (2) The dimensional stone raw blocks are processed mainly in industrial plants. For this purpose the blocks must have, on one hand, an orthogonal form (Fig. 15) and a minimum size, and on the other hand the choice of the block size is often related to the optimal utilization of the resource related to the size of the end product (e.g., block size between 3.5 and 9 m3). (3) Due to modern requirements for the use and con- struction of buildings, rocks with the same color and de´cor will be chosen for a technical function in accordance to their maximum resistance of a selected property (e.g., rocks with high abrasion resistance as floor slabs). The effects of the above-mentioned international market mechanisms were directly decisive for the development of the natural stone industry in Uruguay in the last 20 years. Fig. 17 Stereograms (equal area projection, lower hemisphere) showing the measured joints using Stereo Net a Arapey Basalt from the Cerro del Estado quarry (contours 1, 2, 3, 4, 5 times uniform distribution: t.u.d.); b Cerro A´spero Granite quarries (contours 1, 2, 3, 4, 5, 6 times uniform distribution); c Sacramento Dolerite from the Rosarito quarry (contours 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 t.u.d.); d Moskart Granite (contours 1, 2, 3, 4, 5 t.u.d.); e Artigas Syenite (contours 1, 2, 3, 4, 5, 6, 7 t.u.d.); and f Violeta Imperial (contours 1, 2, 3, 4, 5 t.u.d.) 1420 Environ Earth Sci (2013) 69:1397–1438 123 Because of its natural conditions (climate), the country could not follow the international trend toward yellow dimensional stones in the years 1995–2006. This particular color is due to limonitic alteration of the rocks (a charac- teristic of tropical countries), which, nevertheless, retain their essential petrophysical properties. The rocks offered did not fulfill the international trend and their business volume significantly declined. Only the timeless de´cor and color offered by the dark gray to black dolerites occupy a permanent place on the international market. Even this segment needs qualitative development to be able to compete with the blocks offered from Northern China and India exhibiting larger dimensions. The criteria for deposit profitability require geologic studies that can determine the following controlling elements: (1) An inventory of the joint sets to determine the frequency of minimum dimension of exploitable blocks to achieve the optimal block size for the industry, as well as to minimize the waste material. Fig. 18 Rosarito dolerite quarry a general view of the upper and lower floor; b joint set frequency of the upper floor; c joint set frequency of the lower floor; d median block volume of the upper floor; and e median block volume of the lower floor Environ Earth Sci (2013) 69:1397–1438 1421 123 (2) Mineralogical and structural factors that influence the formation, stability, and variability of the fabric and color. (3) Factors of the genesis of the deposit, as well as the influence of alteration, which causes an impact on the relevant petrophysical properties, that favor or limit the usability. Block sizes For the evaluation of the yield of a quarry, the block sizes must be estimated. This can be done as described by Singewald (1992), Palmstrøm (1982, 1996, 2001), and Sousa (2010). All these authors use the joint set frequency to estimate the mean or median block sizes. Singewald (1992) method is the less complex to use, since it calculates Vb (block volume) by multiplying the average distribution of three main joint sets (See Eq. 1). Palmstrøm (1982, 1996, 2001) uses the Jv (volumetric joint count) (See Eq. 2) and b (block shape factor; Eq. 3) for calculating Vb (See Eq. 4). Sousa (2010) uses Jmed (median volumetric joint count) (See Eq. 5); the block volume was calculated afterward using (Eq. 4). The parameters x, y, z and S1, S2, S3 are the distances between the different joints that Fig. 19 3D model of the Maldonado Granite made using 3D Block Expert a section of the quarry modeled (total volume 191 m3), some joints are marked in red, yz-plane is the foliation plane, scale in meters; b, c 3D view of the section modeled; d stereogram of the Maldonado quarry with walls of section modeled in blue (x) and green (y); e joint frequency histogram of the quarry; and f raw block volume distribution using 3D Block Expert 1422 Environ Earth Sci (2013) 69:1397–1438 123 compose a joint set, and a1, a2, and a3 the angles between these joint sets. Vaverage ¼ xaverage  yaverage  zaverage ð1Þ Jv ¼ 1=S1 þ 1=S2 þ 1=S3 ð2Þ b ¼ a2 þ a2  a3 þ a3ð Þ3= a2  a3ð Þ2 ð3Þ Vb ¼ b  Jv  3  1=Sin a1  Sin a2  Sin a3 ð4Þ Jmed ¼ 1=S1med þ 1=S2med þ 1=S3med ð5Þ The three methods were applied in several Uruguayan quarries and different block sizes were obtained (Table 5; Fig. 16). Table 6 shows that the Sousa (2010) is the most conservative estimation, since it uses the median and not the average joint spacing as the other methods. For all the cases analyzed the joints were measured and afterward their spacing, taking into account to which joint set they belong. The orientations of the joints are shown in the stereograms in Fig. 17. When possible, the joint sets as well as their spacing in more than one floor were measured. In the case of the Artigas Pearl syenite quarry, the boulder zone at the top of the deposit was also measured (U46_b). The sizes of these boulders are greater than the average and median blocks calculated using the equations above for the floors in the quarry itself (Table 6). In the case of the Rosarito dolerite quarry, block sizes in the lower floor are higher than in the upper floor, since the joint density is also higher in the upper floor (Fig. 18). Fig. 20 3D model of the Salmon Red Syenite made using 3D Block Expert a section of the quarry modeled (total volume 396 m3) with some of the joints marked in red, scale in meters; b, c 3D view of the section modeled; d stereogram of the Maldonado quarry with walls of section modeled in blue (x) and green (y); e joint frequency histogram of the quarry; and f raw block volume distribution using 3D Block Expert Environ Earth Sci (2013) 69:1397–1438 1423 123 In the Maldonado Granite and especially in the Artigas Syenite the opposite occurs. A possible explanation for this abnormal behavior can be found in the two-stage landform development model proposed by Bu¨del (1957) and described by Twidale (2002). In the first stage, surface rock is affected by the weathering of the materials around the joints, and boulders start to form. Weathering then proceeds downwards into the subsurface, where the meteoric water stays longer in contact with the rock. In the second stage, the regolith between the joints of the surface is transported, but not with the regolith of the subsurface. Weathering can proceed more intensely in the subsurface since water is available. Fig. 21 a, c, e, g Cufre´ Granite quarry; b, d, f, h Cerro A´spero Granite quarry number 192. a, b Block deposit; c, d Block sizes measured directly in the quarries; e, f joint set distribution; and g, h Plausible block sizes being obtained in the quarries studied 1424 Environ Earth Sci (2013) 69:1397–1438 123 T a b le 7 S u m m ar y o f li th o lo g ic al , m in er al o g ic al , an d p et ro p h y si ca l as p ec ts ; d et er io ra ti o n ri sk s; an d p o ss ib le m ar k et s fo r U ru g u ay an co m m er ci al g ra n it es (* d at a fr o m C E E -U ru g u ay n o d at e, Q 1 , Q 2 an d Q 3 v al u es fr o m M o sc h 2 0 0 8 ) Id C o m m er ci al n am e R o ck D e´c o r P et ro p h y si ca l p ro p er ti es D et er io ra ti o n ri sk s U se s* * * C o n cl u si o n fo r ec o n o m ic al as p ec t P ri ce ra n g e (U S $ F O B ) M o d al an al y si s (v o l% ) C o lo r F ab ri c* * U C S F le x . p o r. U 1 1 A A b so lu te B la ck D o le ri te 3 7 P l, 3 3 A u g , 2 0 G r. in t. , 9 O p B la ck F G , H M [ Q 3 [ Q 3 \ Q 1 – IA H ig h v al u e, in te rn at io n al m ar k et 1 ,2 0 0 – 1 ,7 0 0 U 1 1 O M o d er at e o r O ri en ta l B la ck D o le ri te 4 1 P l, 2 9 A u g , 3 H b l, 2 2 G r. in t. , 5 O p D ar k G ra y M G , H M – H T [ Q 3 [ Q 3 \ Q 1 – IA H ig h v al u e, in te rn at io n al m ar k et 9 0 0 – 1 ,2 0 0 U 6 6 P im af o x o r O ri en ta l B la ck D o le ri te 4 7 P l, 4 2 A u g , 6 G r. in t. , 1 O p D ar k G ra y M G , H M – H T [ Q 3 [ Q 3 \ Q 1 – IA H ig h v al u e, in te rn at io n al m ar k et 9 0 0 – 1 ,2 0 0 U 8 7 M ah o m a B la ck G ab b ro /n o ri te B la ck M G , H M – H T – – – S u lfi d es I In te rn al m ar k et 8 0 0 – 1 ,2 0 0 U 4 9 A ra p ey B la ck B as al t 3 Q tz , 4 0 P l, 3 1 A u g , 1 7 L m , 9 O p D ar k G ra y F G , H M Q 3 – [ Q 3 W ea th er ed IA In te rn al m ar k et 2 5 0 – 3 5 0 U 2 M al d o n ad o G ra n it e 5 1 Q tz , 3 4 M c, 1 0 P l, 5 B t G ra y (P in k ) C G , H M – H T [ Q 3 [ Q 3 Q 1 – IA In te rn al m ar k et , h ig h re si st an ce p av in g 2 0 0 – 3 0 0 U 4 C h am an g a´ G ra n o -d io ri te 3 1 Q tz , 9 O r, 7 M c, 3 8 P l, 1 5 B t G ra y M G , H M – H T Q 3 [ Q 3 \ Q 1 – IA In te rn al m ar k et 2 0 0 U 5 3 C u ch il la d el P er d id o G ra y B lu e G ra n it e 3 3 Q tz , 2 6 O r, 2 9 P l, 1 0 B t, 1 A u g ; 1 H b l G ra y M G , H T [ Q 3 [ Q 3 \ Q 1 – IA In te rn al m ar k et 2 0 0 U 7 0 C er ro A´ sp er o o r G ra y R o ch a G ra n it e 3 0 Q tz , 3 6 O r, 6 M c, 8 P l, 1 2 B t, 7 M s, 1 C al G ra y F G – M G , H M [ Q 3 – Q 3 C ar b o n at es , li m o n it ic al te ra ti o n IA In te rn al an d in te rn at io n al m ar k et 2 0 0 – 3 0 0 U 7 3 C u fr e´ G ra y B lu e G ra n it e 4 0 Q tz , 1 O r, 2 9 M c, 2 4 P l, 6 B t G ra y M G , H T – – \ Q 1 L im o n it ic al te ra ti o n IA In te rn al m ar k et 2 0 0 U 8 3 G o n˜ i G ra n it e 4 5 Q tz , 2 8 O r, 2 4 P l, 3 B t G ra y M G – C G , H M – H T – – – – IA In te rn al m ar k et , h ig h re si st an ce p av in g 2 0 0 U 9 2 P an d e A zu´ ca r Q tz al k al i fe ld sp ar sy en it e 8 Q tz , 8 0 O r, 1 1 H b l G ra y C G , H M – – – – IA In te rn al m ar k et 2 0 0 U 9 3 S an ta T er es a G ra n it e 1 8 Q tz , 6 3 M c, 1 0 P l, 9 B t G ra y v C G , H M – – – – IA In te rn al m ar k et 2 0 0 U 9 4 Is la M al a T o n al it e 4 2 Q tz , 1 M c, 5 3 P l, 4 B t G ra y M G , H T – – – – IA In te rn al m ar k et 2 0 0 U 9 5 G ar zo´ n G ra y o r Ig u az u´ G ra y G ra n it e 4 6 Q tz , 3 2 O r, 6 M c, 1 3 P l, 3 B t G ra y F G , H M [ Q 3 – – – IA In te rn al m ar k et 2 0 0 – 3 0 0 U 7 L ab ra d o ri ta O ri en ta l o r M o sk ar t G ra n it e 4 1 Q tz , 4 6 M c, 8 P l, 1 H b l, 2 F es ti l, 2 O p G re en is h g ra y , g ra y is h b ro w n v C G , H M Q 3 \ Q 1 Q 3 M ic ro cr ac k s IA In te rn al m ar k et 4 0 0 – 5 0 0 U 1 5 S al m o n R ed o r G u az u b ir a´ Q tz al k al i fe ld sp ar sy en it e 1 2 Q tz , 7 1 O r, 1 3 P l, 2 H b l, 1 C h l, 1 F es ti l P in k sa lm o n C G – v C G , H M Q 3 Q 3 [ Q 3 P o re s IA In te rn al m ar k et 4 0 0 – 5 0 0 Environ Earth Sci (2013) 69:1397–1438 1425 123 This results in a boulder zone at the top and a weathered zone underneath, whose thickness depends on the intensity and duration of weathering. For dimensional granitic deposits it is important to determine the depth at which this weathering effect ends. Another estimation method for block sizes uses the software 3D-Block Expert described in Nikolayew et al. (2007), Siegesmund et al. (2007a, b), and Mosch et al. (2010). This program provides a better spatial distribution of the blocks in the section of the quarry considered for an optimized extraction. Sections of three quarries were modeled using this program: the Maldonado Granite (Fig. 19), Cufre´ Granite, and the Salmon Red Syenite (Fig. 20). In the Cufre´ Granite the whole quarry was modeled (a total volume of 9,979 m3), but the total amount of joints measured was very low (seven). The quarry is most likely not very representative of the global behavior of the deposit, and therefore, the results of the tectonic analyses overestimates the block sizes obtained by real mining. In the Maldonado Granite model (Fig. 19a–c) two sub- vertical joint sets are observable, which are orthogonal to each other, and a third joint set that is subhorizontal with a significant dip (Fig. 19d, e). This last joint set affects the deposit negatively, since it diagonally crosscuts the blocks that would otherwise be regular. The joint set parallel to the yz-wall is determined by the foliation of the rock, as depicted in Fig. 19a. The raw block size distribution (Fig. 19f) shows that the highest proportion of raw blocks is larger than 8 m3. The Salmon Red Syenite model (Fig. 20a–c) shows a lower amount of joints affecting the considered section. However, there are four joint sets affecting the rock and this is evidenced by the presence of vertical joints that are not orthogonal (Fig. 20d, e). The raw block distribution shows that most of the blocks that this section is able to produce are between 3.5 and 6.5 m3 and larger than 8 m3 (Fig. 20f). In two inactive quarries it was possible to measure the blocks remaining after the commercialization of the best ones. These are probably not the largest blocks that those quarries once produced (Fig. 21a, b). Most of the blocks in the Cufre´ Gray Blue quarry number 172 have a vol- ume between 1 and 6.5 m3 (Fig. 21c) being larger than those in the Cerro A´spero quarry (Fig. 21d). This is in accordance with the joint set frequency measured for both quarries (Fig. 21e, f) and the results acquired by applying the method of Singewald (1992), Palmstrøm (1982, 1996, 2001), and Sousa (2010) (Table 6; Fig. 16). The application of these methods in the Cufre´ quarry leads to a block size that is extremely large, but in accordance with those sizes obtained using the program 3D Block Expert.T a b le 7 co n ti n u ed Id C o m m er ci al n am e R o ck D e´c o r P et ro p h y si ca l p ro p er ti es D et er io ra ti o n ri sk s U se s* * * C o n cl u si o n fo r ec o n o m ic al as p ec t P ri ce ra n g e (U S $ F O B ) M o d al an al y si s (v o l% ) C o lo r F ab ri c* * U C S F le x . p o r. U 4 6 A rt ig as P ea rl A lk al i fe ld sp ar sy en it e 8 6 O r, 5 P l, 4 H b l, 5 F es ti l G ra y is h b lu e w it h p in k ri m s v C G , H T \ Q 1 \ Q 1 [ Q 3 M ic ro cr ac k s, p o re s IA In te rn al m ar k et 4 0 0 – 5 0 0 U 4 7 V io le ta Im p er ia l Q u ar tz sy en it e 1 1 Q tz , 6 7 O r, 7 P l, 8 H b l, 1 L m , 1 A u g , 2 O p , 3 F es ti l P al e re d -v io le t an d b ro w n is h C G , H M Q 3 \ Q 1 [ Q 3 – IA In te rn al m ar k et 4 0 0 – 5 0 0 U 7 4 C ar am el P in k o r L a P az G ra n it e 2 5 Q tz , 6 0 M c, 7 P l, 7 B t, 1 H b l P in k an d re d v C G , H T Q 3 * – Q 1 – IA In te rn al m ar k et 3 0 0 U 7 6 G u az u n am b ı´, M o n te v id eo o r Ig u az u´ G ra n it e 2 7 Q tz , 1 5 O r, 1 6 M c, 3 6 P l, 4 B t, 1 A u g , 1 C al R ed an d re d d is h b ro w n M G , H M Q 2 * – Q 3 C ar b o n at es IA E v en tu al ly in te rn at io n al m ar k et 3 0 0 – 4 0 0 U 8 8 M ah o m a G ra n it e 4 1 Q tz , 7 O r, 1 5 M c, 3 0 P l, 6 B t P in k M G , H M Q 2 * – Q 2 – IA E v en tu al ly in te rn at io n al m ar k et 3 0 0 – 4 0 0 A b b re v ia ti o n s af te r K re tz (1 9 8 3 ) ex ce p t th e o n es m ar k ed w it h ? A b al b it e, C a m C a cl in o am p h ib o le , A u g au g it e, B t b io ti te , C al ca lc it e, C hl ch lo ri te , S tp st il p n o m el an e, G r. In t. ? g ra p h ic in te rg ro w th , H b l h o rn b le n d e, L m li m o n it e, M c m ic ro cl in e, M s m u sc o v it e, O p ? o p aq u es , O r o rt h o cl as e, P l p la g io cl as e, Q tz q u ar tz * * F G fi n e- g ra in ed , M G m ed iu m -g ra in ed , C G co ar se -g ra in ed , vC G v er y co ar se -g ra in ed * * * I in te ri o r u se , A ex te ri o r u se 1426 Environ Earth Sci (2013) 69:1397–1438 123 Reserves and economic aspects The feasibility of the utilization of a deposit is determined not just by the dimensions of the deposit, but also by the economic demands and the deposit geometry, the stability of the country rock and the environmental conditions (clima, infrastructure, etc.). Nevertheless, the decisive cri- terion is the volume of the deposit. This depends on the dimensions of occurrence of the rock, which actually meets the criteria of a marketable color and de´cor with exploit- able block sizes. In the present research the surface area has been determined by the analysis of geological maps, satellite images, and observations in the field. A careful analysis of the morphology of the area of the deposit can lead to the identification of sectors not suitable for mining (e.g., occurrence of faults or highly fractured sectors). For the calculation of maximal reserves, it is reasonable to assume a maximum depth of 100 m. The reasons for not considering a greater depth are the stability of the rock massif, the economic costs of mining (e.g., transport costs, cost of water pumping, mine ventilation, safety of the staff, etc.), and rock mechanical problems (stress relief at greater depth can lead to intense fracturing, limiting the production of blocks). In stratiform deposits only the maximum depth of the strata is exploitable. The exploration and evaluation of a dimensional stone deposit should consider, on the one hand, the maximum extension of the reserve. On the other hand, a minimum deposit volume is required. The opening and operation of a quarry demands a significant investment that is com- monly covered by loans. The repayment period is between 10 years for movable goods and 30 years for immovable properties. For dimensional stones a 30-year repayment period is also normally accepted. The main reason is that this kind of resource is not only listed on the stock exchange and their commercialization allows relatively low profit margins, but also due to its depen- dence on the prevailing taste (color and de´cor trends) and the trade cycles of the construction industry. In many countries the approval of operating plans for a quarry is based on these terms of repayment. For these reasons a minimum reserve volume should be calculated for a 30-year operation: (a) Scheduled annual production volume, taking into account non-productive periods (rainy seasons, freez- ing temperatures, impassable transportation routes, work regime). (b) Mining rate related to the joint systems inventory of the deposit. (c) Mining rate by squaring of the industrial blocks. (d) Mining rate considering the influence of lithological elements, which require a differentiation by taking into account the quality of the color and de´cor, which causes an impact on the revenue. (e) In addition, the rate of utilizable raw material for the fabrication of products that are not taken into account in the industrial usable blocks (e.g., small blocks for self-production, building bricks, paving materials). Mafic rocks The mafic rock deposits provide one of the most important varieties of dimensional stone: the black commercial granite. In Uruguay they are mainly represented by the dolerite dike swarm, which intrudes into an area covering 20,000 km2 in the southwestern part of the country. The dikes are normally not wider than 40 m and around one kilometer long. The maximal depth reached in the quarries by the prevailing mining method is about eight meters. In similar deposits in northern China and southern Sweden depths of more than 50 m are possible. In these kinds of deposits the maximum mineable depth is a very relevant factor for the economic viability of the mine. The stability of the country rock is an important parameter to consider when the mining proceeds down- wards. When the country rock is not stable enough, the mining can lead to landslides compromising the safety of the personnel (staff) and the continuity of the mining itself. This holds especially true in the case of the Uruguayan dolerite deposits, where the contacts of the dikes with the country rock are sub-vertical and dipping steeply to the southeast (Morales Demarco et al. 2011). The waste rock produced in the mining of the dolerites is usually higher than that of other commercial granites with a different geometry. In several dikes from Group A (high TiO2) a variation of the grain size is observable from the contact with the country rocks (where the grain size is finer) to the center of the intrusion (where the grain size is coarser). Thus, two varieties of commercial granites can be mined: one is a very fine-grained and deep black color (Absolute Black) and another is dark gray in color (Moderate Black) (Mor- ales Demarco et al. 2011). Based on a minimum of 19 identified productive dikes in the dike swarm outcrop area (20,000 m2), these authors proposed a probable reserve of 407,500 m3, being 10 % of Absolute Black quality. Economic aspects of mafic rock deposits Due to their high quality color, de´cor, and petrophysical properties these rocks are very valuable. They have inter- national prices between 1,200 and 1,700 US$/m3 free on board (FOB) for the Absolute Black and between 900 and 1,200 US$/m3 FOB for the Moderate Black (Table 7). Environ Earth Sci (2013) 69:1397–1438 1427 123 For Moderate Black a probable reserve of 366,750 m3 is proposed (Morales Demarco et al. 2011). Taking an average value of 1,000 US$/m3 FOB an annual production value of 12.2 million US$ of Moderate Black can be calculated for a 30-year mining period. Absolute Black has a lower probable reserve of 40,750 m3 (Morales Demarco et al. 2011), but a higher price, of 1,500 US$/m3. For the same mining period would lead to a value of 2 million US$/year. Gray Granitoids The Uruguayan granitoids only show a small variety of the typical colors and de´cors of the internationally marketed granitoids. Most of the granitoids mined in the country are gray and medium-grained. This kind of hard dimensional stone is widespread worldwide and their de´cor is not so interesting for the international market. Nevertheless, three of them are interesting for the local and regional markets: Cufre´, Maldonado, and Cerro A´spero. The last one is possibly the most relevant due to its fine-grained texture, light gray color, and excellent petrophysical properties. Cerro A´spero Granite The mining district Cerro A´spero Granite (U70) is located around 13 km west of the city of Rocha, in eastern Uru- guay (Fig. 5). This district contains four quarries. Two of them are relatively large quarries (about 3,000 m2), which are presently inactive and the other two are still active but smaller (around 400 m2). The rock is a fine- to medium-grained light gray granite with a relatively scarce occurrence of enclaves or veins. Its color and de´cor are very interesting for the international market, and since this rock has very good petrophysical qualities, it could compete for a place in the fine-grained gray granites sector. The quarries are located in a granitic massif occupying an area of approximately 1.8 km2, which is expressed in the geomorphology as a gentle slope (1.5 %) hill, known as Cerro A´spero. The rock mined is characterized by a slight differentiation in grain size between fine- and medium- grained and a light gray color. Phenocrysts of plagioclase of white and light gray colors (up to 10 mm) and black clots of biotite (up to 5 mm) can eventually appear. Small mafic enclaves (up to 3 cm) and narrow aplitic dikes (up to 1 cm) are relatively rare. The de´cor and color of this granite is very homogeneous. A boulder zone occurs at the top of the hill, with potential interest for the squaring of large blocks. There the yield of production is expected to be very high (around 90 %). The underlying weathered zone is around two meters thick in the already opened quarries. This zone represents waste mate- rial for the dimensional stone industry, but it could be used for road paving and quarry filling after the mining ceases, thus reducing the cost of mining. The most economically interesting sector is on the eastern side of this granitic massif, where one of the large inactive quarries is located (quarry number 192). The factors that make this sector more interesting are the fine grain size of the rock and the more favorable joint set distribution. The distribution of the fine-grained area is around 90,000 m2. A minimum depth of 10 m can be easily reached taking into account the mining situation in the deposit. The gentle slope of the hill where the deposit is localized allows the consideration of the surface as flat to simplify the calculations. This assumption is valid for all the following deposits considered. The raw production of this sector would be around 0.9 million m3. The yield of pro- duction inferred is 50 % taking into account the blocks in the deposit and the waste material produced: 450,000 m3. The block size determined using the Singewald (1992), Palmstrøm (1982, 1996, 2001) and Sousa (2010) methods are 6.16 and 3.27 m3, the maximum and median, respec- tively. The sizes of the blocks in the deposit were measured (Fig. 18b, d) and they are smaller than those calculated using the cited methods. This is because they are the blocks left behind after the commercialization of the better ones, probably due to their inferior quality or smaller size. Quarry number 193, the second largest quarry, is also currently inactive and located in the western sector of the deposit. The rock is characterized by its medium-grained texture and by the relatively higher frequency of joints. From the joint set distribution measurements, a fault- damage zone presumably affects this quarry, since the block sizes calculated using the Palmstrøm (2001) and Sousa (2010) methods are significantly smaller than those obtained for quarry number 192 (Table 6). In fact, this quarry produces small paving stones (around 0.04 m3) using unsophisticated technology. Cufre´ Gray Blue Granite The Cufre´ Gray Blue Granite deposit is located 16 km from Nueva Helvecia, in the Colonia department. The only quarry in the area is now inactive. The rock is a medium- grained gray granite with relatively frequent mafic enclaves and narrow aplitic dikes and a gentle foliation. The previously described methods of Palmstrøm (1982, 1996, 2001) and Sousa (2010) probably overestimate the plausible block sizes being mined in this deposit. This is due to the lack of visible joints affecting the rock massif in the observed quarry. Nevertheless, taking into account the real block size distribution measured in the blocks left out in the quarry, it is possible to assume a production of large blocks suitable for processing by gang saw blade. 1428 Environ Earth Sci (2013) 69:1397–1438 123 The total outcrop area is around 15 km2, but the potentially most interesting zone is about eight hectares (80,000 m2), where the quarry was opened. The weathered zone is relatively narrow, around 1–1.5 m that has to be considered waste material in the cost calculation. A mini- mum mining depth of 10 m would lead to a total volume available for extraction of approximately 800,000 m3. A yield of 30 % is possible for this deposit taking into account the structural elements, such as mafic enclaves, dikes, and the low incidence of joints. From this 240,000 m3 to be produced, just around 10 % will attain the requirements for exportable blocks. Maldonado Granite Maldonado district is located five kilometers from the cities of Maldonado and Punta del Este. There are three active quarries, whose production consists mainly of small blocks with rough surfaces for the local market. The rock is characterized by a dark gray color and a coarse-grained and foliated fabric. In the upper floor of the quarry the evidence for weathering is visible by the oxi- dation of the biotite clots as limonitic (orange) spots. Elongated mafic enclaves and aplitic dikes are aligned within the foliation and so homogeneously distributed that they act as part of the de´cor. The district area is about 1.3 km2 and 5 % of it could be possibly mined. Considering a mining depth of 10 m at several levels, the total volume would be 650,000 m3. The normal yield for this kind of mining in Uruguay is around 30 %. Since the requirements for this rock are not high, there is no limitation in respect to block size. This is very relevant because, even though the raw block size distribution mod- eled using the software 3D Block Expert show positive results (Fig. 19), the block size calculations using the Palmstrøm (1982, 1996, 2001) and Sousa (2010) methods show very small block sizes (\0.20 m3) (Table 6), making this rock incapable of entering international markets. Moskart Granite The Moskart Granite district is situated in the locality of Soca, about 50 km east of Montevideo. Several quarries were active in this district; however, at present there are no mining activities. These activities were in close connection with more traditional farming activities (e.g., agriculture and livestock). This district has an area of about 800,000 m2, being 10 %, located in different sectors of the district and interesting for mining. For a reserve calculation a mining depth of 10 m can be considered, even though it is possible to reach larger depths due to the stability of the rock massif. The yield of this dimensional granite is considered to be high (about 50 %) allowing for the absence of waste material in the areas sur- rounding the quarries. A probable reserve of 400,000 m3 is calculated for the Moskart Granite deposit. From the block size calculations relatively small block sizes are expected. The most conservative method (Sousa 2010) calculations determine a median block size of 1.8 m3. Economic aspects of gray granitoid deposits Gray granitoid deposits show a relatively narrow de´cor range and their petrophysical properties are very good. The prices for these granites range between 200 and 300 US$/ m3 FOB (Table 7). From the reserve calculations, the Cerro A´spero Granite deposit could produce annually up to 15,000 m3 of large-, medium-, and small-sized blocks. These blocks could be traded with prices of around 200–300 US$, depending on their sizes, color, and de´cor quality. The annual quarry gross income would be between 3 and 4.5 million US$. For Cufre´ Gray Granite an annual production rate of 8,000 m3 is proposed. Considering an international price for this kind of dimensional stone of 200 US$/m3, the annual quarry gross income would be around 1.6 million US$. An annual rate of 6,500 m3 is estimated for Maldonado Gray Granite deposit. The annular income taking a price of 200 US$/m3 would be 1.3 million US$. The Moskart Granite is with no doubt the exception in this group, since its de´cor is very unique and it is possible to square large blocks making this rock very competitive. Its price is between 400 and 500 US$/m3 FOB (Table 7). The yearly production rate would be 13,000 m3. Consid- ering that 10 % of this production are exportable blocks and taking the price in m3 of 450 US$, an exportation income of 585,000 US$ should be expected. Syenitoids Uruguayan syenitoids are mined in two districts in the Sierra de las A´nimas Complex. Since the start of produc- tion at the beginning of the 20th century and before the economic crisis in Uruguay in 2002, the production took place in small quarries offering a diverse color spectrum. In the southern mining area (Pan de Azu´car—Piria´polis) large quarries were located in the Cerro Pan de Azu´car and Sierra de las Palmas hills with a capacity to provide material for export. During the 1980s and 1990s, mining activity was concentrated in small quarries in the northern mining district (the Camino del Amigo-Estancia Guazu- bira´). Nowadays all quarries are inactive. The color and de´cor of the syenitoids are a major con- trolling parameter of the deposit. They are related to the amount and grain size of the feldspars, and the color development related to hydrothermal alteration. Environ Earth Sci (2013) 69:1397–1438 1429 123 Artigas Pearl This deposit shows hydrothermal alteration and comprises a total exposure of 4.6 km2. Considering the outcrop con- ditions and the geological findings, an area of 90,000 m2 can be mined. Due to the intrusion of dikes, a decrease of 30 % in the possible reserve volume has to be considered. The presence of dikes (mainly quartz alkali feldspar tra- chyte) leads to a high rate of waste material. The waste material of the weathered section on the top of the deposit is not included in this estimation. Individual boulders are exposed in this section and are of industrial value, as long as good petrophysical properties stay and are not affected by joints. However, the amount of the waste material to be removed in the weathered section below the boulder zone is calculated to be around 90 %. The joint distance measured thus far within the outcrops of the deposit indicates a decrease of the joint distance with the depth (See Table 6). At what depth the rock (Artigas Pearl Syenite) is weathered and the joints opened, is still an uncertainty. Hence, only boulders at the top of the hill and in the upper floor can be mined at present. Average block sizes of 38.1 and 2.14 m3 (median) were determined for the boulder zone and upper floor, respectively. A new exploi- tation of this upper floor should be geared to the geometry of the surface. The mining rate of the boulder zone is estimated to be very high (around 50 %), being drastically lower in the upper floor by around 10 %. Considering that the boulder zone extends for an area of 240,000 m2 and the average height is 5 m, the probable reserve of this zone taking into consideration the yield of the mining would be around 600,000 m3. The upper floor could be mined in a similar area and at similar depths, but as the yield is lower here a probable reserve of 120,000 m3 is expected. Pan de Azu´car White In the southern mining district white syenite crops out in the hill Cerro Pan de Azu´car. Commercially it is known as Pan de Azu´car White, but the quarry from where it was mined is now inactive. This dimensional stone is charac- terized by its light gray color and coarse-grained texture. Even though this rock shows feldspar substitutions, the absence of red stain is related to the lack of hematite in the pores of the feldspar, probably due to the lack of hydro- thermal influence. The surface distribution of this deposit is unknown, due to the steep slope of the hill and the lush vegetation that covers the outcrops. A minimum area of 21,000 m2 is determined by the extent of the inactive quarry and its surroundings. Con- sidering a safe mining depth of 10 m, the probable reserves would be about 210,000 m2. With a mining yield of 50 %, a block production of 105,000 m3 is expected. Guazubira´ Syenites: Salmon Red and Violeta Imperial In the northern mining district the pink and light red colors dominate (Salmon Red Syenite). The mining district has an area of about 5 km2. Typical for this district are numerous wide fault zones as indicated by the valleys. Former mining in the center or nearby these zones produced only ballast and rubble (aggregates). The joint set distribution has been measured and analyzed using the previously described methods of Palmstrøm (1982, 1996, 2001) and Sousa (2010). A deposit (quarry number 075) for production of dimensional stone localized in a fault zone has a median block size of just 0.4 m3. In another deposit (quarry number 079) outside the fault zones a median block volume of 4.89 m3 is calculated. Considering the tectonic setting the potential mining area is reduced to almost 30 % of the whole deposit: 1.5 km2. The waste material would be considered a cost factor, but not as a decrease in the reserves. For a realistic calculation of the deposit reserves, quarry 079 will be used as an example. Its dimensions are around 700 9 300 m, therefore an area of 210,000 m2. Using a con- servative mining depth of 10 m and a mining yield of 60 %, the reserves would be about 1,260,000 m3. The yield proposed is based on the international experience and the model of a sec- tion of quarry 075 using 3D Block Expert (Fig. 20). A theoretical annual production capacity of 42,000 m3 is calculated for a mining duration of 30 years in the quarry 079. Oscillations in the world market must be considered. It is also necessary to evaluate the considered area using economical geophysical methods to determine the distri- bution and magnitude of the waste material to be removed. Regarding the cost of mining an optimization can be proposed using two different mining procedures. One pro- cedure would be to use a greater surface area for mining at lower depth, and the second the construction of numerous mining levels to reach greater depths in a smaller area. The influence of volcanic rocks occurring at the rim of the deposit cannot be easily evaluated. It cannot be excluded that the deposit is affected by dikes, veins, or sills. The small deposit of Violeta Imperial Syenite is a special case in regards to de´cor, where it shows smaller and narrow alkali feldspars that partially exhibit an interstitial fabric and a red-violet color. Its dimension is less than 10,000 m2. Considering a mining depth of 10 m and a rate of 60 %, the possible reserves of this deposit are calculated to be 60,000 m3. A production would be possible as a special target and would only be economically viable in combination with the main production of the pink-colored syenite. Economic aspects of syenitoid deposits The syenitoid group may also have a good position on the international market, since the range in de´cor for these 1430 Environ Earth Sci (2013) 69:1397–1438 123 rocks is quite uncommon and very pleasing to the eye. As the petrophysical properties are not a limiting factor for their commercialization, these rocks could be sold at prices between 400 and 500 US$/m3 FOB. An annual production of 24,000 m3 is proposed for the Artigas Pearl Syenite. The attainable average market price of 500 US$/m3 would account for 12 million US$ per year. For the Pan de Azu´car Syenite an annual production of 3,500 m3 can be calculated. At market prices for white granitic stones of 200 US$/m3 FOB, the annual income of its mining would be 700,000 US$. Due to its color and de´cor the Salmon Red Syenite could be easily placed on the market in the category of red gra- nitic dimensional stones. Its fabric makes it particularly Fig. 22 Damages. a Moskart Granite broken floor cladding due to the low flexural strength of this rock; b Moskart Granite outdoor fac¸ade cladding with calcite precipitated in the microcracks, probably by the remobilization of the cement material; c Artigas Pearl Syenite outdoor cladding; precipitation of calcite from the cement in the joint between two slabs; d Artigas Pearl outdoor monument cladding with a crack presumably posterior to the placement. Note the microcracks and little pores homogeneously distributed in the entire polished slab; e La Paz Granite urban monument affected by biomechanical deterioration due to the growth of a tree; and f the same monument shows anthropogenic deterioration (graffiti) Environ Earth Sci (2013) 69:1397–1438 1431 123 interesting, because it gives the impression of being opti- cally homogeneous. Taking an average price level of 500 US$ per m3 and an average rate of 50 % of exportable industrial blocks would result in an annual amount of 10.5 million US$. For the Violeta Imperial deposit the annual production of 2,000 m3 can be calculated. The prices for this kind of colored granitic stones average 450 US$/m3 FOB, allowing an annual value of 900,000 US$. Final remarks and conclusions The Uruguayan commercial granites can be classified by their petrography and geochemistry into mafic rocks, granitoids, and syenitoids. For each of these groups a characterization has been carried out considering their color and de´cor, their petrophysical properties and the chance of their economically mining (deposit). The only mafic rock deposits successfully mined in Uru- guay today as dimensional stone are the dolerites. Even though there are two distinct geochemical and petrographical groups (A and B, with high and low TiO2 contents, respec- tively), the de´cor and the petrophysical behavior is similar for both groups (samples U11O and U66). The exception to this assessment is the absence of the high quality black de´cor in Group B, since Absolute Black Dolerite (U11A) has only been found in the dikes of Group A (Morales Demarco et al. 2011). The high densities and especially the very low porosities and pore-related properties (e.g., water absorption, water vapor diffusion) of these rocks make them high quality granitic dimensional stones. They occupy a very favorable position in regards to their diverse applications; since they are very resistant to weathering and freezing and present no deterioration risks (See Table 7). The near-isotropic char- acter of their petromechanical properties make possible their use as constructive elements subjected to high uniaxial applied loads, independently of the orientation of these ele- ments (e.g., fac¸ades, support masts). Similarly, the thermal expansion is also near isotropic making possible the appli- cation of these rocks as elements that require an extreme low anisotropy (e.g., precision tables). Uruguayan dolerites, therefore, can be used as constructive elements in all indoor and outdoor applications and can occupy a relevant position on the international market. The Uruguayan black commercial granites are compa- rable with several worldwide known dimensional stones in regards to de´cor and petrophysical properties (Table 6). The Absolute Black Dolerite can be compared with the Shanxi Black. They are similar in de´cor but the Uruguayan variety is slightly darker than Shanxi Black. In respect to their petrophysical properties they are very similar. Mod- erate Black Dolerite is comparable to the Impala Dark. The Uruguayan dolerite has a finer grain size and higher com- pressive strength but a lower flexural strength. The fine-grained gray granite varieties Cerro A´spero and Garzo´n Gray are similar in de´cor to the Padang Light Granite (G633/G3533) (China) and Kuro Gray (Finland). The petrophysical properties of the Uruguayan fine-grained gray granites are between those of these two internationally known granites (Table 7). Cerro A´spero Granite show higher UCS values as Padang Light, as well as slightly lower water absorption values. Oxidation of biotite under normal weathering conditions has an adverse effect on the color (by the staining of surrounding minerals) and in the rock stability. In the Cerro A´spero Granite no accumulation of iron hydroxide occurs due to the extremely low capillary water uptake. This characteristic places this granite in a better market position in comparison to the Padang Light, which is one of the most commercialized light gray and fine-grained granites. In its porosity and pore-related pe- trophysical properties, the Cerro A´spero Granite is com- parable to the Kuro Gray Granite from Finland. The Cerro A´spero Granite deposit can provide material for the dimensional stone industry as well as directly for the building sector. The large blocks can be cut with a gang saw blade for the production of polished slabs for wall cladding. The small- and medium-sized blocks provide material for flagstone and other products using normal saw blades or by simple handwork. For an increase of the competitiveness of the Cerro A´spero Granite it would be important to further analyze this commercial granite and compare it in detail with the world leading fine-grained gray granites. Also a promotion of this granite in interna- tional fairs and specialized literature would improve its position in the international market. The color and de´cor of the Cufre´ Gray Blue Granite is not particularly interesting for the international market, but the rock can be commercialized at local and regional markets. Oxidation of the mafic enclaves and biotite clots with the development of orange-colored limonitic spots has been observed in the quarry. This phenomenon has not been seen in polished slabs used for outdoor fac¸ades (e.g., Torre de Antel; See Fig. 1a). The stone has a very high content of quartz (40 %), and thus a good durability as a polished surface. Due to the presence of a foliation, mafic enclaves, and biotite clots, the de´cor of this rock will vary within a block. The entire block needs to be cut to classify the fin- ished product according to the de´cor (i.e., the presence or the absence of heterogeneities that will determine the products quality). Taking into consideration these facts and also the low porosity and low capillary water absorption, the Cufre´ Gray Blue can substitute for high quality imported stones for indoor and outdoor floor and fac¸ade cladding. Maldonado Gray Granite is comparable in de´cor and petrophysical properties with the Italian Serizzo Antigorio 1432 Environ Earth Sci (2013) 69:1397–1438 123 gneiss. The Uruguayan granite shows higher strength val- ues and lower water uptake. An optimization of the mining of this commercial granite could eventually lead to a higher production of larger blocks, which could place this granite on the international market. Moskart or Soca Granite has similarities in de´cor (the greenish-gray color, the very coarse-grained texture, and the occasional iridescent feldspar) with the Flash Blue Granite from India and the Verde Butterfly from Brazil. The compressive strength is higher in the Uruguayan Granite and its flexural strength and water uptake values are in between both international granites. These charac- teristics make the Uruguayan granite a good competitor against the Indian and Brazilian granites. Due to its very coarse-grained texture and the presence of microcracks, the best method for mining this dimensional stone has proven to be the diamond wire saw. These characteristics, together with the relatively low values of its petrophysical proper- ties, make a previous treatment of the slabs necessary to ensure their stability (e.g., chemical treatment to prevent water infiltration). Examples of this assessment are illus- trated in Fig. 22a, where a step of a stone staircase broke due to the low flexural resistance of this stone. In Fig. 22b an outdoor fac¸ade cladding with precipitated calcite in the microcracks is shown, probably due to the remobilization of the cement material. Despite these application problems the Moskart Granite was commercialized on the interna- tional market during the last decade of the 20th century. The de´cor of the Uruguayan colored syenitoids is so unique that there are no rocks to compare them with. The red granites, on the other hand, can be compared with numerous rocks. The equigranular facies of the La Paz Granite can be compared to the Rosa Santa Eulalia, a granite from Portugal; the porphyritic facies with the Rosavel Granite from Spain and the Guazunambı´ Granite with the Marrom Gaucho Syenite from Brazil. Their petrophysical properties are comparable to those of the international granites, but the compressive strength is clearly higher than the Rosavel quartz syenite. The appearance of numerous open pores in polished slabs of the Artigas Pearl Syenite, as well as in the deposit, is a factor to consider for its application. A coating will be necessary before its utilization as a working table or high quality flooring slabs. The use as a funerary monument is limited due to the high requirements in this sector. Basi- cally, the application of this rock in the heavy duty sector has to be carefully considered, since it has relatively low petrophysical values in comparison to those of the syenite- monzonite groups of Mosch (2008). The Salmon Red Syenite is in demand on the interna- tional market because of its color and de´cor, where it can be used in combination with rough surfaces and more dark red rocks for indoor and outdoor flooring slabs. Comparing the petrophysical values with the syenite-monzonite group investigated by Mosch (2008), this syenite has a very good position, allowing its use in sophisticated construction locations such as fac¸ades and countertops. Pore formation can be problematic in this dimensional stone, so that spe- cial attention has to be taken in the posterior industrial process (cutting and polishing). No negative aspects are known in regards to the weathering behavior. The Pan de Azu´car White Syenite is comparable in de´cor to the Bianco Sardo from Italy. This rock could be interesting for the international market, as long as it can be extracted in industrially utilizable blocks. It could occupy a segment in the market, because the color ‘‘white’’ in hard rocks is not very common. In this sector, aplites and gneisses are offered, which very often show problems with posterior alteration accompanied by the formation of visi- ble limonite. Uruguayan syenitoids have been in use for several decades in the harbor facilities of Argentina and Uruguay. They have a high salinity resistance as well as a high resistance against applied loads (wash of the waves). This allows the application of small blocks on the international market for sectors that need high chemical resistant materials. With this special utilization, the deposits would be more competitive and have a better mining yield, since the high proportion of waste material is composed of small blocks. The waste material could be minimized by the production of aggregates parallel to the production of large blocks. In summary, the color and de´cor, together with the petrophysical properties of the Uruguayan commercial granites places them in a very good position to compete with internationally known granitic stones. The dolerites are particularly interesting because they show excellent petrophysical properties that allow their use in all types of building applications. Their color and de´cor make the commercialization of these rocks independent of the changing fashion demands of the market. Acknowledgments We would like to thank Dipl.-Ing. Peter Machner, Matthias Gehrke, and Dr. Alexander Wetzel for their help with the abrasion measurements at the AMPA Laboratory (Amtliche Materialpru¨fanstalt fu¨r das Bauwesen) of the University of Kassel. Further thanks go to Dr. Rudolf Naumann for the geochemical measurements at the GFZ (GeoForschungsZentrum) in Potsdam; and Janousˇek V, Farrow CM, Erban V, and Sˇmı´d J for the use of the program GCDKit (GeoChemical Data ToolKIT) for plotting the geochemical data. In Uruguay our thanks go to Ing. Jorge Spoturno, Ing. Haroldo Albanell, Dipl. Geol. Silvana Martinez, Dr. Jorge Bossi, Dr. Leda Sa´nchez Bettucci, and MsC. Juan Ledesma for their com- ments, suggestions, and support. We also would like to thank the companies Black Stone S.A., Comercio Exterior S.A., Pimafox S.A., Vodelı´n S.A., and Rufo Hnos S.A. Special thanks also go to the students, friends, and family in Uruguay and Germany for their help and support. We are very grateful to Dr. Klaus Wemmer not only for the help in the field, but also for his support in scientific and Environ Earth Sci (2013) 69:1397–1438 1433 123 existential matters. We also thank Christian Gross for his help with the English corrections. M. Morales Demarco is grateful to the DAAD for the long-term fellowship (A/07/98548). Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, dis- tribution, and reproduction in any medium, provided the original author(s) and the source are credited. Appendix See Appendix Tables 8, 9, 10 and 11. Table 8 Petrophysical properties: density, porosity, water absorption (W.A.) Rock/test ID Bulk density (g/cm3) Matrix density (g/cm3) Porosity (%) Average pore radii (lm) Most abundant pore radii (lm) Capillary W.A. (kg/m2h0.5) Forced W.A. (wt%) Unforced W.A. (wt%) S value Absolute Black Dolerite U11A 2.99 2.99 0.03 0.097 0.013 0.04 0.01 0.01 0.96 Moderate Black Dolerite U11O 3.02 3.02 0.06 0.064 0.021 0.09 0.02 0.02 0.97 Oriental (Pimafox) Dolerite U66 2.97 2.98 0.12 0.209 0.084 0.13 0.04 0.03 0.87 Arapey Black Basalt U49 2.94 2.96 0.98 0.032 0.021 0.16 0.33 0.28 0.86 Maldonado Gray Granite U2 2.64 2.64 0.48 0.051 0.053 0.10 0.18 0.17 0.91 Chamanga´ Gray Granite U4 2.69 2.69 0.27 0.077 0.021 0.10 0.10 0.07 0.70 Cuchilla del Perdido Granite U53 2.72 2.73 0.31 0.070 0.084 0.11 0.12 0.09 0.80 Cerro A´spero Gray Granite U70 2.65 2.67 0.80 0.090 0.133 0.11 0.30 0.27 0.89 Moskart Granite U7 2.66 2.67 0.58 0.070 0.008 0.07 0.22 0.19 0.89 Salmon Red Syenite U15 2.61 2.64 0.86 0.042 0.084 0.82 0.33 0.30 0.91 Artigas Peart Syenite U46 2.64 2.68 1.15 0.077 0.008 0.19 0.44 0.40 0.93 Vioieta Imperial Syenite U47 2.62 2.66 1.34 0.057 0.335 0.22 0.51 0.43 0.83 Table 9 Petrophysical properties: thermal expansion, water vapor diffusion, and ultrasound Rock/test direction ID Thermal expansion (10-6 K-1) Water vapor diffusion Ultrasound (km/s) x y z Average value Anisotropy (%) x y z x y z Absolute Black Dolerite U11A 6.66 6.79 6.68 6.71 2 8,487 6,069 5,583 5.84 5.72 5.92 Moderate Black Dolerite U11O 6.53 6.55 6.87 6.65 5 5,344 5,473 5,599 6.41 6.49 6.34 Oriental (Pimafox) Dolerite U66 5.67 5.87 5.80 5.78 2 120 809 1,130 5.84 5.58 5.61 Arapey Black Basalt U49 6.21 6.03 5.75 6.00 7 -355 -781 -1,251 5.73 5.88 5.41 Maldonado Gray Granite U2 7.3 7.76 8.04 7.70 9 83 228 269 5.15 5.73 5.31 Chamanga´ Gray Granite U4 8.35 7.93 7.30 7.86 13 1,232 851 1,099 5.73 5.22 5.40 Cuchilla del Perdido Granite U53 7.39 7.88 8.28 7.85 11 528 456 459 5.85 5.62 5.57 Cerro A´spero Gray Granite U70 6.94 6.74 6.50 6.73 6 N.d. N.d. N.d. 4.27 4.08 3.38 Moskart Granite U7 7.78 9.47 8.46 8.57 18 374 526 358 5.83 5.57 5.46 Salmon Red Syenite U15 6.27 6.34 6.96 6.52 10 1,508 1,182 1,046 5.15 5.18 5.03 Artigas Pearl Syenite U46 5.74 6.79 6.18 6.23 15 442 1,017 588 5.08 5.03 4.88 Violeta Imperial Syenite U47 6.45 6.45 7.16 6.69 10 861 525 797 5.59 5.45 5.27 1434 Environ Earth Sci (2013) 69:1397–1438 123 T a b le 1 0 P et ro p h y si ca l p ro p er ti es : u n ia x ia l co m p re ss iv e st re n g th , m o d u lu s o f el as ti ci ty , an d in d ir ec t te n si le st re n g th R o ck /t es t d ir ec ti o n ID U n ia x ia l co m p re ss iv e st re n g th (M P a) M o d u lu s o f el as ti ci ty (G P a) In d ir ec t te n si le st re n g th (M P a) x y z x y z x y z A b so lu te B la ck D o le ri te U 1 1 A 4 0 0 ± 3 4 3 7 1 ± 3 7 3 6 7 ± 1 6 3 2 .9 ± 1 7 .4 2 9 .6 ± 9 .9 3 0 .6 ± 1 1 .9 1 6 .7 ± 4 .5 1 9 .5 ± 4 .3 1 7 .5 ± 5 .8 M o d er at e B la ck D o le ri te U 1 1 O 2 6 6 ± 2 7 2 6 9 ± 3 8 2 7 5 ± 2 5 2 7 .3 ± 1 5 .8 2 2 .9 ± 7 .3 1 7 .4 ± 4 .5 1 6 .7 ± 3 .0 1 5 .9 ± 3 .0 1 4 .3 ± 3 .4 O ri en ta l (P im af o x ) D o le ri te U 6 6 3 0 8 ± 3 9 2 6 0 ± 2 9 2 8 5 ± 4 1 2 9 .2 ± 1 6 .0 1 5 .4 ± 6 .3 1 5 .0 ± 6 .1 1 4 .7 ± 3 .2 1 4 .4 ± 2 .9 1 4 .3 ± 2 .7 A ra p ey B la ck B as al t U 4 9 2 2 6 ± 1 9 2 2 9 ± 1 7 2 3 0 ± 9 1 6 .1 ± 3 .8 2 3 .3 ± 6 .2 2 0 .2 ± 6 .1 1 0 .6 ± 2 .0 1 2 .7 ± 3 .1 1 0 .1 ± 1 .1 M al d o n ad o G ra y G ra n it e U 2 1 9 1 ± 9 1 8 7 ± 2 1 1 8 9 ± 2 1 1 6 .4 ± 5 .8 1 5 .7 ± 6 .1 1 6 .9 ± 2 .2 9 .1 ± 1 .6 8 .9 ± 2 .3 6 .8 ± 1 .9 C h am an g a´ G ra y G ra n it e U 4 1 7 5 ± 1 8 2 0 6 ± 1 4 1 8 1 ± 2 1 2 2 .6 ± 5 .4 3 2 .9 ± 1 2 .8 2 3 .9 ± 5 .5 8 .6 ± 1 .2 9 .4 ± 2 .3 1 0 .6 ± 2 .2 C u ch il la d el P er d id o G ra n it e U 5 3 2 0 3 ± 1 3 1 9 6 ± 1 6 1 9 7 ± 1 3 1 7 .4 ± 6 .5 2 2 .7 ± 2 .1 1 1 .9 ± 4 .8 9 .8 ± 2 .7 1 0 .6 ± 1 .3 1 0 .3 ± 2 .3 C er ro A´ sp er o G ra y G ra n it e U 7 0 1 9 0 ± 3 1 – 1 9 7 ± 1 4 1 7 .2 ± 3 .1 – 1 7 .4 ± 6 .1 1 0 .7 ± 1 .8 1 2 .6 ± 2 .7 – M o sk ar t G ra n it e U 7 1 6 2 ± 1 4 1 6 8 ± 1 8 1 8 1 ± 1 4 1 7 .2 ± 4 .4 1 3 .7 ± 4 .2 1 5 .2 ± 3 .2 8 .7 ± 1 .2 6 .6 ± 2 .1 7 .8 ± 1 .4 S al m o n R ed S y en it e U 1 5 1 7 7 ± 1 1 1 5 9 ± 2 3 1 9 3 ± 7 2 6 .4 ± 1 1 .6 1 7 .9 ± 6 .3 2 1 .0 ± 4 .2 8 .8 ± 2 .3 8 .7 ± 1 .8 9 .1 ± 1 .3 A rt ig as P ea rl S y en it e U 4 6 1 3 9 ± 4 1 3 8 ± 1 2 1 3 6 ± 2 1 8 .4 ± 5 .4 1 9 .4 ± 4 .8 2 0 .7 ± 1 3 .4 5 .2 ± 1 .1 6 .4 ± 1 .2 5 .7 ± 1 .0 V io le ta Im p er ia l S y en it e U 4 7 1 6 7 ± 1 7 1 6 9 ± 1 4 1 6 8 ± 1 4 1 3 .9 ± 4 .0 1 8 .2 ± 6 .4 1 6 .1 ± 4 .8 7 .5 ± 1 .6 7 .9 ± 1 .8 7 .2 ± 1 .3 T a b le 1 1 P et ro p h y si ca l p ro p er ti es : fl ex u ra l st re n g th , ab ra si o n st re n g th , an d b re ak in g lo ad at th e d o w el h o le R o ck /t es t d ir ec ti o n ID F le x u ra l st re n g th (M P a) A b ra si o n st re n g th (c m 2 /5 0 cm 2 ) B re ak in g lo ad at th e d o w el h o le (M P a) x y z x y z A b so lu te B la ck D o le ri te U 1 1 A 5 1 .8 ± 2 .2 5 2 .8 ± 2 .1 4 6 .1 ± 1 .5 2 .2 2 .4 2 .2 4 .7 ± 0 .8 M o d er at e B la ck D o le ri te U 1 1 O 3 5 .7 ± 2 .5 3 0 .8 ± 1 .3 3 2 .9 ± 1 .3 2 .3 2 .5 2 .4 4 .2 ± 0 .7 O ri en ta l (P im af o x ) D o le ri te U 6 6 3 6 .5 ± 0 .8 3 6 .4 ± 2 .1 3 8 .4 ± 0 .8 2 .0 2 .1 2 .1 3 .6 ± 0 .8 A ra p ey B la ck B as al t U 4 9 N .d . N .d . N .d . 3 .0 3 .4 5 .1 N .d . M al d o n ad o G ra y G ra n it e U 2 1 9 .3 ± 1 .7 2 6 .7 ± 1 .7 1 5 .2 ± 0 .7 1 .8 2 .5 2 .2 3 .2 ± 0 .7 C h am an g a´ G ra y G ra n it e U 4 2 2 .9 ± 1 .8 2 0 .6 ± 1 .3 1 7 .8 ± 1 .1 2 .3 2 .5 2 .4 2 .9 ± 0 .6 C u ch il la d el P er d id o G ra n it e U 5 3 1 9 .9 ± 1 .3 2 1 .7 ± 0 .6 1 9 .0 ± 1 .6 2 .5 2 .6 1 .9 3 .2 ± 0 .3 M o sk ar t G ra n it e U 7 9 .1 ± 3 .7 6 .7 ± 1 .4 9 .1 ± 1 .2 2 .9 2 .9 2 .7 1 .8 ± 0 .4 S al m o n R ed S y en it e U 1 5 1 4 .7 ± 2 .5 1 6 .4 ± 1 .3 1 5 .7 ± 1 .0 2 .7 2 .6 3 .2 2 .5 ± 0 .5 A rt ig as P ea rl S y en it e U 4 6 9 .2 ± 1 .7 8 .4 ± 2 .0 4 .4 ± 1 .4 3 .4 3 .5 3 .4 1 .9 ± 0 .2 V io le ta Im p er ia l S y en it e U 4 7 8 .4 ± 0 .7 8 .5 ± 0 .7 1 3 .0 ± 1 .0 2 .5 2 .5 2 .1 2 .6 ± 0 .4 Environ Earth Sci (2013) 69:1397–1438 1435 123 References Allaby A, Allaby M (1990) The concise Oxford dictionary of earth sciences. 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