One-Pot Synthesis of Xanthate-Functionalized Cellulose for the Detection of Micromolar Copper(II) and Nickel(II) Ions

Greis, Kim
Bethke, Kevin
Stückrath, Julius B.
Ingber, Tjark T. K.
Valiyaveettil, Suresh
Rademann, Klaus

DOI: https://doi.org/10.1002/clen.201900179
Persistent URL: http://resolver.sub.uni-goettingen.de/purl?gldocs-11858/9028
Greis, Kim; Bethke, Kevin; Stückrath, Julius B.; Ingber, Tjark T. K.; Valiyaveettil, Suresh; Rademann, Klaus, 2019: One-Pot Synthesis of Xanthate-Functionalized Cellulose for the Detection of Micromolar Copper(II) and Nickel(II) Ions. In: CLEAN – Soil, Air, Water, 47, 9, DOI: https://doi.org/10.1002/clen.201900179. 

Abstract

A one-pot synthesis and application of cellulose-based sensors to efficiently detect various toxic metal ions in aqueous solutions in micromolar quantities is reported. Cellulose microfibers have been functionalized with carbon disulfide in alkaline solution to form cellulose xanthate. The material detects several toxic metal ions such as copper, nickel, or cobalt ions through color change detectable by the naked eye. The optical sensor can be used as an ideal flash test for assessing the quality of drinking water.