Efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups.

Idzik, Krzysztof R.
Nödler, Karsten
Maier, Friedrich
Licha, Tobias

DOI: https://doi.org/10.3390/molecules191221022
Persistent URL: http://resolver.sub.uni-goettingen.de/purl?gldocs-11858/6912
Idzik, Krzysztof R.; Nödler, Karsten; Maier, Friedrich; Licha, Tobias, 2014: Efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups.. In: Molecules (Basel, Switzerland), 19, 12, 21022-21033, DOI: https://doi.org/10.3390/molecules191221022. 

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Abstract

A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.

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