Efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups.

Idzik, Krzysztof R.
Nödler, Karsten
Maier, Friedrich
Licha, Tobias
Journal: Molecules (Basel, Switzerland); 1912; 2014; p. 21022 - 21033
DOI: https://doi.org/10.3390/molecules191221022
Idzik, Krzysztof R.; Nödler, Karsten; Maier, Friedrich; Licha, Tobias, 2014: Efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups.. In: Idzik, Krzysztof R; Nödler, Karsten; Maier, Friedrich; Licha, Tobias (2014): Efficient synthesis and reaction kinetics of readily water soluble esters containing sulfonic groups. - Molecules (Basel, Switzerland), Vol. 19, Nr. 12, p. 21022-33, DOI 10.3390/molecules191221022.
 
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A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.
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